• Title/Summary/Keyword: UV Absorbers

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Effect on Functional Properties of the Cotton Fabrics Treated by UV-absorbers with Nanosilver/DMDHEU Treatment (자외선 흡수제 처리 시 은나노/수지 첨가가 면직물의 기능성에 미치는 영향)

  • Kang, Mi-Jung;Kwon, Young-Ah
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.9
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    • pp.1463-1471
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    • 2009
  • Silver ions or silver nanoparticles have multi-functional properties. The cotton fabrics for providing multi-functional properties were treated with a nanosilver powder, UV-absorbers, and dimethyloldi-hydroxyethyleneurea (DMDHEU) alone and mixed solution. The physical properties, UV protection, antibacterial, and deodorizing properties of treated cotton fabrics were evaluated. The results were as a follows. The UV protection of cotton fabrics were increased by the application of a nanosilver and Uv-absorbers mixture. The UV protection of treated fabrics were improved by nanosilver/DMDHEU/UV-absorbers mixed solution. The wrinkle recovery properties of fabrics treated with DMDHEU and nanosilver improved. The stiffness of fabrics are decreased by a nanosilver/DMDHEU/UV-absorbers mixed solution. The antibacterial properties of the fabrics treated with nanosilver/DMDHEU/UV-absorbers mixed solution is 99.99%. The functional properties of cotton fabrics are shown to be better with aanosilver/DMDHEU/UV-absorbers mixed than treated with nanosilver alone.

Overview of New UV-filters (새로운 UV 필터에 대한 고찰)

  • Osterwalder, Uli;Kang, Chul-Sang;Herzog, Bernd
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.31 no.3 s.52
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    • pp.237-244
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    • 2005
  • Sunscreens have been in use for about 70years and 'tanning without burning' was propagated as their major advantage. The objective changed from 'getting a tanned skin' to 'getting skin protection' since UV have been proposed to a major risk of skin cancer and the risk of developing skin cancer related also to non-burning UVA. The new expectation from consumers has triggered the development of new UV absorbers and led to the approval of 7 new, organic UV absorbers in Europe over the last few years. The significant progress due to these new UV absorbers will be discussed in this report. These UV absorbers provide an efficient absorption of UV radiation (UVB and/or UVA) and easily incorporate in any kind of formulation. These are also safe, i.e. devoid of adverse effects. These new filters give the formulators new possibilities to cover the whole UV range iron 290 to 400 nm, and also to use less filter due to the boosting effect of the new UVA and broadband fitters.

Preparation of Silica Microcapsules containing Water-Soluble UV Absorbers by a W/O Microemulsion Sol-Gel Process (W/O 마이크로에멀젼 졸-겔 법을 이용한 수용성 UV 흡수제를 함유한 실리카 마이크로캡슐의 제조)

  • 함경국;안복엽;석상일
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.220-220
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    • 2003
  • The microencapsulation of droplets or particles within a solid shell leads to the formation of core-shell particles. Microencapsulation provides protection and controlled release of core materials such as drugs, vitamins, enzymes, perfumes, and the like. Such particles have, therefore, found a diverse range of applications in the pharmaceutical, agricultural, cosmetic, and food industries. UV absorbers are widely used for cosmetics to screen out ultra violet (UV) rays which have side effects on human skin. The absorbers are made generally from synthetic organic compounds, which can stimulate the human skins to develop allergic phenomena.

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UV Blocking Coatings by Combination of Organic-inorganic Hybrid Materials and UV absorbers (유-무기 하이브리드 재료와 자외선 흡수제의 배합에 의한 자외선 차단 코팅)

  • Yu, Dong-Sik;Lee, Ji-Ho;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1296-1301
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    • 2006
  • The human eye is exposed to UV and visible light. UV light exposure becomes harmful to the eye. Protection for eyes should block all ultraviolet rays. In our study, organic-inorganic hybrid materials have been applied to UV blocking coatings with UV absorbing materials on transparent plastics. The optical properties of UV blocking coatings were investigated in PMMA, CR 39 and PC substrates. In case of all UV absorbers, the transmission of UV light decreases with an increased amount of absorber. Our findings indicate that PMMA significantly reduced the transmission of UV radiation, CR 39 showed moderate decrease, while UV-uncoated PC had some UV blocking properties. Adhesion, hot water resistance and chemical resistance of the UV-coated CR 39 lenses were good. Pencil hardness were 4H. Abrasion resistance were poor.

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Simultaneous Determination of UV Absorbers Migrated from Polyethylene and Polypropylene Food Packaging Materials into Food Simulants by HPLC-UVD (HPLC-UVD를 이용한 폴리에틸렌, 폴리프로필렌 기구 및 용기·포장 유래 자외선흡수제 동시분석법)

  • Choi, Heeju;Choi, Jae Chun;Bae, In-Ae;Lee, Chanyong;Park, Se-Jong;Kim, MeeKyung
    • Journal of Food Hygiene and Safety
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    • v.32 no.5
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    • pp.434-442
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    • 2017
  • The UV light in sunlight breaks down the chemical bonds in a polyolefin polymer through a process called photodegradation, ultimately causing cracking, chalking, colour changes, and loss of physical properties such as impact strength, tensile strength, elongation, and others. UV absorbers are used to prevent or terminate the oxidation of plastics by UV light. They are receptive to UV radiation and dissipate the energy harmlessly as heat. Benzotriazoles and benzophenones are used mainly in polyolefins such as polyethylene and polypropylene. In this study, we have developed a method for the analysis of 12 UV absorbers, which are Uvinul 3000, Cyasorb UV 24, Uvinul 3040, Tinuvin 312 and P, Seesorb 202, Chimassorb 81, Tinuvin 329, 234, 326, 328 and 327, migrated from the food packaging materials into four food simulants for aqueous, acidic, alcoholic and fatty foods. The UV absorbers in food simulants were determined by reversed-phase high performance liquid chromatograph-ultraviolet detector with 310 nm after solid-phase extraction with a hydrophilic-lipophilic balance (HLB) cartridge or dilution with isopropanol. The analytical method showed a good linearity of coefficient ($R^2{\geq}0.99$), limits of detection (0.049~0.370 mg/L), and limits of quantification (0.149~1.120 mg/L). The recoveries of UV absorbers spiked to four food simulants ranged from 70.05% to 110.13%. The developed method would be used as a reliable tool to determine concentrations of the migrated UV absorbers.

Stability and Sun Protection Efficacy of Sunscreens Based on the Solubility and a Combination of Organic UV Absorbers (유기 자외선 흡수제의 조합과 용해도에 따른 자외선 차단 효율의 비교 및 안정성에 관한 연구)

  • Yeon, Jae Young;Hong, Seung Deok;Choi, Se Bum;Kim, Ta Gon;Lee, Cheong Hee;Lee, Sang Gil;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.41 no.3
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    • pp.189-199
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    • 2015
  • In this study, we have investigated the stability of sunscreens based on the solubility of organic UV absorbers in the oil and sun protection efficacy of the products composed of a combination of organic UV absorbers to develop more stable and efficient sunscreen products. Results showed that the solubility of the organic UV absorber and stability were varied depending on the type, storage conditions and concentration of oil. It was also observed from the products in the emulsion type. Various UV absorbances were determined to the products composed of the combination of organic UV absorbers. In some combinations, a synergistic effect was observed to make an increase in absorbance compared to a single component. In other cases, specific synergistic effect was displayed only when combined with the particular component. In addition, the storage condition also affected the sunscreen efficacy. In conclusion, this study confirmed that there are various factors which could affect the UV-blocking efficiency of sunscreen products.

A Study on UV-CUT Processing (자외선 침투 방지용 직물의 개발)

  • 김삼수;김성동;조규민
    • Textile Coloration and Finishing
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    • v.6 no.3
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    • pp.52-59
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    • 1994
  • Polyester, polyester/cotton blend, nylon and cotton fabrics were ultraviolet cutting finished with padding method or exhaustion method using several UV absorbers. The transmittance of ultraviolet ray in the textiles can be greatly depressed by the processing and it is expected that human skin can be kept safe from sun-burn or damages by ultraviolet ray.

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A Study on the Ultraviolet(UV)-Cut Fiber (자외선 차단 직물에 환한 연구)

  • 최인려
    • The Research Journal of the Costume Culture
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    • v.11 no.6
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    • pp.967-971
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    • 2003
  • As the concerns over health increased in 1990's, research and development on the health material were also activated. The development of UV-cut textile became the hot issue, because the damage of W irradiation due to ozone depletion has become widely known. UV-cut effect is determined by the material, the color, the organization and the density of UV-cut fibers. UV-cut effect is very different according to the fibers. Polyester is known to have a better effect. Even in the same textile material, staple fiber has more effect than filament fiber. Different colors have different offsets. Although textiles have the same color, the effects can be different according to the depth of color. PET, PET/cotton blend, nylon and cotton fabrics were ultraviolet cutting finished with padding method using several absorbers. These UV-cut effect can be improved through the processing. Safety of UV-cut textile for the body must be considered future, Until now the figure of the UV-cut effects has been emphasized. There has been no experiment on the human body, although the textiles are directly on the human body. Futhermore there os no safety standard of UV-cut textiles. Therefore every effort will be made to set the standard UV-cut processing is established. The need of UV-cut products will be known to the consumers.

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Color Change and Tensile Properties of Wood Flour Reinforced Polypropylene Composites; Influence of Photostabilizers

  • Lee, Sun-Young
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.2
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    • pp.171-178
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    • 2009
  • A comparative analysis of the hindered amine light stabilizers (HALS) and UV abosrber (UVA) and their respective photostabilizing effect on wood plastic composites (WPCs) are reported in this study. The influence of accelerated weathering on the mechanical properties of the composites and the microscopic morphology of a degraded layer on the cross section and the surface were studied. UV absorbers were more efficient at preventing composite lightening than was UV stabilizer. The amount of whitening decreased with the increase of photostabilizers. With the addition of a UV absorber (Tinuvin360), the tensile modulus and strength of the composites increased slightly. However, the addition of a light stabilizer (Tinuvin770) and a UV absorber decreased the tensile modulus and strength of the composites. After 250 and 500 hr exposure, tensile modulus and strength of the un stabilized and stabilized composites decreased. The tensile strength of UV absorber (Chimassorb81)-stabilized composites was significantly greater than that of control and light stabilizer (Tinuvin770)- and UV absorber (Tinuvin360)-stabilized composites. UV absorber-stabilized samples showed less whitening and photodegradation than control and light stabilizer-stabilized samples.

Thermal Melt Grafting of Maleimides Having UV-absorber onto Polypropylene (폴리프로필렌에 UV 흡수제를 갖는 말레이미드의 용융그래프팅)

  • Kim, Taek Hyeon;Na, Hye-Sun
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.49-53
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    • 2014
  • A novel monomeric UV-absorber was prepared by the reaction of 2,4-dihydroxybenzophenone with N-4-chlorocarbonylphenylmaleimide in the presence of triethylamine. This reactive maleimide was grafted onto polypropylene (PP) by the thermal melt-processing in a mini-max-moulder. IR spectroscopic method was used for the quantitative determination of the extent of grafting of monomeric maleimide. To find the optimal reaction conditions, the dependence of reaction temperature and time and the concentration of monomeric UV-absorber was investigated on the grafting yields. The photooxidative effect of the grafted PP was evaluated in the weatherometer comparing to the PP mixed with UV-absorbers using the carbonyl index of IR spectrum. The grafted PP showed an excellent anti-photooxidative effect.