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Synthesis of anisotropic defective polyaniline/silver nanocomposites

  • Kamblea, Vaishali;Kodwania, Gunjan;Sridharkrishna, Ramdoss;Ankamwar, Balaprasad
    • Advances in nano research
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    • 제2권2호
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    • pp.111-119
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    • 2014
  • The chemical synthesis of anisotropic defective polyaniline/Ag composite (PANI/Ag) is explored using silver nitrate ($AgNO_3$) as the precursor material. This study provides a simple method for the formation of PANI/Ag nanocomposites at two different aniline concentrations $5{\mu}l$ (PANC5) and $10{\mu}l$ (PANC10). The composite PANC5 exhibits UV-Visible absorption peaks at 436 nm and 670 nm whereas, PANC10 exhibits absorption peaks at 446 nm and 697 nm. This shift is caused by the strong interaction between polyaniline and silver. The characterized FTIR peaks observed at around $3410cm^{-1}$ (PANC5) and $3420cm^{-1}$ (PANC10) was due to the N-H stretching vibrations. The appearance of a broad band instead of a sharp peak can be attributed due to the presence of a high concentration of N-H groups in the nanocomposite. The TEM images show that the sample contains defective spherical, truncated triangular and rod shaped particles. The results showed that the PANI/Ag nanocomposites are composed of nano-sized particles of 43-53 nm that contain Ag domains of 33-37 nm with polymer thickness 5.7-11.2 nm at two different aniline concentrations.

충격 신호 분석에 기반한 침식 지수 개발 (Estimation of Erosion Index Based on Impact Signal Analysis)

  • 히까르도 테노리오;권병혁;마르시아 모라에스;윤홍주
    • 한국전자통신학회논문지
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    • 제15권3호
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    • pp.543-552
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    • 2020
  • 이 연구는 브라질 북동부의 Maceió-Alagoas 지역에서 강우로 인한 토양의 침식 지수를 추정할 수 있는 알고리즘을 결정하는 것을 목적으로 한다. 2003년부터 2006년까지 10분 이상 지속된 680회의 강우 사례에서 수집한 분당 26,889개의 데이터 샘플은 우적 크기 분포에 따라 분류되었다. 종속 변수와 독립 변수로 구성된 방정식은 99%의 결정 계수로 침식지수를 추정한다. 최소 강우 강도와 침식도의 관계는 통계적 유의성으로 검증되었다.

Mediation Role of Satisfaction and Trust on Attitudinal Commitment and Relationship Quality

  • TRAN, Thi Trang;TRAN, Anh Tung;PHAM, Thi Ngan
    • The Journal of Asian Finance, Economics and Business
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    • 제7권10호
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    • pp.275-281
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    • 2020
  • This study aims to explore a new approach of relationship assessment by partially employing attitudinal commitment to measure the influence on perception of cooperation within the Vietnamese rice supply chains, which begins from commercial enterprises up to the retailers in the Vietnamese market. The quantitative research is first built around the measurement instruments for the constructs of relationship quality (RQ) and its dimensions; next, a questionnaire is designed; finally, we deal with sample issues and analyze the data to answer the research questions. The truncated sampling technique and Likert-scale survey is a suitable method for analyzing Vietnamese rice retailers and data collection. The preliminary test was conducted using SPSS Statistics; the main test was, then, carried out to evaluate the proposed model and test the hypotheses. Appropriately, the results point to a significant influence of attitudinal factors on trust and satisfaction. In addition, with the involvement of perceived trust and satisfaction, that combination showed the mediating effect between the attitudinal factors and the relationship quality. The ad-hoc analysis indicated the significant role of the two mediators. To be more specific, the high degree of trust and satisfaction has a positive impact on the formation of the relationship between participants in the sector.

비정규분포공정(非正規分布工程)에서 메디안특수관리도(特殊管理圖)의 모형설계(模型設計) (Design of Median Control Chart for Nonnormally Distributed Processes)

  • 신용백
    • 품질경영학회지
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    • 제15권2호
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    • pp.10-19
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    • 1987
  • Statistical control charts are useful tools to monitor and control the manufacturing processes and are widely used in most Korean industries. Many Korean companies, however, do not always obtain desired results from the traditional control charts by Shewhart such as the $\overline{X}$-chart, X-chart, $\widetilde{X}$-chart, etc. This is partly because the quality charterstics of the process are not distributed normally but are skewed due to the intermittent production, small lot size, etc. In the Shewhart $\overline{X}$-chart, which is the most widely used one in Korea, such skewed distributions make the plots to be inclined below or above the central line or outside the control limits although no assignable causes can be found. To overcome such shortcomings in nonnormally distributed processes, a distribution-free type of confidence interval can be used, which should be based on order statistics. This thesis is concerned with the design of control chart based on a sample median which is easy to use in practical situation and therefore properties for nonnormal distributions may be easily analyzed. Control limits and central lines are given for the more famous nonnormal distributions, such as Gamma, Beta, Lognormal, Weibull, Pareto, and Truncated-normal distributions.

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A cross-entropy algorithm based on Quasi-Monte Carlo estimation and its application in hull form optimization

  • Liu, Xin;Zhang, Heng;Liu, Qiang;Dong, Suzhen;Xiao, Changshi
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제13권1호
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    • pp.115-125
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    • 2021
  • Simulation-based hull form optimization is a typical HEB (high-dimensional, expensive computationally, black-box) problem. Conventional optimization algorithms easily fall into the "curse of dimensionality" when dealing with HEB problems. A recently proposed Cross-Entropy (CE) optimization algorithm is an advanced stochastic optimization algorithm based on a probability model, which has the potential to deal with high-dimensional optimization problems. Currently, the CE algorithm is still in the theoretical research stage and rarely applied to actual engineering optimization. One reason is that the Monte Carlo (MC) method is used to estimate the high-dimensional integrals in parameter update, leading to a large sample size. This paper proposes an improved CE algorithm based on quasi-Monte Carlo (QMC) estimation using high-dimensional truncated Sobol subsequence, referred to as the QMC-CE algorithm. The optimization performance of the proposed algorithm is better than that of the original CE algorithm. With a set of identical control parameters, the tests on six standard test functions and a hull form optimization problem show that the proposed algorithm not only has faster convergence but can also apply to complex simulation optimization problems.

신종발견확률의 편의보정 비모수 최우추정량에 관한 연구 (On asymptotics for a bias-corrected version of the NPMLE of the probability of discovering a new species)

  • 이주호
    • 응용통계연구
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    • 제6권2호
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    • pp.341-353
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    • 1993
  • 여러 개의 종으로 구성된 모집단에서 일정 크기의 표본을 추출하였을 경우, 다음차례에 뽑힐 종이 새로운 종이 될 조건부확률의 추정량으로서 가장 널리 사용되어 온 것은 Good(1953)이 경험적 베이지안 접근법을 사용하여 제안한 비모수추정량이다. Clayton과 Frees(1987)는 Good의 추정량에 대한 대안으로서 비모수최우추정량을 제안하고, 시뮬레이션을 통해 모집단이 비교적 불균일할 경우 자신들이 제안한 추정량이 Good의 추정량보다 평균제곱오차가 작음을 보여 주었고, Lee(1989)는 모집단이 균등분포에 비교적 가깝지 않은 절단기하분포를 따를 때 이를 점근적으로 규명하였다. 그러나 비모수최우추정량은 상당한 편의를 지니고 있는데, 본 연구에서는 이 편의의 일부를 보정한 새로운 추정량이 대부분의 모집단분포 형태에 있어 비모수최우추정량보다 평균제곱오차가 작으며, 모집단이 균일분포에 아주 가까운 경우를 제외하고는 Good의 추정량보다도 평균제곱오차가 작음을 점근적으로 규명하고, 이를 소표본 시뮬레이션을 통하여 확인하였다.

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Cell-SELEX Based Identification of an RNA Aptamer for Escherichia coli and Its Use in Various Detection Formats

  • Dua, Pooja;Ren, Shuo;Lee, Sang Wook;Kim, Joon-Ki;Shin, Hye-su;Jeong, OK-Chan;Kim, Soyoun;Lee, Dong-Ki
    • Molecules and Cells
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    • 제39권11호
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    • pp.807-813
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    • 2016
  • Escherichia coli are important indicator organisms, used routinely for the monitoring of water and food safety. For quick, sensitive and real-time detection of E. coli we developed a 2'F modified RNA aptamer Ec3, by Cell-SELEX. The 31 nucleotide truncated Ec3 demonstrated improved binding and low nano-molar affinity to E. coli. The aptamer developed by us out-performs the commercial antibody and aptamer used for E. coli detection. Ec3(31) aptamer based E. coli detection was done using three different detection formats and the assay sensitivities were determined. Conventional Ec3(31)-biotin-streptavidin magnetic separation could detect E. coli with a limit of detection of $1.3{\times}10^6CFU/ml$. Although, optical analytic technique, biolayer interferometry, did not improve the sensitivity of detection for whole cells, a very significant improvement in the detection was seen with the E. coli cell lysate ($5{\times}10^4CFU/ml$). Finally we developed Electrochemical Impedance Spectroscopy (EIS) gap capacitance biosensor that has detection limits of $2{\times}10^4CFU/mL$ of E. coli cells, without any labeling and signal amplification techniques. We believe that our developed method can step towards more complex and real sample application.

Location and shape of the mandibular lingula: Comparison of skeletal class I and class III patients using panoramic radiography and cone-beam computed tomography

  • Jung, Yun-Hoa;Cho, Bong-Hae;Hwang, Jae Joon
    • Imaging Science in Dentistry
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    • 제48권3호
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    • pp.185-190
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    • 2018
  • Purpose: The aim of this study was to compare the location and the shape of the mandibular lingula in skeletal class I and III patients using panoramic radiography and cone-beam computed tomography. Materials and Methods: The sample group included 190 skeletal class I patients and 157 class III patients. The location of the lingula in relation to the deepest point of the coronoid notch was classified into 3 types using panoramic radiographs. The shapes of the lingulae were classified into nodular, triangular, truncated, or assimilated types using cone-beam computed tomographic images. The data were analyzed using the chi-square test. Results: The tips of the lingulae were at the same level as the coronoid notch in 75.3% of skeletal class I patients and above the coronoid notch in 66.6% of class III patients. The positions of the lingulae in relation to the deepest point of the coronoid notch showed statistically significant differences between class I and class III patients. The most common shape was nodular, and the least common was the assimilated shape. Although this trend was not statistically significant, the triangular shape was more frequently observed in class III patients than in class I patients. Conclusion: The locations and the shapes of the mandibular lingulae were variable. Most of the lingulae were at the same level as the coronoid notch in skeletal class I patients and above the coronoid notch in skeletal class III patients. The nodular and assimilated-shaped lingulae were the most and the least prevalent, respectively.

비정규분포공정에서 매디안특수관리도의 모형설계와 적용연구 (Median Control Chart for Nonnormally Distributed Processes)

  • 신용백
    • 기술사
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    • 제20권3호
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    • pp.15-25
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    • 1987
  • Statistical control charts are useful tools to monitor and control the manufacturing processes and are widely used in most Korean industries. Many Korean companies, however, do not always obtain desired results from the traditional control charts by Shewhart such as the X-chart, X-chart, X-chart, etc. This is partly because the quality charterstics of the process are not distributed normally but are skewed due to the intermittent production, small lot size, etc. In Shewhart X-chart, which is the most widely used one in Korea, such skewed distributions make the plots to be inclined below or above the central line or outside the control limits although no assignable causes can be found. To overcome such shortcomings in nonnormally distributed processes, a distribution-free type of confidence interval can be used, which should be based on order statistics. This thesis is concerned with the design of control chart based on a sample median which is easy to use in practical situation and therefore properties for nonnormal distributions may be easily analyzed. Control limits and central lines are given for tile more famous nonnormal distributions, such as Gamma, Beta, Lognormal, Weibull, Pareto, Truncated-normal distributions. Robustness of the proposed median control chart is compared with that of the X-chart, the former tends to be superior to the latter as the probability distribution of the process becomes more skewed. The average run length to detect the assignable cause is also compared when the process has a Normal or a Gamma distribution for which the properties of X are easy to verify, the proposed chart is slightly worse than the X-chart for the normally distributed product but much better for Gamma-distributed products. Average Run Lengths of the other distributions are also computed. To use the proposed control chart, the probability distribution of the process should be known or estimated. If it is not possible, the results of comparison of the robustness force us to use the proposed median control chart based on a normal distribution. To estimate the distribution of the process, Sturge's formula is used to graph the histogram and the method of probability plotting, $X^2$-goodness of fit test and Kolmogorov-Smirnov test, are discussed with real case examples. A comparison of the propose4 median chart and the X chart was also performed with these examples and the median chart turned out to be superior to the X-chart.

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비정규분포공정에서 메디안특수관리도 통용모형설정에 관한 실증적 연구(요약) (Median Control Chart for Nonnormally Distributed Processes)

  • 신용백
    • 산업경영시스템학회지
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    • 제10권16호
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    • pp.101-106
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    • 1987
  • Statistical control charts are useful tools to monitor and control the manufacturing processes and are widely used in most Korean industries. Many Korean companies, however, do not always obtain desired results from the traditional control charts by Shewhart such as the $\bar{X}$-chart, $\bar{X}$-chart, $\bar{X}$-chart, etc. This is partly because the quality charterstics of the process are not distributed normally but are skewed due to the intermittent production, small lot size, etc. In Shewhart $\bar{X}$-chart. which is the most widely used one in Kora, such skewed distributions make the plots to be inclined below or above the central line or outside the control limits although no assignable causes can be found. To overcome such shortcomings in nonnormally distributed processes, a distribution-free type of confidence interval can be used, which should be based on order statistics. This thesis is concerned with the design of control chart based on a sample median which is easy to use in practical situation and therefore properties for nonnormal distributions may be easily analyzed. Control limits and central lines are given for the more famous nonnormal distributions, such as Gamma, Beta, Lognormal, Weibull, Pareto, Truncated-normal distributions. Robustness of the proposed median control chart is compared with that of the $\bar{X}$-chart; the former tends to be superior to the latter as the probability distribution of the process becomes more skewed. The average run length to detect the assignable cause is also compared when the process has a Normal or a Gamma distribution for which the properties of X are easy to verify, the proposed chart is slightly worse than the $\bar{X}$-chart for the normally distributed product but much better for Gamma-distributed products. Average Run Lengths of the other distributions are also computed. To use the proposed control chart, the probability distribution of the process should be known or estimated. If it is not possible, the results of comparison of the robustness force us to use the proposed median control chart based oh a normal distribution. To estimate the distribution of the process, Sturge's formula is used to graph the histogram and the method of probability plotting, $\chi$$^2$-goodness of fit test and Kolmogorov-Smirnov test, are discussed with real case examples. A comparison of the proposed median chart and the $\bar{X}$ chart was also performed with these examples and the median chart turned out to be superior to the $\bar{X}$-chart.

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