• 열처리공학회지
• /
• 제19권1호
• /
• pp.10-19
• /
• 2006

Microstructure and morphology of precipitates in $Ni_3Al$- and TiAl-based intermetallics containing carbon have been investigated in terms of transmission electron microscopy(TEM). In an $L1_2$-ordered $Ni_3Al$ alloy with 4 mol.% of chromium and 0.2~3.0 mol.% of carbon, fine octahedral precipitates of $M_{23}C_6$ type carbide were formed in the matrix by aging at temperatures around 973 K after solution annealing at 1423 K. TEM examination revealed that the $M_{23}C_6$ phase and the matrix lattices have a cube-cube orientation relationship and keep partial atomic matching at the {111} interface. After prolonged aging or by aging at higher temperatures, the $M_{23}C_6$ precipitates then adopt a rod-like morphology elongated parallel to the <100> directions. In the $L1_0$-ordered TiAl containing 0.1~2.0 mol.% carbon, TEM observations revealed that needle-like precipitates, which lie only in one direction parallel to the [001] axis of the $L1_0$ matrix, appear in the matrix and preferentially at dislocations. Selected area electron diffraction(SAED) patterns analyses have shown that the needle-shaped precipitate is $Ti_3AlC$ of perovskite type. The orientation relationship between the $Ti_3AlC$ and the $L1_0$ matrix is found to be $(001)_{Ti3AlC}//(001)_{L10\;matrix}$ and $[010]_{Ti3AlC}//[010]_{L10\;matrix}$. By aging at higher temperatures or for longer period at 1073 K, plate-like precipitates of $Ti_2AlC$ with a hexagonal structure are formed on the {111} planes of the $L1_0$ matrix. The orientation relationship between the $Ti_2AlC$ and the $L1_0$ matrix is $(0001)_{Ti2AlC}//(111)_{L10\;matrix}$ and $_{Ti2AlC}//_{L10\;matrix}$.

• Bulletin of the Korean Chemical Society
• /
• 제31권5호
• /
• pp.1331-1335
• /
• 2010

A novel spherical carbon composite material, in which nanosized disordered carbons are dispersed in a soft carbon matrix, has been prepared and investigated for use as a potential anode material for lithium ion batteries. Disordered carbons were synthesized by ball milling natural graphite in air. The composite was prepared by mixing the ball-milled graphite with petroleum pitch powder, pelletizing the mixture, and pyrolyzing the pellets at $1200^{\circ}C$ in an argon flow. The ballmilled graphite consists of distorted nanocrystallites and amorphous phases. In the composite particle, nanosized flakes are uniformly distributed in a soft carbon matrix, as revealed by X-ray diffractometer (XRD) and transmission electron microscopy (TEM) experiments. The composite is compatible with a pure propylene carbonate (PC) electrolyte and shows high rate capability and excellent cycling performance. The electrochemical properties are comparable to those of hard carbon.

• 한국산업융합학회 논문집
• /
• 제4권1호
• /
• pp.27-34
• /
• 2001

Refining of powder particles and their dissolution into the Al matrix during mechanical alloying(MA) were investigated by using X-ray diffraction(XRD) transmission electron microscopy (TEM) functions of alloy composition, milling time and ball to powder ratio(BPR). It is found that Ti particles less than 20nm are observed in a dark field image of mechanically alloyed Al-10wt%Ti whose XHD pattern exhibits no Ti peak. The observed change of lattice constant of AI indicates that about 1 wt%Ti can he solved in Al after MA for a long time, independent of alloy composition, milling time and BPR, suggesting that most of Ti particles arc retained in the Al matrix. It is concluded that the disappearance of XRD peaks in mechanically alloyed Al-10wt%Ti is not simply attributable to the dissolution of Ti into Al, but associated mainly with extreme refining and/or heavy straining of Ti Particles.

• 전자공학회논문지A
• /
• 제30A권7호
• /
• pp.75-81
• /
• 1993

In this paper, New type of Static Edge Triggered D Flip-Flop Circuits which are effective for the sequencial selecting and addressing of Matrix type Electrodes being applied to Flat Display Devices is proposed by the Design Technique using the Transmission Characteristics of Feedback Transistors and Charge Back Up Function. These Circuits composed of 2-4 less transistors in number than Conventional Static D Flip Flop's have some advantages that the Maximum Transition Time of Clock Signals allowed is increased by 100-450 times more than that of the Conventional circuit at 100KHz Clock Frequence and Circuit Safety is much increased by making the wider ranges, 1-4V, of Clock Levelas a Non-operating periods than 3-3.2V ranges in case of the Conventional Circuit at 10MHz clock frequence. By these advantages, These circuits can be very effectively used in case that clock signal has long transition time, especially on the low frequency operation.

• The Journal of the Acoustical Society of Korea
• /
• 제21권4E호
• /
• pp.164-169
• /
• 2002

This paper proposes a hybrid method for vibration analysis in the medium to high frequency ranges using Power Flow Analysis (PFA) algorithm and Statistical Energy Analysis (SEA) coupling concepts. The main part of the developed method is the application of coupling loss factor (CLF) suggested in SEA to the power transmission, reflection coefficients in PI' A boundary conditions. The developed hybrid method shows very promising results with regard to the applications for the various damping loss factors in wide frequency ranges. And also this paper presents the applied results of Power Flow Finite Element Method (PFFEM) by forming the new joint element matrix with CLF to analyze the various plate structures in shape. The analytical results of automobile, complex plate structures show good agreement with those of PFFEM using the PFA coefficients.

• Transactions on Electrical and Electronic Materials
• /
• 제14권1호
• /
• pp.43-46
• /
• 2013

In order to develop electrical insulation material, organically modified layered silicate was incorporated into an epoxy matrix to prepare nanocomposite. Transmission electron microscopy (TEM) observation showed that organophillic clay was in an exfoliated state, while hydrophilic clay was not dispersed into nanolayers within the epoxy matrix. Epoxy/organophilic clay (2.8 wt%) nanocomposite was mixed and cured at $150^{\circ}C$ for 4.5 hr. I-V characteristics, volume resistance and dielectric properties for the cured nanocomposite were estimated. Current density increased with increasing temperature, and volume resistance decreased with increasing temperature, in neat epoxy and epoxy/organophilic clay (2.8 wt%) nanocomposite. As frequency increased, the dielectric loss value decreased in the two systems.

• 한국분말재료학회지
• /
• 제4권2호
• /
• pp.100-105
• /
• 1997

In this study the changes of the hardness and microstructures during aging at 120$^{\cire}C$ of an RS-P/M Al-5.6wt%Zn-2.0wt%Mg-1.3wt%Zr-1.0wt%Mn-0.25wt%Cu alloy were studied using a transmission electron microscopy. The hardness increased rapidly at early stage of aging and reached the maximun when the specimen was aged for 24 hr. The many irregular-shaped $Al_4Mn$ and rod-shaped $Al_6Mn$ dispersoids with 0.1-0.4 $\mu$m in length were observed in the as-extruded alloy. The dark particles with 2-3 nm in size were observed in aged specimen for 5hr and those are thought to be G.P.zones or precursor of $\eta'$ precipitates. In aged specimen for 24 hr, the $\eta'$ phases were distributed homogeneously within the matrix and the PFZ with 30-40 nm in width was observed along the grain boundary. With further aging, the width of PFZ increased and $\eta$ phases were also detected within the matrix.

• Journal of the Korean Association of Oral and Maxillofacial Surgeons
• /
• 제26권6호
• /
• pp.602-605
• /
• 2000

Human alveolar bone cells were isolated from alveolar bone fragments obtained from normal individual undergoing third molar extractions. Alveolar bone fragments were cultured as explant. Cells began to migrate in the first $5{\sim}7$ day and were confluent in $5{\sim}7$ week. Matrix mineralization was observed by 4 week. Our studies utilize established protocols for the characterization of these cells as osteoblasts by means of alkaline phosphatase activity determination, identification of osteocalcin antigens, establishing the presence of cells expressing type I collagen and determining the ability of cells to produce calcification. Transmission electron microscopic observations confirmed the presence of a collagen matrix undergoing a mineralization process. This new model, using human alveolar bone cells, may provide a tool to investigate alveolar bone development and physiology and to set up new therapeutic approaches.

• 한국기계가공학회지
• /
• 제11권5호
• /
• pp.68-75
• /
• 2012

This study aims at the structural analysis of vibration and fatigue according to the tie rod configuration. The maximum displacement amplitude is happened at 156Hz by harmonic vibration analysis, this tie rod model can be broken as the weakest state. Among the cases of nonuniform fatigue loads, 'SAE bracket history' with the severest change of load becomes most unstable but 'Sine wave' becomes most stable. In case of 'Sine wave' with the average stress of 0MPa and the amplitude stress of 570MPa, the possibility of maximum damage becomes 70%. This stress state can be shown with 140 times more than the damage possibility of 'SAE bracket history' or 'SAE transmission'. The structural result of this study can be effectively utilized with the design on tie rod by investigating prevention and durability against its damage.

• 제어로봇시스템학회논문지
• /
• 제12권7호
• /
• pp.719-727
• /
• 2006

This paper proposes a new method to obtain a maximum allowable delay bound for a scheduling of networked discrete control systems and event-based scheduling method. The proposed method is formulated in terms of linear matrix inequalities and can give a much less conservative delay bound than the existing methods. A network scheduling method is presented based on the delay obtained through the proposed method, and it can adjust the sampling period to allocate same utilization to each control loop. The presented method can handle three types of data (sporadic, emergency data, periodic data and non real-time message) and guarantees real-time transmission of periodic and sporadic emergency data using modified EDF scheduling method.