• Title/Summary/Keyword: Trace metal

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Investigation on Contents of Heavy Metals and Parasites of the Dropwort(Oenanthe javanica) cultivated in Chollanamdo (전라남도내 미나리의 중금속 함량 및 기생충에 대한 조사)

  • Heo, Nam-Chil;Kim, Choong-Mo;Park, Sook;Na, Hwan-Sik
    • Korean Journal of Food Science and Technology
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    • v.32 no.4
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    • pp.970-973
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    • 2000
  • Heavy metal contents and parasite egg examination for the safety evaluation of dropwort(Oenanthe javanica) from the inside of Chonnam province(5 regions) and suburbs of Kwang-ju(1 region) were investigated. The contents of heavy metals(Hg, Pb, As, Cd, Mn, Zn, Cu) were determined by the Atomic Absorption Spectrophotometer and parasite eggs were examined to various internalparasites(F. hepatica, C. sinesis, G. lamblia, Cryptosporidium, A. lumbricoides and A. duodenale). First, Hg and As were detected in trace level and $0.003{\sim}0.01\;ppm$. Pb was not detected in all samples and Cd contents of dropworts were detected $0.014{\sim}0.087\;ppm$. The contents of 4 kinds of heavy metals(Hg, As, Pb and Cd) in dropworts cultivated in various regions(6 regions) were not detected or trace levels. Therefore, dropworts cultivated in Chonnam province and suburbs of Kwang-ju were free from contamination of heavy metals. Moreover, the result of parasite egg examination(Trematoda, Protozoa and Nematoda) was not detected in all samples.

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Optimal Condition for Simultaneous Saccharification and Fermentation Using Pretreated Corncob by Oxalic Acid (옥살산 전처리 옥수숫대를 이용한 동시당화발효 최적 조건 탐색)

  • Seo, Young-Jun;Lim, Woo-Seok;Lee, Jae-Won
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.6
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    • pp.490-497
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    • 2011
  • In this study, we determined optimal conditions for simultaneous saccharification and fermentation (SSF) using corncob biomass pretreated with oxalic acid. The effect of SSF temperature ($25.8{\sim}34.2^{\circ}C$) and agitation speed (80~220 rpm) were significant at a 99% confidence level in its effect on ethanol production. The highest ethanol production was expected when SSF was performed at $30^{\circ}C$, 170 rpm (22.5 g/L). The ethanol production was improved by mixture of yeast extract (1.25 g/L) and urea (1.25 g/L) as nitrogen source. However, addition of trace metal components and vitamin for SSF was not affected in the ethanol production. Optimal concentration of $KH_2PO_4$, $MgSO_4{\cdot}7H_2O$ for SSF was 1 g/L, 0.25 g/L respectively.

AN EXPERIMENTAL STUDY OF INTERFACIAL ELEMENTAL TRANSITION IN CERAMO-METAL RESTORATION (도저용 착시 도재-금속 개면에서의 원소이동에 관한 실험적 연구)

  • Lee, Keun-Woo;Lee, Ho-Yong
    • The Journal of Korean Academy of Prosthodontics
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    • v.25 no.1
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    • pp.95-118
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    • 1987
  • This study was undertaken to observe the elemental transition of Interface depending on different pretreatment methods, the number of filings, the kinds of porcelain powders and the various alloys in ceramo-metal restoration. The materials used in this study were Pors-on $4^{(R)}$ and Ceramco porcelain powder to compare the differences depending on the pretreatement methods and the number of firings. Ceramco porcelain powder and Vita porcelain powder were used to compare the differences of elemental transition depending on the porcelain powders. The $Parasil^{(R)},\;PGV^{(R)}$ and Pors-on $4^{(R)}$ as Pd-Ag alloy were used to compare the difference of elemental transition depending on the various alloys. The pretreatment methods were : no treatment, treatment under vacuum and air, treatment with 50 % hydrofluoric acid and double heat tretament. The number of firings were 3, 5 and 7 repeated firings All specimens were observed by SEM and concentration of elements were analyzed quantitatively with EPMA The results of this study were obtained as follows : 1. In the groups of air-treatment, concentration of Sn were the highest and widest. A high concentration of In were in the groups of vacuum and air treatment. 2. There were no significant differences in concentration of Sn between the group of vacuum, 5 minutes hydrofluoric acid and double heat treatment. (p>0.05) 3. As the period of time of hydrofluoric acid treatment increased, not only were the trace elements reduced but the main components such as Pd and Ag were also reduced. 4. Concentration of Sn and In increased and diffused with repeated firings but 5 repeated and 7 repeated firings groups had no significant differences. (p>0.05) 5. Sn were more concentrated in the group of Ceramco porcelaion powder than Vita porcelain powder. 6. The higher concentration of trace elements in the alloy, the more increasing concentration of Sn and In in the interface.

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Heavy metals in the rice and rice paddy soil of Kyung Nam district (경남 일원의 논흙 및 쌀 중의 중금속)

  • Lee, Dong-Gun;Lim, Gyung-Teck
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.6 no.1
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    • pp.73-79
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    • 1977
  • Heavy metals in the rice and rice paddy soil of Kyung Nam district were surveyed by use of MIBK extraction and atomic absorption spectrophotomter. Mercury was analyzed by nom-flame mercury vapor method. Rice paddy soil showed that cupper amounted to the level of $13.8{\sim}8.4ppm$, average value of 11.5ppm. Lead: $2.6{\sim}0.6ppm$, average 0.02ppm. The conentration of heavy metal $0.04{\sim}0.01ppm$, average 1.5 ppm, Zinc ; $16.1{\sim}7.2ppm$, average 11.3 ppm. Cadmium in rice were containted $2.59{\sim}0.16ppm$ of cupper, average value of 1.80 ppm. Lead: $0.2{\sim}N.D$, Zinc ; $0.11{\sim}0.60ppm$. Cadmium was shown trace at 4 places and mercury was shown trace at 6 places. Cupper showed the highest ratio of heavy metal. Levels in rice and soil whereas zinc showed the highest transmission from soil to rice.

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Diffusion of the High Melting Temperature Element from the Molten Oxides for Copper Alloys (구리 합금을 위한 초고융점 원소의 용융산화물 확산 공정)

  • Song, Jeongho;Noh, Yunyoung;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.26 no.3
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    • pp.130-135
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    • 2016
  • To alloy high melting point elements such as boron, ruthenium, and iridium with copper, heat treatment was performed using metal oxides of $B_2O_3$, $RuO_2$, and $IrO_2$ at the temperature of $1200^{\circ}C$ in vacuum for 30 minutes. The microstructure analysis of the alloyed sample was confirmed using an optical microscope and FE-SEM. Hardness and trace element analyses were performed using Vickers hardness and WD-XRF, respectively. Diffusion profile analysis was performed using D-SIMS. From the microstructure analysis results, crystal grains were found to have formed with sizes of 2.97 mm. For the copper alloys formed using metal oxides of $B_2O_3$, $RuO_2$, and $IrO_2$ the sizes of the crystal grains were 1.24, 1.77, and 2.23 mm, respectively, while these sizes were smaller than pure copper. From the Vickers hardness results, the hardness of the Ir-copper alloy was found to have increased by a maximum of 2.2 times compared to pure copper. From the trace element analysis, the copper alloy was fabricated with the expected composition. From the diffusion profile analysis results, it can be seen that 0.059 wt%, 0.030 wt%, and 0.114 wt% of B, Ru, and Ir, respectively, were alloyed in the copper, and it led to change the hardness. Therefore, we verified that alloying of high melting point elements is possible at the low temperature of $1200^{\circ}C$.

Trace Element Analysis and Source Assessment of Household Dust in Daegu, Korea (대구지역 일반주택의 축적먼지 중 미량원소성분 분석과 오염원 평가)

  • Do, Hwa-Seok;Song, Hee-Bong;Jung, Yeoun-Wook;Yoon, Ho-Suk;Kwak, Jin-Hee;Han, Jeong-Uk;Kang, Hye-Jung;Phee, Young-Gyu
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.1
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    • pp.69-78
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    • 2010
  • In order to investigate the degree of household dust contamination, 48 samples of household dust (24 from urban area and 24 from rural area) in Daegu city were collected in vacuum cleaner during January to February 2009. Samples were sieved below 100 ${\mu}m$, and 14 elements (Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, V, Zn) were analyzed using ICP after acid extraction. Results obtained from the source assessment of trace elements using enrichment factor showed that Ca, Fe, K, Mg, Mn, Na, and V were influenced by natural sources such as weathered rock and resuspended soil, while Cd, Cr, Cu, Ni, Pb and Zn were influenced by anthropogenic sources such as fuel combustion and waste incineration. Concentrations were remarkably higher in components from natural sources than in components from urban anthropogenic sources. Household dust in urban area was more affected by anthropogenic sources compared with that of rural area. Pollution index of heavy metals revealed that urban area was 1.8 times more contaminated with heavy metal components than rural area. The correlation analysis among trace elements indicated that components were correlated with natural sources-natural sources (Al-Mg, Al-Mn, Fe-Mn) and natural sources-anthropogenic sources (Al-V, Fe-Cr, V-Mn) in both urban area and rural area. Trace element components of rural area were more correlated than those of urban area. Houses that use oil for heating fuel had relatively higher contents of heavy metals rather than those using gas or electricity for heating fuel. Houses with children also had higher contents of heavy metals. In addition, the age of houses was found to influence the heavy metal levels in household dusts, with older houses (>10years) having higher concentrations than newer houses (<10years) and houses located near the major road (<10 m) were found to have relatively higher heavy metal levels in household dust.

How are S0 galaxies formed? A case of the Sombrero galaxy

  • Kang, Jisu;Lee, Myung Gyoon;Jang, In Sung;Ko, Youkyung;Sohn, Jubee;Hwang, Narae;Park, Byeong-Gon
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.38.2-38.2
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    • 2019
  • S0 galaxies are mostly known to be formed in dense environments from spiral progenitors. Recently, however, a new formation scenario has been suggested that field S0s can be formed from elliptical progenitors. The Sombrero galaxy (M104, NGC 4594) is a massive disk galaxy located in the field environment, and its morphological type has been controversial from Sa to E. Thus, it is an ideal target to test the new scenario. We trace the giant halo of M104 with globular clusters to test this scenario. From the wide images obtained with CFHT/MegaCam, we find a large number of globular clusters in this galaxy. We also confirm their membership by measuring the radial velocities from the spectra obtained with MMT/Hectospec. The color distribution of these globular clusters is bimodal, and blue (metal-poor) globular clusters are more spatially widely spread than red (metal-rich) globular clusters. This indicates that M104 hosts a giant metal-poor halo as well as an inner metal-rich halo. Combining this result with the fact that M104 is unusually massive and brighter than other spiral galaxies, we infer that M104 was indeed a massive elliptical galaxy that had formed a metal-rich halo by gas-rich mergers and a metal-poor halo by gas-poor mergers. In addition, we find young star clusters around the disk of M104, which shows that the disk formed after the spheroidal halos had formed. In conclusion, we suggest that M104 was originally a massive elliptical galaxy and was transformed to a lenticular galaxy by acquiring its disk later.

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Effects of Temperature and Heavy Metals on Extractable Lipofuscin in the Blue Crab, Callinectes sapidus

  • Ju, Se-Jong;Harvey, H.R.
    • Journal of the korean society of oceanography
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    • v.37 no.4
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    • pp.232-241
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    • 2002
  • The potential role of environmental factors on extractable lipofuscin accumulation rate in the blue crab was studied by examining the effect of temperature on laboratory reared blue crabs and the effect of trace metals from samples collected at impacted sites (Baltimore Harbor) and a relatively pristine site (outdoor ponds at Horn Point Laboratory, Cambridge, MD, USA). Lipofuscin levels did not significantly related with sampling sites or heavy metal concentrations in the crab tissue. Heavy metal body burden was highly variable among sampling sites and tissue types but significantly higher for both impacted areas (Curtis Creek and Inner Harbor) in comparison to the reference site. Among tissue types, gills showed the highest metal concentrations with the exception of Hg, which was highest in muscle tissue. For two groups of crabs that were held at either ambient (4 to 1$0^{\circ}C$) or heated seawater (19$^{\circ}C$) for two months, normalized-lipofuscin levels were significantly different (P-0.001). Results suggest that temperature may affect lipofuscin accumulation (=0.25ng-lipofuscin/mg-protein/temperature-degree day). Therefore, temperature should be considered for accurate age calibration of crab populations using lipofuscin.

Geochemical Study of Coastal Sediments around the Samcheonpo Coal-fired Power Plant (삼천포화력발전소 주변해역 퇴적물의 지구화학적 연구)

  • Lee, Doo-Ho;Lim, Ju-Hwan;Jeong, Yeon-Tae;Jeong, Nyeon-Ho;Kang, Jeong-Won
    • Journal of Environmental Impact Assessment
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    • v.10 no.2
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    • pp.85-98
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    • 2001
  • This study was conducted to investigate the geochemical factors governing the distribution of heavy metals(Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) in the marine surface sediment samples collected from the Samcheonpo coal-fired power plant. Variations of absolute metal concentrations were related to those in textural and/or carbonate and organic matter content. Most elements, except for Pb, showed generally lower contents compared with the average shale concentration, and the effect of anthropogenic input appeared to be minimal in the sediments. Computations of LF%(labile fraction) and EF(enrichment factor) based on all trace metal data indicated the presence of mineralogical control for Co, Cr, Cu, Ni, and Zn, and anthropogenic contamination for Pb, which needs to be considered in the design of long term monitoring programmes.

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A Study on the Heavy Metal Contents of Common Salts in Korea (우리나라 일부 소금의 중금속 함량에 대한 조사연구)

  • Hwang, Seong-Hi
    • Journal of Environmental Health Sciences
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    • v.14 no.1
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    • pp.73-86
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    • 1988
  • In order to determine the content levels of trace metals in common salts, 64 bay salt samples were collected from three producing districts and 33 bay salt samples, 32 remade salt samples and 5 fine salt samples were collected from 7 major cities in Korea, from August to September 1987. These were analysed for content levels of Pb, Cd, Cu, Zn and Mn using Atomic Absorption Spectrophotometer. The results were as follows: 1. Lead contents in three type salts were N.D. - 1081.9 $\mu$g/kg and fourteen percent of the 114 samples exceeded the World Health Organization(WHO) criteria of 100$\mu$g/kg. Cadmium contents of samples were N.D.- 382C.5 $\mu$g/kg and five percent of the 114 samples were over the Spanish criteria of 500 $\mu$g/kg. Copper contents of samples were 8,9-214.9 $\mu$g/kg and there was not a sample over the World Health Organization(WHO) criteria of 500 $\mu$g/kg. Zinc contents ranged N.D. - 342.9 $\mu$g/kg and Manganese contents ranged N.D.- 8.31 mg/kg. 2. The comparison of heavy metal contents among the bay salts from three producing districts was significantly different in Pb, Cd and Cu contents. 3. The comparison of heavy metal contents between the bay salts and remade salts was not significantly different in Pb, Cd and Cu contents. 4. The contents of Pb, Cd, Zn and Mn in fine salts were much lower than those of bay salts and remade salts.

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