• 제목/요약/키워드: Transition region

검색결과 960건 처리시간 0.029초

Microwave Sol-Gel Derived NaLa(MoO4)2 Yellow Phosphors Doped with Ho3+/Yb3+ and Upconversion Photoluminescence

  • Lim, Chang Sung
    • Korean Journal of Materials Research
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    • 제26권1호
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    • pp.29-34
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    • 2016
  • $NaLa_{1-x}{(MoO_4)}_2$:$Ho^{3+}/Yb^{3+}$ phosphors with the correct doping concentrations of $Ho^{3+}$ and $Yb^{3+}$ ($x=Ho^{3+}+Yb^{3+}$, $Ho^{3+}=0.05$ and $Yb^{3+}=0.35$, 0.40, 0.45 and 0.50) were successfully synthesized by the microwave-modified sol-gel method. Well-crystallized particles formed after heat-treatment at $900^{\circ}C$ for 16 h showed a fine and homogeneous morphology with particle sizes of $3-5{\mu}m$. The optical properties were examined using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the UC intensities of the doped samples exhibited strong yellow emissions based on the combination of strong emission bands at 545-nm and 655-nm emission bands in green and red spectral regions, respectively. The strong 545-nm emission band in the green region corresponds to the $^5S_2/^5F_4{\rightarrow}^5I_8$ transition in $Ho^{3+}$ ions, while the strong emission 655-nm band in the red region appears due to the $^5F_5{\rightarrow}^5I_8$ transition in $Ho^{3+}$ ions. Pump power dependence and Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail.

pH- and Temperature-Sensitive Bifunctional Hydrogels of N-Isopropylacrylamide and Sulfadimethoxine Monomer

  • Lee, Jin-Woo;Lee, Doo-Sung;Kim, Sung-Wan
    • Macromolecular Research
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    • 제11권3호
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    • pp.189-193
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    • 2003
  • pH- and temperature-sensitive bifunctional hydrogels composed of N-isopropylacrylamide (NiPAAm) and a sulfadimethoxine monomer (SDM) derived from sulfadimethoxine were prepared. These hydrogels exhibit simultaneous pH- and temperature-induced volume-phase transitions. The pH-induced volume-phase transition behavior is produced by the ionization/deionization of SDM and is very sharp. In the high pH region, the ionization of SDM induces swelling of the hydrogels. In the low pH region, the deionization of SDM induces deswelling of the hydrogels. The temperature-induced volume-phase transition behavior of the bifunctional hydrogels exhibits negative thermosensitivity because of the NiPAAm component. The hydrogels swell even at low pH as the temperature decreases. The hydrogels swell at low temperature and high pH, and deswell at high temperature and low pH. The volume of the hydrogels dependl on the balance of the swelling and deswelling produced by the two competing stimuli, pH and temperature.

A Study on Steady and Unsteady Behavior of Helium Jet in the Stationary Atmosphere (헬륨 기체분류의 정상적 비정상적 거동에 관한 연구)

  • Kim, B.G.;Suh, Y.K.;Ha, J.Y.;Kwon, S.S.
    • Transactions of the Korean Society of Automotive Engineers
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    • 제1권3호
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    • pp.34-45
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    • 1993
  • This study aims to analyze the mixing characteristics of hydrogen considered as a new fuel for internal combustion engines. As the physical property of helium gas is similar to that of hydrogen, helium gas was used in this study. To analyze the steady and unsteady behavior of jet, helium gas was injected into the stationary atmosphere at the normal temperature and pressure. Concentration of helium gas in the center of jet flow is in inverse proportion with axial distance from the nozzle tip. This agrees with the free jet theory of Schlichting. The relative equation for dimensionless concentration to radial/axial distance the axial distance of potential core region, the cone angle a of the jet flow and the relative equation for arriving distance of the front of jet flow to the lapse of time are obtained. But free jet theory of Schlichting in the dimensionless concentration is not in agreement with the present experimental results of the distance of the radial direction. It needs more study. When the arrival frequency of jet flow is used as a parameter, the transition area changing from unsteady flow area into steady flow area becomes gradually wider downstream, but its ratio for the whole unsteady flow area gradually decreases.

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Evaluation of Hydrides Effects on Corrosion and Tensile Properties of Stress-relieved Zirconium Claddings (응력이완 열처리된 지르코늄 피복관의 부식 및 인장특성에 미치는 수소화물 영향 평가)

  • Bang, Je-Geon;Baek, Jong Hyuk;Lee, Myung Ho;Jeong, Yong Hwan
    • Journal of the Korean Society for Heat Treatment
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    • 제17권6호
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    • pp.356-364
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    • 2004
  • The hydrides in cladding affect the corrosion and tensile properties. In this study corrosion and tensile properties were evaluated with varying the hydrogen concentration. The charged hydrogen contents were ranged from 200 to 1000 ppm. The corrosion rate in water and LiOH solution increases with the hydrogen concentration. The hydride did not affect the corrosion mechanism in the pre-transition region, but in the post-transition region the corrosion rate was accelerated. Cladding E contained higher Niobium content was slowly accelerated compared with other claddings. The yield and ultimate strengths were independent on the hydrogen content. However, the total elongation decreased gradually with increasing the hydrogen content. SEM observation of fracture surface showed that an average of depth of voids decreased with increasing the hydrogen content and small secondary crack are observed.

Deposition of Al Doped ZnO Films Using ICP-assisted Sputtering on the Plastic Substrate (유도결합 플라즈마 스퍼터링을 이용한 플라스틱 기판 상의 Al이 도핑된 ZnO 박막 증착)

  • Jung, Seung-Jae;Han, Young-Hun;Lee, Jung-Joong
    • Journal of the Korean institute of surface engineering
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    • 제39권3호
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    • pp.98-104
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    • 2006
  • Al-doped ZnO (AZO) films were deposited on the plastic substrate by inductively coupled plasma (ICP) assisted DC magnetron sputtering. The AZO films were produced by sputtering a metallic target (Zn/Al) in a mixture of argon and oxygen gases. AZO films with an electrical resistivity of ${\sim}10^3\;{\Omega}cm$ and an optical transmittance of 80% were obtained even at a low deposition temperature. In-situ process control methods were used to obtain stable deposition conditions in the transition region without any hysteresis effect. The target voltage was controlled either at a constant DC power. It was found that the ratio of the zinc to oxygen emission intensity, I (O 777)/I (Zn 481) decreased with increasing the target voltage in the transition region. The $Ar/O_2$ plasma treatment improve the adhesion strength between the polycarbonate substrate and AZO films.

GaAs MESFET Model using Channel-length Modulation (채널길이변조를 이용한 GaAs MESFET 모델)

  • 이상흥;이기준
    • Journal of the Korean Institute of Telematics and Electronics T
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    • 제35T권1호
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    • pp.14-21
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    • 1998
  • In the conventional GaAs MESFET circuit simulation, the DC and transient simulation results are often failed due to the discontinuities of the first and second order derivatives arising from the use of separate models in linear, saturation, and transition regions. In this paper, we propose a unified drain current-voltage model by using a unified channel length modulation effect that is derived by extending the channel length modulation effect in the saturation region to the linear region. Calculated results from the proposed drain current-voltage model agree well with the results of Shur model. Also, we propose a unified capacitance model for linear, transition, and saturation regions by using a unified channel length modulation effect. Its results from the proposed capacitance model agree well with 2-D device simulation results. Thus, the proposed models are expected to be useful in circuit simulations.

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Bonding and Antibonding Regions (II). Origin of Barriers to Internal Rotation of $H_2O_2$ and $C_2H_6$ (결합공간과 반결합공간 (제2보). $H_2O_2$$C_2H_6$의 Internal Rotation Barrier의 원천적 요인)

  • Kim Hojing;Lee Duckhwan
    • Journal of the Korean Chemical Society
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    • 제23권1호
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    • pp.20-29
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    • 1979
  • The origin of barriers to internal rotation of hydrogen peroxide and ethane is investigated by using the concept of Bonding and Antibonding Regions. The strong bond formations between the axial and end atoms on the same side make the real charge densities in these molecules less dependent on conformations than those in the hypothetical molecules having no axial atoms. Thus, the existence of the axial atoms should induce the migration of the transition density from the Bonding region to the Antibonding region. Barrier to internal rotation can be understood in terms of this migration of the transition density to such an extent that the change in nuclear-nuclear repulsion energy becomes the dominating part of the total perturbation energy.

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Direct Numerical and Large Eddy Simulations of Transitional Flows around Turbulence Stimulators at Very Low Speeds (초저속 영역에서 난류 촉진기 주위 천이 유동의 직접 수치 및 대형 와 모사)

  • Lee, Sang Bong
    • Journal of the Society of Naval Architects of Korea
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    • 제55권3호
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    • pp.265-273
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    • 2018
  • Direct numerical and large eddy simulations of transitional flows around studs installed on flat plate and bulbous bow have been performed to investigate an effectiveness of turbulence stimulators on laminar-to-turbulence transition at a very low speed. The flow velocity was determined to be 0.366m/s corresponding to 4 knots of full-scale ship speed when the objective ship was Kriso container ship. The spatial evolution of skin friction coefficient disclosed that a fully development of turbulence was observed behind the second stud installed on flat plate while a rapid transition from laminar to turbulence gave rise to the fully development of turbulence behind the first stud installed on bulbous bow. A comparison of streamwise mean velocity profiles showed that the viscous sublayer and log-layer were in good agreement with previous results although the friction velocity of Smagrosinsky sub-grid scale model was about 10% larger than that of direct numerical simulation. While the turbulence intensities of bulbous bow was similar to those of flat plate in inner region, larger intensities of turbulence were observed in outer region of bulbous bow than those of flat plate.

Numerical Analysis of Transitional Flow in a Stenosed Carotid Artery (협착된 경동맥내 천이 유동 수치 해석)

  • Kim, Dongmin;Hwang, Jinyul;Min, Too-Jae;Jo, Won-Min
    • Journal of the Korean Society of Visualization
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    • 제20권1호
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    • pp.52-63
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    • 2022
  • Direct numerical simulation of blood flow in a stenosed, patient-specific carotid artery was conducted to explore the transient behavior of blood flow with special emphasis on the wall-shear stress distribution over the transition region. We assumed the blood as an incompressible Newtonian fluid, and the vessel was treated as a solid wall. The pulsatile boundary condition was applied at the inlet of the carotid. The Reynolds number is 884 based on the inlet diameter, and the maximum flow rate and the corresponding Womersley number is approximately 5.9. We found the transitional behavior during the acceleration and deceleration phases. In order to quantitatively examine the wall-shear stress distribution over the transition region, the probability density function of the wall-shear stress was computed. It showed that the negative wall-shear stress events frequently occur near peak systole. In addition, the oscillatory shear stress index was used to further analyze the relationship with the negative wall-shear stress appearing in the systolic phase.

Covid-19 and Transitions: Case Material from Southeast Asia

  • King, Victor T.
    • SUVANNABHUMI
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    • 제14권2호
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    • pp.27-59
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    • 2022
  • During the past two decades, the Southeast Asian region has experienced a range of major crises. Service industries such as tourism and the marginal and migrant laborers who work in them have usually been at the sharp end of these testing events, from natural and environmental disasters, epidemics and pandemics, global financial slumps, terrorism, and political conflict. The latest challenge is the "Novel Coronavirus" (Covid-19/SARS-CoV-2) pandemic. It has already had serious consequences for Southeast Asia and its tourism development and these will continue for the foreseeable future. Since the SARS epidemic of 2002-2004, Southeast Asian economies have become integrated increasingly into those of East Asia (China, Japan, South Korea, Taiwan, Hong Kong). This paper examines one of the most significant current crises, Covid-19, and its consequences for Southeast Asia, its tourism industry, and its workers, comparing experiences across the region, and the issues raised by the over-dependence of some countries on East Asia. In research on crises, the main focus has been on dramatic, unpredictable natural disasters, and human-generated global economic downturns. Not so much attention has been devoted to disease and contagion, which has both natural and socio-cultural dimensions in origins and effects, and which, in the case of Covid-19, evoke a pre-crisis period of normality, a liminal transition or "meantime" and a post-crisis "new normality." The transition is not straightforward; in many countries, it operates as a set of serial lockdowns and restrictions, and to predict an uncertain future remains difficult.