• Applied Chemistry for Engineering
• /
• v.20 no.4
• /
• pp.396-401
• /
• 2009

A micro-spherical activated carbon with meso-pore structure of 52~64% and particle diameter of $2{\sim}10{\mu}m$ was prepared for the improvement electrochemical performance of activated carbon as electrode material for electric double layer capacitor. Resorcinol-formaldehyde resin was used as a carbon source in this preparation. According to electrochemical analysis of EDLC using this activated a carbon with showing effects to reduce charge transfer resistance and to increase rate capability, it was found out that micro-spherical activated carbon could be a good method as well as a material for enhancing the performance of electric double layer capacitor.

• Restorative Dentistry and Endodontics
• /
• v.16 no.2
• /
• pp.1-17
• /
• 1991

The purpose of this study was to analyze the in vivo amalgam corrosion products qualitatively. 30 molars with large, intact amalgam restorations were selected. All the restorations were more than 5 years old. Twenty of the removed amalgams were embedded in acrylic resin block. The exposed surfaces of fifteen embedded amalgams were polished by amalgam polishing kit, and the rest were observed without polishing. The remaining 10 amalgams were fractured centrally and perpendiculary to the occlusal surface with a wire-cutter. After all specimens were cleaned ultrasonically in distilled water, each surface was examined under S.E.M. and E.D.A.X. (Energy Dispersive Micro X-ray Analyzer) to determine the morphology and chemical nature of the corrosion products. The following results were obtained: 1. The surfaces of the unpolished amalgam restorations were covered with thin amorphous layer of Sn-Ca-P-S complex with numerous cracks. 2. In the conventional amalgams, the major corrosion products were Sn-Cl phases however, tin oxide phases were also observed. 3. Only tin oxide phase was identified in the high copper amalgam, but it was less frequently observed than in the conventional amalgam. 4. It was easier to observe the corrosion product morphology in the fractured surfaces than in the polished ones. The morphologies of the corrosion product crystals looked like a stack of slightly bended plates in the Sn-Cl phases and polyhedra or polygonal prisms in the tin oxide phases.

• Journal of the Korean Ceramic Society
• /
• v.46 no.5
• /
• pp.528-533
• /
• 2009

High purity $\beta$-SiC powders were synthesized using sol-gel processing. TEOS and phenol resin were used as the starting material for the silicon source and carbon source, respectively. The process turned out to be capable of producing high purity SiC powder purity degree with 99.98 %. However, it was difficult to control the shape and size of $\beta$-SiC powders synthesized by sol-gel process. In this study, $\beta$-SiC powder with size of $1{\sim}5$ um an 30 nm were used as the seeds for $\beta$-SiC to control the $\beta$-SiC powder morphology. It was found that $\beta$-SiC powder seeds was effective to increase the powder average size of synthesized $\beta$-SiC using sol-gel process by acting as the preferred growing sites for $\beta$-SiC.

• Restorative Dentistry and Endodontics
• /
• v.4 no.1
• /
• pp.35-38
• /
• 1978

The purpose of this study was to measure micro-knoop hardness and coefficient of thermal expansion on composite resins (Epolite, Adaptic, Hipol and Compo T.) Four different type of composite resins were measured at the varying depth of 30, 60, 90, 150, 200, 400, 700 and 1000 micron from the surface to deep portion. The specimens were stored both in the air room temperature for 2 days, 30 days and in water at $37^{\circ}C$ for 30 days. Thermal expansions of specimens(4mm in diameter and 50mm in height) were measured in quartz tube dilatometer from $20^{\circ}$ to $70^{\circ}C$ The following results were obtained. 1. The hardness of superficial portion were lower than inner portion of resin. 2. The value of hardness obtained from the specimen stored in room temperature in the water at $37^{\circ}C$ for 30 days were lower than above described Cases. 3. The coefficient of thermal expansion of Adaptic had $29.75{\times}10^{-6}/^{\circ}C$, Hipol had $30{\times}10^{-6}/^{\circ}C$, Epolite had $39.85{\times}10^{-6}/^{\circ}C$ and Compo T had $36.95{\times}10^{-6}/^{\circ}C$.

• Restorative Dentistry and Endodontics
• /
• v.17 no.1
• /
• pp.206-213
• /
• 1992

The aim of this study was to compare the accuracy of radiographic diagnosis of secondary carious lesions adjacent to composite filling materials with different radiopacity. The level of radiopacity that is most compatible with the radiographic diagnosis of secondary caries was studied in a two part experiment. In the first part, the radiopacity of 6 posterior composites CBP, CF, HM, LF, PQ, P50), enamel and dentin were measured by desitometer and 6 posterior composites divided into 3 groups based on their level of radiopacity compared with enamel and dentin. In the seocnd part, class II composite fillings with or without secondary caries were made in extracted premolar and radiographs of the teeth were examined by 10 dentists to diagnose simulated carious lesion. The following results were obtained: 1. The radiopacity of 6 posterior composites varied between 1.76(PQ) and 6.78(P50)mm Al equivalent. 2. For 4 composites the radiopacity exeeded that of an equal thickness of enamel, and for two the radiopacity was lower than that of dentin. 3. The detection of secondary caries was facillitated when the radiopacity of a composite resin was similar to or slightly greater than that of enamel.

• Restorative Dentistry and Endodontics
• /
• v.24 no.1
• /
• pp.67-75
• /
• 1999

The use of composite restorative materials is established due to continuing improvements in the materials and restorative techniques. Composite resins are widely used for the restoration of cervical lesions because of esthetics, good physical properties and working time. There are several types of cavity design for class V composite resin filling, but inappropriate cavity form may affect bonding failure, microleakage and fracture during mastication. Cavity preparations for composite materials should be as conservative as possible. The extent of the preparation is usually determined by the size, shape, and location of the defect. The design of the cavity preparation to receive a composite restoration may vary depending on several factors. In this study, 5 types of class V cavity were prepared on each maxillary central incisor. The types are; 1) V-shape, 2) round(U) shape, 3) box form, 4) box form with incisal bevel and 5) box form with incisal bevel and grooves for axial line angles. After restoration, in order to observe the concentration of stress at bonding surfaces of teeth and restorations, developing a 2-dimensional finite element model of labiopalatal section in tooth, surrounding bone, periodontal ligament and gingiva, based on the measurements by Wheeler, loading force from direction of 45 degrees from lingual side near the incisal edge was applied. This study analysed Von Mises stress with SuperSap finite element analysis program(Algor Interactive System, Inc.). The results were as follows : 1. Stress concentration was prevalent at tooth-resin bonding surface of cervical side on each model. 2. In model 2 without line angle, stress was distributed evenly. 3. Preparing bevel eliminated stress concentration much or less at line angle. 4. Model with round-shape distributed stress concentration more evenly than box-type model with sharp line angle, therefore decreased possibility of fracture. 5. Adding grooves to line angles had no effect of decreasing stress concentration to the area.

• Restorative Dentistry and Endodontics
• /
• v.22 no.1
• /
• pp.428-446
• /
• 1997

Restorative procedures can lead to weakening tooth due to reduction and alteration of tooth structure. It is essential to prevent fractures to conserve tooth. The resistance to fracture of the restored tooth may be influenced by many factors, among these are the cavity dimension and the physical properties of the restorative material. The placement of direct composite resin restorations has generally been found to have a strengthening effect on the prepared teeth. It is the purpose of this investigation to study the relationship between the cavity isthmus and the fracture resistance of a tooth in composite resin restorations. In this study, MO cavity was prepared on maxillary first premolar. Three dimensional finite element models were made by serial photographic method and isthmus(1/4, 1/3, 1/2 of intercuspal distance) were varied. Two types of model(B and R model) were developed. B model was assumed perfect bonding between the restoration and cavity wall and R model was left unfilled. A load of 500N was applied vertically at the first node from the lingual slope of the buccal cusp tip. This study analysed the displacement, 1 and 2 direction normal stress and strain with FEM software ABAQUS Version 5.2 and hardware IRIS 4D/310 VGX Work-station. The results were as follows : 1. Displacement of buccal cusp in R model occurred and increased as widening of the cavity, and displacement in B model was little and not influenced by cavity width. 2. There was a significant decrease of stress resulting in increase of fracture resistance in B model when compared with R model. 3. With the increase of the isthmus width, B model showed no change in the stress and strain. In R model, the stress and strain increased both in the area of buccal-pulpal line angle and the buccal side of marginal ridge, therefore the possibility of crack increased. 4. The stress and strain were distributed evenly on the tooth in B model, but in R model, were concentrated on the buccal side of the distal marginal ridge and buccal-pulpal line angle, therefore the possibility of fracture increased.

• Restorative Dentistry and Endodontics
• /
• v.31 no.4
• /
• pp.300-311
• /
• 2006

The purpose of this study is to evaluate prospectively the effect of different bonding systems and retention grooves on the clinical performance of resin restorations in non-carious cervical lesions (NCCLs). Thirty-nine healthy adults who had at least 2 NCCLs in their premolar areas were included in this study. One hundred and fifty teeth were equally assigned to six groups: (A) Scotchbond Multi-Purpose (SBMP, 3M ESPE, St. Paul, MN, USA, 4th generation bonding system) without retention grooves; (B) SBMP with retention grooves; (C) BC Plus (Vericom Co., Anyang, Gyeonggido, Korea, 5th generation bonding system) without retention grooves; (D) BC Plus with retention grooves; (E) Adper Prompt (3M ESPE, Seefeld, Germany, 6th generation bonding system) without retention grooves; (F) Adper Prompt with retention grooves. All cavities were filled with a hybrid composite resin. Denfil (Vericom Co., Anyang, Gyeonggido, Korea) by one operator. Restorations were evaluated at baseline and at 6-month recall, according to the modified USPHS (United States Public Health Service) criteria. Additionally, clinical photographs were taken and epoxy resin replicas were made for SEM evaluation. At 6-month recall, there were some differences in the number of alpha ratings among the experimental groups. But, despite the differences in the number of alpha ratings, there was no significant difference among the 3 adhesive systems (p < 0.05). There was also no significant difference between the groups with or without mechanical retention (p < 0.05). Follow-ups for longer periods than 6 months are needed to verify the clinical performance of different bonding systems and retention grooves.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.27 no.4
• /
• pp.558-563
• /
• 2000

The lasers have been used in dentistry for more than 30 years and the application of lasers for drilling dental hard tissue has been investigated since the early developement of lasers. Recently, the Er:YAG laser was invented for hard tissue ablation. The Er:YAG laser, having a wavelength of 2.94um, is highly absorbed in both water and hydroxiapatite, leading to a very effective material for hard tissue removal by bursting off the solid tissue component that is, enamel and dentin are removed by the Er :YAG laser by water vaporization and microexplosion, without any melting of inorganic tissues. Therefore, the Er:YAG laser produced round craters with well defined margins and the surrounding tissues had no cracks and no charring. When used for cavity preparation, pulpal damage should not occur if hear buildup is minimized by careful selection of exposure parameters and by use of a water spray. The present study demonstrated that the Er:YAG laser cut the tooth substance adequately for composite resin restoration, without having undesirable side effects such as harmful effects on the pulp, discoloration or cracking etc. Also, the child patients were well cooperative during laser treatment mainly because of little noise, lesser vibration and minimal pain compared to conventional means of cavity preparation.

• Restorative Dentistry and Endodontics
• /
• v.29 no.6
• /
• pp.532-540
• /
• 2004

The aim of this study was to measure the cusp deflection during composite restoration for MOD cavity in premolar and to examine the influence of cavity dimension, C-factor and restoration method on the cusp deflection. Thirty extracted maxillary premolar were prepared to four different sizes of MOD cavity and divided into six groups. The width and depth of the cavity were as follows. Group 1; $1.5{\;}{\times}{\;}1{\;}mm$, Group 2; $1.5{\;}{\times}{\;}2{\;}mm$, Group 3; $3{\;}{\times}{\;}1{\;}mm$, and Group 4-6; $3{\;}{\times}{\;}2{\;}mm$ respectively. Group 1-4 were restored using bulk filling method with Z-250 composite. However, Group 5 was restored incrementally, and Group 6 was restored with an indirect resin inlay. The cusp deflection was recorded at the buccal and lingual cusp tips using LVDT probe for 10,000 seconds. The measured cusp deflections were compared between groups, and the relationship between the cube of the length of cavity wall/the cube of the thickness of cavity wall ($L^3/T^3$). C-factor and cusp deflection or % flexure ($100{\;}{\times}$ cuspal deflection / cavity width) was analyzed. The cusp deflection of Group 1-4 were $12.1{\;}\mu\textrm{m},{\;}17.2{\;}\mu\textrm{m},{\;}16.2{\;}\mu\textrm{m}{\;}and{\;}26.4{\;}\mu\textrm{m}$ respectively. The C-factor was related to the % flexure rather than the cusp deflection. There was a strong positive correlationship between the $L^3/T^3$ and the cusp deflection. The cusp deflection of Group 5 and 6 were $17.4{\;}\mu\textrm{m}{\;}and{\;}17.9{\;}\mu\textrm{m}$ respectively, which are much lower value than that of Group 4.