• Title/Summary/Keyword: Trap system

Search Result 308, Processing Time 0.031 seconds

Preparation and Characterization of Sulfonated Poly (Arylene Ether Sulfone) Random Copolymer-Polyolefin Pore-filling Separators with Metal Ion Trap Capability for Li-ion Secondary Battery (리튬이온 이차전지용 금속이온 선택성 술폰화 폴리아릴렌에테르술폰 공중합체-폴리올레핀 함침격리막 제조 및 특성)

  • Jeong, Yeon Tae;Ahn, Juhee;Lee, Chang Hyun
    • Membrane Journal
    • /
    • v.26 no.4
    • /
    • pp.310-317
    • /
    • 2016
  • Lithium ion secondary battery (LISB) is an energy conversion system operated via charging-discharging cycle based on Lithium ion migration. LISB has a lot of advantages such as high energy density, low self-discharge rate, and a relatively high lifetime. Recently, increasing demands of electric vehicles have been encouraging the development of LISB with high capacity. Unfortunately, it causes some critical safety issues. It includes dendrite formation on negative electrode, resulting in electric shortage problems and battery explosion. Also, the elevated temperatures occurred during the LISB operation induces thermal shrinkage of polyolefin (e.g., polyethylene and polypropylene) separators. Consequently, the low thermal stability leads to decay of LISB performances and the reduction of lifetime. In this study, sulfonated poly (arylene ether sulfone) (SPAES) random copolymers were used as key materials to prepare polyolefin pore-filling separator. The resulting separators were evaluated in the term of metal ion chelation capability associated with dendrite formation, $Li^+$ ion conductivity and thermal durability.

The study on characteristics and fabrications of ferroelectric $LiNbO_3$ thin films using RF sputtering (RF스퍼터링법을 이용한 강유전체 $LiNbO_3$ 박막의 제작과 특성연구)

  • Choi, Y.S.;Jung, S.M.;Choi, S.W.;Yi, J.
    • Proceedings of the KIEE Conference
    • /
    • 1998.07d
    • /
    • pp.1352-1354
    • /
    • 1998
  • $LiNbO_3$ transistor showed relatively stable characteristic, low interface trap density, and large remanent polarization. This paper reports ferroelectric $LiNbO_3$ thin films grown directly on p-type Si(100) substrates by 13.56 MHz rf magnetron sputtering system for FRAM applications. To take advantage of low temperature requirement for growing films, we deposited $LiNbO_3$ films lower than $300 ^{\circ}C$. RTA(Rapid Thermal Anneal) treatment was performed for as-deposited films in an oxygen atmosphere at $600^{\circ}C$ for 60 sec. We learned from X-ray diffraction that the RTA annealed films were changed from amorphous to poly-crystalline $LiNbO_3$ which exhibited (012), (015), and (022) orientations. The I-V characteristics of $LiNbO_3$ films before and after anneal treatment showed that RTA improved the leakage current of films. The leakage current density of films decreased from $10^{-5}$ to $10^{-7} A/cm^2$ at room temperature measurement. Breakdown electric field of the films exhibited higher than 500 kV/cm. The C-V curves showed the clockwise hysteresis represents ferroelectric switching characteristics. From C-V curves, we calculated dielectric constant of thin film $LiNbO_3$ as 27.5 which is close to that of bulk value.

  • PDF

Analysis of a.c. Characteristics in ZnO-Bi2O3Cr2O3 Varistor using Dielectric Functions (유전함수를 이용한 ZnO-Bi2O3Cr2O3 바리스터의 a.c. 특성 분석)

  • Hong, Youn-Woo;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.23 no.5
    • /
    • pp.368-373
    • /
    • 2010
  • In this study, we have investigated the effects of Cr dopant on the bulk trap levels and grain boundary characteristics of $Bi_2O_3$-based ZnO (ZB) varistor using admittance spectroscopy and dielectric functions (such as $Z^*,\;Y^*,\;M^*,\;{\varepsilon}^*$, and $tan{\delta}$). Admittance spectra show more than two bulk traps of $Zn_i$ and $V_o$ probably in different ionization states in ZnO-$Bi_2O_3-Cr_2O_3$ (ZBCr) system. Three kinds of temperature-dependant activation energies ($E_{bt}'s$) were calculated as 0.11~0.14 eV of attractive coulombic center, 0.16~0.17 eV of $Zn_{\ddot{i}}$, and 0.33 eV of $V_o^{\cdot}$ as dominant bulk defects. The grain boundaries of ZBCr could be electrochemically divided into two types as a sensitive to ambient oxygen i.e. electrically active one and an oxygen-insensitive i.e. electrically inactive one. The grain boundaries were electrically single type under 460 K (equivalent circuit as parallel $R_{gb1}C_{gb1}$) but separated as double one ($R_{gb1}C_{gb1}-R_{gb2}C_{gb2}$) over 480 K. It is revealed that the dielectric functions are very useful tool to separate the overlapped bulk defect levels and to characterize the electrical properties of grain boundaries.

Two vivax malaria cases detected in Korea (비무장지대 부근에서 발생한 양성 삼일열 말라리아 환자 2례)

  • Cho, Seung-Yull;Kong, Yoon;Park, Sill-Moo;Lee, Joon-Seung;Lim, Young-Ae;Chae, Seok-Lae;Kho, Weon-Gyu;Lee, Jong-Soo;Shim, Jae-Chul;Shin, Hak-Kyoon
    • Parasites, Hosts and Diseases
    • /
    • v.32 no.4
    • /
    • pp.281-284
    • /
    • 1994
  • On .lune and .truly 1994, two cases of vivax wl,Blaria were consecutively diagnosed at the Yongsan Hospital, Chung-Ang University in Seoul. The first patient was a soldier sewing in western parts of the demilitarized zone (DMZ) while the second case was a resident of a village near DMZ. Neither patients had history of being abroad. Republic of Korea (ROK) has been free of malaria since the mid-1970s except for imported cases. The two ivfn malaria cases, together with an additional patient detected in 1993, occurred in relatively small areas near DMZ. This necessitated an epidemiologic surveillance. When medical records and blood smears in the areas were examined, no other cases were found. Of 7,723 mosquitoes collected by a black light trap for ho nights in June, 7,066 (91.5%) were Anopheles sinensis. In order to evaluate a significance of the recent malaria occurrence, a surveillance system should be operated in the areas.

  • PDF

Reinterpretation of Business Models: Network Subscriber Perspective (네트워크 관점에서의 비즈니스 모델 재해석: 가입자 개념을 중심으로)

  • Kim, Jaeyoung;Han, Jaemin;Kim, YooJung
    • Information Systems Review
    • /
    • v.14 no.2
    • /
    • pp.93-102
    • /
    • 2012
  • Network brings new values to the business in rapid changes of business paradigm. While business reveals new business model, the business has kept making efforts to replace traditional business model to network environment in order to solve the problems of spaces and times. In this research, we emphasize necessity through case study that the traditional concept of customer should be related with the concept of business network. The finding of this research mainly focused on business, tries to use traits of network without changes of business model, is easy to trap in structural inertia. However, the targeted companies in the case study preferentially considered customer as subscriber. Consequently, they successfully changed their existing business model as well as their business relationships with other companies. Based on methods of "Value Curve" and "Customer Experience Cycle," we analyzed the changed business model and proposed a conceptual idea regarding concept shifting from traditional customer to network subscriber. We hope that the research implicates to propose a new method for business model to develop more advanced business opportunities through using the concept of network subscriber.

  • PDF

Experimental Study on the Characteristics of Brown Gas (브라운가스의 특성에 대한 실험적 연구)

  • Kim Chang-Hee;Oh Kyu-Hyung;Kang Kyung-Soo;Park Chu-Sik;Bae Ki-Kwang;Kim Jong-Won
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
    • /
    • 2006.05a
    • /
    • pp.262-262
    • /
    • 2006
  • The characteristics of Brown gas was experimentally studied in view of efficiency and flame propagation. For this study, the Brown gas stack with 7 cells was manufactured following the Brown gas related patents and reports. All measuring equipments were re-tested and calibrated by Korea Laboratory Accreditation Scheme (KOLAS) certified laboratories. Since the amount of produced gas is most crucial in determining the efficiency, we adopted two gas collecting methods such as bottle trap method and wet gas meter method. The energy efficiency of our own fabricated stack was measured to be 75%, which is comparable to general alkaline water electrolysis efficiency. In order to analyze the flame propagation characteristics of Brown gas, we measured the flame propagation pressure, velocity, and shape by using strain type pressure sensor, optical sensor, and high speed camera in conjunction with Schliren system, respectively. From the experimental results, it was found that the flame propagation behavior of Brown gas was almost the same as that of hydrogen and oxygen mixture gas in 2:1 molar ratio. Moreover, from the high speed camera analysis, we concluded that Brown gas flame exhibits explosion behavior as does mixture gas ($H_{2}:O_{2}=2:1$).

  • PDF

Screening Method for Non-viable Seeds in Brassicaceae Vegetable Crops by Sinapine Leakage (Sinapine누출을 이용한 십자화과 채소의 퇴화종자 선별법)

  • 민태기
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.39 no.5
    • /
    • pp.473-479
    • /
    • 1994
  • A seed coating system was developed to screen non-viable seeds in the Brassicaceae. The crops studied were radish, chinese cabbage, broccoli, cauliflower and brussel sprout. Sinapine leaked more from artificially deteriorated seeds than non-deteriorated seeds. Seed coating with cellulose was to trap the sinapine leakage in the non-viable Brassicaceae vegetable seeds. The seeds were first hydrated, then coated with cellulose powder to capture the leakage. Coated seeds were dried, then sorted two fractions-fluorescent seeds and non-fluorescent seeds under the UV light. The ratio of the fluorescent seeds were higher in bad seedlot than good one. The germination rate were increased 3∼35% by eliminating the fluorescent seeds in tested Brassica vegetable seeds. Sowing non-fluorescent seeds resulted in a greater percent normal seedling than non-coated seeds in all seedlots. The fluorescent seeds contained a high percentage of the dead and abnormal seedlings.

  • PDF

Effect of Sonicated Extract of Treponema Denticola on Osteoclast Differentiation (Treponema denticola 분쇄액에 의한 파골세포 형성 효과)

  • Choi, Bong-Kyu;Lee, Hyun-Jung;Jeong, Gook-Jin;Jung, Soon-Hee;Kwak, Wall-Ah;Yoo, Yun-Jung
    • Journal of Periodontal and Implant Science
    • /
    • v.29 no.4
    • /
    • pp.995-1005
    • /
    • 1999
  • Alveolar bone destruction is a character-istic of periodontal disease. Treponema denticola are found in significantly increased numbers in the sites affected with periodontal disease. In order to clarify the role of T. denticola in destruction of alveo-lar bone in periodontal disease, this study was undertaken to determine the effect of sonicated extract of T. denticola on osteo-clast differentiation in co-culture system of mouse bone marrow cells and calvaria cells. The ability of osteoclast formation was estimated by counting the number of tar-tartrate resistant acid phosphatase(TRAP) positive cells. Sonicated extract of this bacteria stimulated osteoclast formation in a dose dependent manner(p<0.05). Indomathacin, an inhibitor of prostaglandin synthesis, decreased osteoclast formation induced by sonicated extract of this bacte-bacteria(p<0.05). Extract-induced osteoclast formation was decreased, when sonicated extract of bacteria was heated(p<0.05). These findings suggest that T. denticola induces osteoclast differentiation, and protein component of this bacteria and $PGE_2$ may play an important role in this process.

  • PDF

Study on Estimation of PM Mass in DPF from Pressure Drop in 3L Diesel Engine (3L급 디젤엔진의 배압이용 DPF 매연포집량 예측에 대한 연구)

  • Kim, Hong-Suk;Lee, Jin-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.34 no.5
    • /
    • pp.499-504
    • /
    • 2010
  • It is important to determine the exact soot mass in a DPF system in order to control the timing of PM regeneration. The soot mass accumulated in a filter can be estimated from the pressure drop in the filter and the exhaust gas flow rates. In this study, the soot index is defined as the pressure drop in the DPF divided by the pressure drop in a DOC. An effective signal processing method for determining the soot index is proposed; the results yielded by this method indicate good correlation between the soot index and the amount of soot loaded into the filter for both steady-state and transient-state operating conditions in a 3L diesel engine for passenger vehicles.

Fast and Accurate Determination of Algal Toxins in Water using Online Preconcentration and UPLC-Orbitrap Mass Spectrometry (온라인 시료주입과 UPLC-Orbitrap 질량분석법을 이용한 수질 조류독소의 고속분석방법 개발 및 환경시료적용)

  • Jang, Je-Heon;Kim, Yun-Seok;Choi, Jae-Won
    • Journal of Korean Society on Water Environment
    • /
    • v.28 no.6
    • /
    • pp.843-850
    • /
    • 2012
  • Due to the fast response to algae bloom issue in drinking water treatment plant, very fast determination methodology for algal toxin is required. In this study, column switching technique based online preconcentration method was combined with high resolution full scan mass spectrometer to save sample preparation time and to obtain fast and accurate result. After parameter optimization of online preconcentration, 1mL filtered sample was directly injected to trap column with switching valve system. Next, target toxins are eluted by 98% acetonitrile and analysed with 150 - 1,100 amu scan range at 50,000 resolving power. Method detection limit (MDL) for microcystin-LR, the most toxic isomer, was 0.1 ng/mL and others such as microcystin-YR, microcystin-RR and nodularin were 0.08, 0.03 and 0.04 ng/mL, respectively. This is the best improved sensitivities with 1mL volume in the literature. Furthermore, due to the use of ultra pressure HPLC (UPLC), the whole method run was completed in 4 min. Real sample applications for 173 sample including 55 surface water and 118 treatment plant samples for raw and treated water could be done within 16 hours. In our calculation, this methodology is roughly 80% faster than the previous manual solid-phase extraction with LC-MS/MS method.