• Title/Summary/Keyword: Trapping Efficiency

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Optimization of $p^+$ seeding layer for thin film silicon solar cell by liquid phase epitaxy

  • Lee, Eun-Joo;Lee, Soo-Hong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.6
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    • pp.260-262
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    • 2005
  • Thickness optimization of heavily doped p-type seeding layer was studied to improve performance of thin film silicon solar cell. We used liquid phase epitaxy (LPE) to grow active layer of $25{\mu}m$ thickness on $p^+$ seeding layer. The cells with $p^+$ seeding layer of $10{\mu}m\;to\;50{\mu}m$ thickness were fabricated. The highest efficiency of a cell is 12.95%, with $V_{oc}=633mV,\;J_{sc}=26.5mA/cm^2$, FF = 77.15%. The $p^+$ seeding layer of the cell is $20{\mu}m$ thick. As thicker seeding layer than $20{\mu}m$, the performance of the cell was degraded. The results demonstrate that the part of the recombination current is due to the heavily doped seeding layer. Thickness of heavily doped p-type seeding layer was optimized to $20{\mu}m$. The performance of solar cell is expected to improve with the incorporation of light trapping as texturing and AR coating.

Application of Nanoroll-Type Ag/g-C3N4 for Selective Conversion of Toxic Nitrobenzene to Industrially-Valuable Aminobenzene

  • Devaraji, Perumal;Jo, Wan-Kuen
    • Journal of Environmental Science International
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    • v.29 no.1
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    • pp.95-108
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    • 2020
  • Silver nanoparticles were loaded onto g-C3N4 (CN) with a nanoroll-type morphology (Ag/CN) synthesized using a co-polymerization method for highly selective conversion of toxic nitrobenzene to industrially-valuable aminobenzene. Scanning electron microscopy and high-resolution transmission electron microscopy (HRTEM) images of Ag/CN revealed the generation of the nanoroll-type morphology of CN. Additionally, HRTEM analysis provided direct evidence of the generation of a Schottky barrier between Ag and CN in the Ag/CN nanohybrid. Photoluminescence analysis and photocurrent measurements suggested that the introduction of Ag into CN could minimize charge recombination rates, enhancing the mobility of electrons and holes to the surface of the photocatalyst. Compared to pristine CN, Ag/CN displayed much higher ability in the photocatalytic reduction of nitrobenzene to aminobenzene, underscoring the importance of Ag deposition on CN. The enhanced photocatalytic performance and photocurrent generation were primarily ascribed to the Schottky junction formed at the Ag/CN interface, greater visible-light absorption efficiency, and improved charge separation associated with the nanoroll morphology of CN. Ag would act as an electron sink/trapping center, enhancing the charge separation, and also serve as a good co-catalyst. Overall, the synergistic effects of these features of Ag/CN improved the photocatalytic conversion of nitrobenzene to aminobenzene.

Multi-crystalline Silicon Solar Cell with Reactive Ion Etching Texturization

  • Park, Seok Gi;Kang, Min Gu;Lee, Jeong In;Song, Hee-eun;Chang, Hyo Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.419-419
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    • 2016
  • High efficiency silicon solar cell requires the textured front surface to reduce reflectance and to improve the light trapping. In case of mono-crystalline silicon solar cell, wet etching with alkaline solution is widespread. However, the alkali texturing methods are ineffective in case of multi-crystalline silicon wafer due to grain boundary of random crystallographic orientation. The acid texturing method is generally used in multi-crystalline silicon wafer to reduce the surface reflectance. However the acid textured solar cell gives low short-circuit current due to high reflectivity while it improves the open-circuit voltage. To reduce the reflectivity of multi-crystalline silicon wafer, double texturing method with combination of acid and reactive ion etching is an attractive technical solution. In this paper, we have studied to optimize RIE experimental condition with change of RF power (100W, 150W, 200W, 250W, 300W). During experiment, the gas ratio of SF6 and O2 was fixed as 30:10.

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DYE SENSITIZED SOLAR CELLS WITH HIGH PHOTO-ENERGY CONVERSION -CONTROLL OF NANO-PARTICLE SURFACES-

  • Hayase, Shuzi
    • Proceedings of the KIEE Conference
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    • 2006.04b
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    • pp.52-56
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    • 2006
  • Some of factors affecting photo-conversion efficiency of dye sensitized solar cells (DSCs) are discussed in terms of $TiO_2$ electrodes. The first topic is on the surface modification of $TiO_2$ nano-particles, which is associated with electron traps on the surface of $TiO_2$ nano-particles. The surface is modified with dye molecules under pressurized $CO_2$ atmosphere to increase the surface coverage of $TiO_2$ nano-particles with dye molecules. This increases Jsc because of an increase in the amount of dye molecules and a decrease in the amount of trapping sites on $TiO_2$ nano-particles. In addition, the decrease in the amount of trap sites increases Voc because decreases in Voc are brought about by the recombination of $I_2$ molecules with electrons trapped on the $TiO_2$ surfaces. Selective staining for tandem cells is proposed. The second topic is on the contact between a $SnO_2$/F transparent conductive layer (TCL) and nano-particles. Polishing the TCL surfaces with silica nano-particles increases the contact, resulting in Jsc increases. The third topic is the fabrication of ion-paths in $TiO_2$ layers. Electro-spray coating of $TiO_2$ nano-particles onto TCL is shown to be effective for fabricating ion-paths in $TiO_2$ layers, which increases Jsc.

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OPTIMIZATION OF $P^+$ SEEDING LAYER FOR THIN FILM SILICON SOLAR CELL (결정질 실리콘 박막 태양전지의 $P^+$ 씨앗층 형성 최적화에 관한 연구)

  • Lee, Eun-Joo;Lee, Soo-Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.168-171
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    • 2005
  • Thickness optimization of heavily doped p-type seeding layer was studied to improve performance of thin film silicon solar cell. We used liquid phase epitaxy (LPE) to grow active layer of $25{\MU}m$ thickness on p+ seeding layer. The cells with p+ seeding layer of $10{\mu}m\;to\;50{\mu}m$ thickness were fabricated. The highest efficiency of a cell is $12.95\%$, with Voc=633mV, $Jsc=26.5mA/cm^2,\;FF=77.15\%$. The $P^+$ seeding layer of the cell is $20{\mu}m$, thick. As thicker seeding layer than $20{\mu}m$, the performance of the cell was degraded. The results demonstrate that the part of the recombination current is due to the heavily doped seeding layer. Thickness of heavily doped p-type seeding layer was optimized to $20{\mu}m$. The performance of solar cell is expected to improve with the incorporation of light trapping as texturing and AR coating.

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Response of Ussur Brown Katydid, Paratlanticus ussuriensis to Light-Emitting Diodes(LED) (LED 광원에 대한 갈색여치의 행동반응)

  • Jung, Myung-Pyo;Bang, Hea-Son;Kim, Myung-Hyun;Han, Min-Su;Na, Young-Eun;Kang, Kee-Kyung;Lee, Deog-Bae
    • Korean Journal of Environmental Agriculture
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    • v.28 no.4
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    • pp.468-471
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    • 2009
  • This study was conducted to determine the phototactic response of Paratlanticus ussuriensis to different wavelength of light by the use of LEDs and to provide a basic information for developing an improved trap with the longer trapping efficiency to control environment-friendly this katydid. P. ussuriensis were attracted to the single LED light source, especially, blue and white. For the multiple LED light sources, the movement of P. ussuriensis was not significantly different among LED-light bands. Overall, P. ussuriensis had a tendency to move to light source although they were not attracted to a specific wavelength of light. These methods may be used as information for conducting a phototactic response of other insects.

A Preliminary Study on Changes in Macrobenthic Assemblages in the Fenced Experimental Plots for Restoring Tidal Marsh, Hogok-ri Tidal Flat, West Coast of Korea

  • Koo, Bon-Joo;Je, Jong-Geel
    • Ocean and Polar Research
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    • v.24 no.1
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    • pp.63-71
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    • 2002
  • This preliminary study on the changes of macrobenthic assemblages in experimental sediment fences was conducted as a part of tidal marsh restoration project. Intertidal sediment fences were designed to increase the efficiency of trapping sediments on unvegetated tidal flats in order to raise sediment elevation and to allow colonization of intertidal vegetation. Although increment of soil surface level was not observed over the first three months of the study, it was possible to obtain some effects of the sediment fence. Three months later, the particle sizes of the surface sediment at experimental plots became much finer compared to unfenced areas on the natural mudflats located in the same tide level as that of the plots. The difference was much greater on the plot with drainage canals than on the plot without ones. Species diversity of the experimental plots became much higher than that of natural sites. Perinereis aibuhitensis and Glauconome chinensis which were absent from initial community appeared with high density in the plot with drainage canals. Those species were significantly different in abundance between the experimental plot and the natural mudflat. Changes in species composition were not detected in another experimental plot without drainage canals.

Pore Structure Modification and Characterization of Porous Cordierite with Chemical Vapor Infiltration (CVI) SiC Whisker (화학증착 탄화규소 휘스커에 의한 다공성 코디어라이트의 기공구조 개질 및 특성평가)

  • Kim, Ik-Whan;Kim, Jun-Gyu;Lee, Hwan-Sup;Choi, Doo-Jin
    • Journal of the Korean Ceramic Society
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    • v.45 no.2
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    • pp.132-137
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    • 2008
  • The main purpose of this study is enhancing the filtering efficiency, performance and durability of filter by growing SiC whiskers on cordierite honeycomb substrate. The experiment was performed by Chemical Vapor Infiltration (CVI) in order to control pore morphology of substrate. Increasing the mechanical strength of porous substrate is one of important issues. The formation of "networking structure" in the pore of porous substrate increased mechanical strength. The high pressure gas injection to the specimen showed that a little of whiskers were separated from substrate but additional film coating enhanced the stability of whisker at high pressure gas injection. Particle trap test was performed. More nano-particle was trapped by whisker growth at the pore of substrate. Therefore it is expected that the porous cordierite which deposited the SiC whisker will be the promising material for the application as filter trapping the nano-particles.

Synthesis and Characterization of a Ceria Based Composite Electrolyte for Solid Oxide Fuel Cells by an Ultrasonic Spray Pyrolysis Process (초음파분무 열분해법을 이용한 고체산화물 연료전지용 세리아계 복합체 전해질의 제조 및 특성)

  • Lee, Young-In;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.222-228
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    • 2014
  • Much research into fuel cells operating at a temperature below $800^{\circ}C$. is being performed. There are significant efforts to replace the yttria-stabilized zirconia electrolyte with a doped ceria electrolyte that has high ionic conductivity even at a lower temperature. Even if the doped ceria electrolyte has high ionic conductivity, it also shows high electronic conductivity in a reducing environment, therefore, when used as a solid electrolyte of a fuel cell, the powergeneration efficiency and mechanical properties of the fuel cell may be degraded. In this study, gadolinium-doped ceria nanopowder with $Al_2O_3$ and $Mn_2O_3$ as a reinforcing and electron trapping agents were synthesized by ultrasonic pyrolysis process. After firing, their microstructure and mechanical and electrical properties were investigated and compared with those of pure gadolinium-doped ceria specimen.

Study on Improving Surface Structure with Changing RF Power Conditions in RIE (reactive ion etching) (반응성 이온 건식식각에서 RF Power 변화에 따른 표면 조직화 개선 연구)

  • Park, Seok-Gi;Lee, Jeong In;Kang, Min Gu;Kang, Gi-Hwan;Song, Hee-eun;Chang, Hyo Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.8
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    • pp.455-460
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    • 2016
  • A textured front surface is required in high efficiency silicon solar cells to reduce reflectance and to improve light trapping. Wet etching with alkaline solution is usually applied for mono crystalline silicon solar cells. However, alkali texturing method is not appropriate for multi-crystalline silicon wafers due to grain boundary of random crystallographic orientation. Accordingly, acid texturing method is generally used for multi-crystalline silicon wafers to reduce the surface reflectance. To reduce reflectivity of multi-crystalline silicon wafers, double texturing method with combination of acid and reactive ion etching is an attractive technical solution. In this paper, we have studied to optimize RIE condition by different RF power condition (100, 150, 200, 250, 300 W).