• Title/Summary/Keyword: Trapping characteristics

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Design of Single Ion Conductive Solid Polymer Electrolytes Utilizing the Characteristics of the Boron Atom

  • Matsumi, Noriyoshi;Ohno, Hiroyuki
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.275-275
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    • 2006
  • A series of organoboron polymer electrolytes were prepared and their ion conductive characteristics was investigated in detail. Alkylborane type polymer electrolytes prepared by hydroboration polymerization exhibited improve lithium transference number due to efficient anion trapping of alkylborane unit. A lithium borate type polymer/salt hybrid was also successfully prepared by dehydrocoupling polymerization of lithium mesitylhydrorate. Ionic conductivity of single ion conductive polymer/salt hybrid was further improved in the case of comb like polymer/boron stabilized imido anion hybrid prepared via polymer reaction of poly(organoboron halide) with hexylamine and PEO monomethylether and subsequent neutralization with lithium hydride.

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Degradation Characteristics of Hot-Electron-Induced p-MOSFET's GateOxide Thickness Variations by Stress (스트레스에 의한 핫-전자가 유기된 p-MOSFET의 게이트 산화막 두께 변화의 열화의 특성 분석)

  • Yong Jae Lee
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.1
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    • pp.77-83
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    • 1994
  • Characteristics of hot-electron-induced degradation by AC, DC was investigated for p-MOSFET's(W/L=25/l$\mu$m) with sub-10nm RTP-CVD gate oxides. It was confirmed that the surface channel p-MOSFET of a thinner gate oxide shows less degradation. Mechanisms for this effect were analyzed using a simple MOS Device degradation model. It was found that the number of generated electron traps(fixed charge) is determined by the amount of peak gate current, dependent of the gate oxide thickness, and the major cause of the smaller degradation in the thinner gate oxide devices is the lower hot electron trapping carriers.

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A Study on the Fabrication and Electromagnetic Characteristics of High Tc Superconductor Using Pyrosis method for Electrical Equipment (열분해법에 의한 전력기기용 고온 초전도체의 합성 기술 및 전기 자기적 특성)

  • Lee, Sang-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.10
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    • pp.453-456
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    • 2005
  • We have fabricated superconducting ceramics by chemical process. A high Tc superconducting with a nominal composition of YBaCuO was prepared by the pyrolysis method. The electromagnetic properties in YBaCuO superconductor was studied. In the measurement of current-voltage characteristics, a voltage across the superconducting sample was observed on applying an external magnetic field. The voltage increases with increase in applied magnetic flux, but it becomes constant at about 10$^{-2}$T. The voltage continues to appear the removal of the magnetic field. The appearance of the voltage is ascribed to the trapping of magnetic flux. Depending on the direction of applied magnetic flux less than 2.5$\times$10$^{-5}$ T, the voltage in the magnetized sample increases or decreases.

A Study on the Electric Characteristics of High Tc Superconductor (전력기기용 초전도의 전기적 특성)

  • Lee, Sang-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.10
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    • pp.481-484
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    • 2006
  • The electric properties in YBCO superconductor was studied. In the measurement of current-voltage characteristics, a voltage across the superconducting sample was observed on applying an external magnetic field. The voltage increases with increase in applied magnetic flux, but it becomes constant at about $10^{-2}T$. The voltage continues to appear the removal of the magnetic field. The appearance of the voltage is ascribed to the trapping of magnetic flux. Depending on the direction of applied magnetic flux less than $2.5{\times}10^{-5}T$, the voltage in the magnetized sample increases or decreases.

Effect of Post Annealing in Oxygen Ambient on the Characteristics of Indium Gallium Zinc Oxide Thin Film Transistors

  • Jeong, Seok Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.10
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    • pp.648-652
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    • 2014
  • We have investigated the effect of electrical properties of amorphous InGaZnO thin film transistors (a-IGZO TFTs) by post thermal annealing in $O_2$ ambient. The post-annealed in $O_2$ ambient a-IGZOTFT is found to be more stable to be used for oxide-based TFT devices, and has better performance, such as the on/off current ratios, sub-threshold voltage gate swing, and, as well as reasonable threshold voltage, than others do. The interface trap density is controlled to achieve the optimum value of TFT transfer and output characteristics. The device performance is significantly affected by adjusting the annealing condition. This effect is closely related with the modulation annealing method by reducing the localized trapping carriers and defect centers at the interface or in the channel layer.

Geomorphological Characteristics and OSL Ages of the Moraeul dune in Daechoengdo Island, South Korea (대청도 모래울 사구의 지형 특성과 OSL 연대)

  • Choi, Kwang Hee
    • Journal of The Geomorphological Association of Korea
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    • v.27 no.4
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    • pp.1-11
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    • 2020
  • Coastal dunes play an important role in coastal defense. The Moraeul dune in Daecheongdo Island is representative in this regard. However, there is little knowledge, concerning the morphology, grain size, and formation timing of the dune. This study investigated the geomorphological characteristics of the Moraeul dune using topographic surveys, grain size analyses, and OSL dating. The dune was classified as 'single accreted foredune', which was developed under dense vegetation cover and efficient sand trapping. The dune consisted of fine to medium sand with 1.6Φ of mean grain size, and was covered with pine trees (> 100 years old). The samples from the upper part of the dune yielded quartz OSL ages ranging 0.5 ~ 0.7 ka. Therefore, it is likely that the dune developed at least before the Little Ice Age and became what it is today about one century ago.

Numerical Study of a Novel Bi-focal Metallic Fresnel Zone Plate Having Shallow Depth-of-field Characteristics

  • Kim, Jinseob;Kim, Juhwan;Na, Jeongkyun;Jeong, Yoonchan
    • Current Optics and Photonics
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    • v.2 no.2
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    • pp.147-152
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    • 2018
  • We propose a novel bi-focal metallic Fresnel zone plate (MFZP) with shallow depth-of-field (DOF) characteristics. We design the specific annular slit patterns, exploiting the phase-selection-rule method along with the particle swarm optimization algorithm, which we have recently proposed. We numerically investigate the novel characteristics of the bi-focal MFZP in comparison with those of another bi-focal MFZP having equivalent functionality but designed by the conventional multi-zone method. We verify that whilst both bi-focal MFZPs can produce dual focal spots at $15{\mu}m$ and $25{\mu}m$ away from the MFZP plane, the former exhibits characteristics superior to those of the latter from the viewpoint of axial resolution, including the axial side lobe suppression and axial DOF shallowness. We expect the proposed bi-focal MFZP can readily be fabricated with electron-beam evaporation and focused-ion-beam processes and further be exploited for various applications, such as laser micro-machining, optical trapping, biochemical sensing, confocal sensing, etc.

Preparation and in Vitro Release of Melatonin-Loaded Multivalent Cationic Alginate Beads

  • Lee, Beom-Jin;Min, Geun-Hong;Kim, Tae-Wan
    • Archives of Pharmacal Research
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    • v.19 no.4
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    • pp.280-285
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    • 1996
  • The sustained release dosage form which delivers melatonin (MT) in a circadian fashion over 8 h is of clinical value for those who have disordered circadian rhythms because of its short halflife. The purpose of this study was to evaluate the gelling properties and release characteristics of alginate beads varying multivalent cationic species $(Al^{+++}, \; Ba^{++}, \; Ca^{++}, \; Mg^{++}, \; Fe^{+++}, \; Zn^{++})$. The surface morphologies of Ca- and Ba-alginate beads were also studied using scanning electron microscope (SEM). MT, an indole amide pineal hormone was used as a model drug. The $Ca^{++}, \; Ba^{++}, \; Zn^{++}, \; Al^{++}\; and\; Fe^{+++}\; ions\; except\; Mg^{++}$ induced gelling of sodium alginate. The strength of multivalent cationic alginate beads was as follows: $Al^{+++}\llFe^{+++} the induced hydrogel beads were very fragile and less spherical. Fe-alginate beads were also fragile but stronger compared to Al-alginate beads. Ba-alginate beads had a similar gelling strength but was less spherical when compared to Ca-alginate beads. Zn-alginate beads were weaker than Ca- and Ba-alginate beads. Very crude and rough crystals of Ba- and Ca-alginate beads at higher magnifications were observed. However, the type and shape of rough crystals of Ba- and Ca-alginate beads were quite different. No significant differences in release profiles from MT-loaded multivalent cationic alginate beads were observed in the gastric fluid. Most drugs were continuously released upto 80% for 5 h, mainly governed by the passive diffusion without swelling and disintegrating the alginate beads. In the intestinal fluid, there was a significant difference iq the release profiles of MT-loaded multivalent cationic alginate beads. The release rate of Ca-alginate beads was faster when compared to other multivalent cationic alginate beads and was completed for 3 h. Ba-alginate beads had a very long lag time (7 h) and then rapidly released thereafter. MT was continuously released from Feand Zn-alginate beads with initial burstout release. It is assumed that the different release rofiles of multivalent cationic alginate beads resulted from forces of swelling and disintegration of alginate beads in addition to passive diffusion, depending on types of multivalent ions, gelling strength and drug solubility. It was estimated that 0.2M $CaCl_2$ concentration was optimal in terms of trapping efficiency of MT and gelling strength of Ca-alginate beads. In the gastric fluid, Ca-alginate beads gelled at 0.2 M $CaCl_2$ concentration had higher bead strength, resulting in the most retarded release when compared to other concentrations. In the intestinal fluid, the decreased release of Ca-alginate beads prepared at 0.2 M $CaCl_2$ concentration was also observed. However, release profiles of Ca-alginate beads were quite similar regardless of $CaCl_2$ concentration. Either too low or high $CaCl_2$ concentrations may not be useful for gelling and curing of alginate beads. Optimal $CaCl_2$ concentrations must be decided in terms of trapping efficiency and release and profiles of drug followed by curing time and gelling strength of alginate beads.

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Analysis of Positive Bias Temperature Instability Characteristic for Nano-scale NMOSFETs with La-incorporated High-k/metal Gate Stacks (La이 혼입된 고유전체/메탈 게이트가 적용된 나노 스케일 NMOSFET에서의 PBTI 신뢰성의 특성 분석)

  • Kwon, Hyuk-Min;Han, In-Shik;Park, Sang-Uk;Bok, Jung-Deuk;Jung, Yi-Jung;Kwak, Ho-Young;Kwon, Sung-Kyu;Jang, Jae-Hyung;Go, Sung-Yong;Lee, Weon-Mook;Lee, Hi-Deok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.3
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    • pp.182-187
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    • 2011
  • In this paper, PBTI characteristics of NMOSFETs with La incorporated HfSiON and HfON are compared in detail. The charge trapping model shows that threshold voltage shift (${\Delta}V_{\mathrm{T}}$) of NMOSFETs with HfLaON is greater than that of HfLaSiON. PBTI lifetime of HfLaSiON is also greater than that of HfLaON by about 2~3 orders of magnitude. Therefore, high charge trapping rate of HfLaON can be explained by higher trap density than HfLaSiON. The different de-trapping behavior under recovery stress can be explained by the stable energy for U-trap model, which is related to trap energy level at zero electric field in high-k dielectric. The trap energy level of two devices at zero electric field, which is extracted using Frenkel-poole emission model, is 1,658 eV for HfLaSiON and 1,730 eV for HfLaON, respectively. Moreover, the optical phonon energy of HfLaON extracted from the thermally activated gate current is greater than that of HfLaSiON.

Characteristics of Optimized Analytical Method of Hydrogen Cyanide in Cigarette Mainstream Smoke by Using Continuous Flow Analyzer(CFA) (Continuous Flow Analyzer(CFA)를 이용한 담배 주류연 중 Hydrogen Cyanide(HCN)의 최적 분석방법 구명)

  • Na, Seung-Ju;Eo, Sung-Je;Kim, Do-Yeon;Bock, Jin-Young;Hwang, Keon-Joong
    • Journal of the Korean Society of Tobacco Science
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    • v.31 no.1
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    • pp.39-44
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    • 2009
  • Hydrogen cyanide (HCN) is present in both the particulate and vapor phase of cigarette mainstream smoke. It is one of the 44 harmful substances on Hoffmann's list and is known to be a major ciliatoxic agent in cigarette mainstream smoke. Typically the determination of HCN in cigarette mainstream smoke has been done through colorimetric and electrochemical techniques, such as UV-spectrophotometry (UV), continuous flow analyzer (CFA), ion chromatography (IC) and capillary GC-ECD. In particular, CFA commonly has been using analysis hydrogen cyanide in cigarette smoke and the basic principle is pyridine-pyrazolone reaction. In this study, the more optimized analytical method is suggested isonicotinic acid-pyrazolone reaction method than previous pyridine-pyrazolone reaction method, a commonly used method for the determination of cyanide in water and air, by CFA. Sample collection was optimized by trapping particulate and vapor phase of smoke separately. The optimum NaOH concentration of the trapping solution was shown to be 0.2 M. HCN was stable up to 6 hours in this concentration but only 3 hours in 0.1 M solution. The sensitivity of this method was fairly good and it might be used in analysis of HCN in cigarette mainstream smoke.