• Textile Coloration and Finishing
• /
• v.29 no.1
• /
• pp.37-44
• /
• 2017

An issue of major concern in the utilization of laminated composites based epoxy resin is associated with the occurrence of delaminations or interlaminar cracks, which may be related to manufacturing defects or are induced in service by low-velocity impacts. A strong interfacial filament/brittle epoxy resin bonding can, however, be combined with the high fracture toughness of weak interfacial bonding, when the filaments are arranged to have alternate sections of shear stress. To improve this drawback of the epoxy resin, UV-thermal dual curable resin were developed. This paper presents UV-thermal dual curable resin which were prepared using epoxy acrylate oligomer, photoinitiators, a thermal-curing agent and thermoset epoxy resin. The UV curing behaviors and characteristics of UV-thermal dual curable epoxy resin were investigated using Photo-DSC, DMA and FTIR-ATR spectroscopy. The mechanical properties of UV-thermal dual curable epoxy resin impregnated CF prepreg by UV curable resin content were measured with Tensile, Flextural, ILSS and Sharpy impact test. The obtained results showed that UV curable resin content improves the epoxy toughness.

• Journal of Environmental Science International
• /
• v.17 no.11
• /
• pp.1227-1233
• /
• 2008

The effect of freeze drying and fixatives in post-treating freeze drying on the morphological properties of the rose (Rosa hybrida L.) petal were investigated for the production of high quality of freeze dried rose. The morphology including form and color of the dried flowers of cut rose were depended on the drying methods. The drying time was extended due to their density and water content, and was shorter in the freeze drying than that in the natural and hot air drying. Freeze dried process for dried flowers took 2 days in a freeze dryer and did not cause shrinkage or toughening of rose petal being dried, preserving its natural shape and color. The diameter of freeze dried flowers showed little reduction compared to fresh flowers. In Hunter color values of petals of freeze dried flowers, L and a values were high and showed little variations in comparison to fresh petals. Freeze drying led to a noticeable increase in anthocyanin contents in petals, suggesting that anthocyanin contents play an important role in the acquisition of freezing tolerance. Exposure of flowers to freeze drying was accompanied by an increase in the carotenoid content. In the post-treating freeze drying, epoxy resin, a fixative, applied alone or in combination to petals of freeze dried flowers showed efficient coating for the protection from humidity and sunlight. Combined application of epoxy and acetone to freeze dried petals permitted maintenance of natural color and excellent tissue morphology, showing color stability and shiny texture in surface of petals. These findings suggest that application of fixatives to freeze dried rose petals improves the floral preservation and epoxy coating provides good quality in the freeze dried flower product.

• Applied Chemistry for Engineering
• /
• v.9 no.2
• /
• pp.172-176
• /
• 1998

Epoxy adduct carboxyl terminated butadiene acrylonitrile(CTBN) was prepared by blending of CTBN and epoxy resin. CTBN/PU/epoxy was prepared from polyurethane(PU), epoxy resin, and CTBN. The CTBN/PU/epoxy using 5 wt% of CTBN content showed shifting damping peak as PU content increased. It suggested that CTBN/PU/epoxy had good compatibility for all composition at 5 wt% of CTBN content. But miscibility of CTBN/PU/epoxy decreased with the increase of the CTBN content. PU content for maximum flexural properties of CTBN/PU/epoxy was 10 wt%, but decreased with the increase of the PU content. The fracture toughness of CTBN/epoxy was improved by addition of the PU. Fracture surfaces of CTBN/PU/epoxy showed the shear deformation and generation of stress whitening which is associated with the cavitation. Cavitation in the CTBN and shear defomation in the PU modified epoxy matrix are the toughening mechanisms for CTBN/PU/epoxy.

• Journal of Biomedical Engineering Research
• /
• v.19 no.5
• /
• pp.433-441
• /
• 1998

This study was performed to evaluate the effects of surface flaw on the fracture of all-ceramic materials. A feldspathic porce lain of VMK68, a cashable ceramic of IPS-Empress, and an alumina-glass composite of In-Ceram were used. Specimens were prepared as 12$\times$3$\times$1mm in dimensions, and a Vickers-produced indentation crack was made at the center of the tensile surface. Test specimens were immersed in dlstilled water and In oil, which were broken under a crosshead speed of 0.05 mm/min by 3-point bend test at 37$^{\circ}C$. The characteristic patterns of Vickers indentation and fracture surfaces were examined by an optical microscope and a scanning electron microscope. The fracture surfaces of the VMK68 and the IPS-Empress showed a median crack pattern at the fracture origin and indicated a tendency to cleavage hackle. The fracture surface of the alumina-glass composite, In-Ceram, showed a Palmqvist crack pattern at the fracture origin and indicated a tendency of toughening by the frictional Interlocking between the microstructurally rough fracture surfaces.

• Polymer(Korea)
• /
• v.24 no.2
• /
• pp.245-251
• /
• 2000

A blend system prepared from epoxy(EP) and polyurethane (PU) was investigated in terms of the contact angle and mechanical properties. The contents of EP/PU were varied within 100/0~100/60 phr in the presence of 20 phr DDM (4,4'-diamino diphenyl methane) as a curing agent for epoxy resin. Contact angle measurements were performed employing a Rame-Hart contact angle goniometer. Deionized water and diiodomethane were chosen as the testing liquids. In this work, Owens-Wendt and Wu's models using a geometric mean were studied to analyze the surface free energy of blend system. For the mechanical and toughening properties of the casting specimens, the critical stress Intensity factor ($K_{IC}$) and impact test were performed. Especially, the impact test was carried out at room and cryogenic temperatures. As a result, specific or polar component of the surface free energy of the blend system was largely influenced on the addition of the PU resulting in increasing the impact strength for the excellent low- temperature performance.

• Macromolecular Research
• /
• v.15 no.4
• /
• pp.308-314
• /
• 2007

The effects of a compatibilizer on polypropylene (PP)/poly(acrylonitrile-butadiene-styrene) (ABS) blends were studied. Blends of the PP/ABS, with PP-g-SAN copolymer as a compatibilizer, were prepared using a twin screw extruder. The flexural and impact strength of the PP/ABS blends with the PP-g-SAN copolymer increased significantly with PP-rich compositions on the addition of the PP-g-SAN copolymer at 3 phr. The increase in the mechanical properties of the PP/ABS/PP-g-SAN blend may have been due to the toughening effects of the ABS in the PP-rich compositions. In the morphology study of the PP/ABS/PP-g-SAN (80/20) blend with the PP-g-SAN copolymer, the minimum droplet size, $5.1{\mu}m$, was observed with the addition on phr of the PP-g-SAN copolymer. The complex viscosity of the PP/ABS/PP-g-SAN (80/20) blends increased with the addition of3 phr of the PP-g-SAN copolymer. From the above mechanical properties, morphology and complex viscosity results for the PP/ABS blends, it is suggested that the compatibility is more increased with the PP-rich composition (PP:ABS=80/20 wt%) of the PP/ABS blend on the addition of 3 phr of the PP-g-SAN copolymer.

• Proceedings of the KWS Conference
• /
• 2002.10a
• /
• pp.53-58
• /
• 2002

Electrical insulation and mechanical properties of the plasma sprayed oxide ceramic coatings were studied before and after the sealing treatment of the ceramic coatings. Plasma sprayed A1$_2$O$_3$-TiO$_2$ coating as the reference coating was sealed using three commercial sealants based on polymer. Penetration depth of the sealants to the ceramic coating was evaluated directly from the optical microscope using a fluorescent dye. It is estimated that the penetration depth of the sealants to the ceramic coating is from 0.2 to 0.5 mm depending on the sealants used. The preliminary test results with a DC puncture tester imply that the dielectric breakdown voltage mechanism of plasma sprayed ceramic coatings has been determined to be a corona mechanism. Dielectric breakdown voltage of the as-sprayed and as-ground samples have shown a linear trend with regard to the thickness showing an average dielectric strength of 20 kV/mm for the thickness scale studied. It is also shown that grinding the coating before sealing and adding fluorescent dye do not agent the penetration depth of sealants. All of the microhardness, two-body abrasive wear resistance, bond strength, and surface roughness of the ceramic coating after the sealing treatment are improved. The extent of improvement is different from the sealants used. However, three-point bending stress of the ceramic coating after the sealing treatment is decreased. This is attributed to the reduced micro-crack toughening effect since the cracks propagate easily through the lamellar of the coating without crack deflection and/or branching after the sealing treatment.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.13 no.6
• /
• pp.309-314
• /
• 2003

A spark plasma sintering technique has been used for the fabrication of $Al_2O_3$-SiC nanocomposites at the low temperature of $1100^{\circ}C$∼$1500^{\circ}C$. The sintered $Al_2O_3$-SiC composites shows very homogeneous microstructure without any particular abnormal grain growth, indicating that the addition of nano-sized SiC particles is very effective to control grain growth and to induce the residual stress in the $Al_2O_3$ matrix, resulting in the intragranular fracture. These SiC particles are present in the grain boundaries and also intragrain, depending on the sintering condition, and improve remarkably the mechanical properties of $Al_2O_3$-SiC composite through the mechanisms of strengthening and toughening induced by crack diffraction and crack bridging.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.28 no.3
• /
• pp.170-174
• /
• 2015

Composite ceramics of alumina-TZP(3Y) have good mechanical and electrical properties. So, They have been used as high strength refractory materials and thick film substrates, etc. In this study, Composite ceramics of alumina-TZP(3Y) were fabricated by uniaxial pressing and sintering at 1,400, 1,500, and $1,600^{\circ}C$, and their microstructures and mechanical properties were investigated. As the TZP(3Y) content in composite ceramics increases from 20 wt.% to 80 wt.%, the fracture toughness increases monotonically, which seems to be related to the higher relative density and/or toughening mechanism by means of stabilized tetragonal zirconia phase at room temperature. In contrast to the fracture toughness, Vickers hardness of the composite ceramics shows maximum value (1,938 Hv) at a 40 wt.% of TZP(3Y). The result of Vickers hardness is likely to be due to more dense sintered microstructure of composite ceramics than pure alumina and reinforcement of composite ceramics with TZP(3Y), considering that Vickers hardness of pure $Al_2O_3$ is greater than that of TZP(3Y). It is also shown that the $ZrO_2$ particles are $l^{\circ}Cated$ between $Al_2O_3$ grains and suppress grain growth each other.

• KCI Concrete Journal
• /
• v.12 no.2
• /
• pp.85-93
• /
• 2000

Potentially significant mechanical improvements in tension can be achieved by the incorporation of randomly distributed, short discrete fibers in concrete. The improvements due to the incorporation fibers significantly influence the composite stress - strain ($\sigma$-$\varepsilon$) characteristics. In general incorporating fibers in a plain concrete has relatively small effect on its precracking behavior. It, however, alters its post-cracking behavior quite significantly, resulting in greatly improved ductility, crack controls, and energy absorption capacity (or toughness). Therefore, a thorough understanding the complete tensile stress - strain ($\sigma$-$\varepsilon$) response of fiber reinforced concrete is necessary for proper analysis while using structural components made with fiber reinforced concrete. Direct tensile stress applied to a specimen is in principle the simplest configuration for determining the tensile response of concrete. However, problems associated with testing brittle materials in tension include (i) the problem related to gripping of the specimen and (ii) the problem of ensuring centric loading. Routinely, indirect tension tests for plain concrete, flexural and split-cylinder tests, have been used as simpler alternatives to direct uniaxial tension test. They are assumed to suitable for fiber reinforced concrete since typically such composites comprise 98% by volume of plain concrete. Clearly since the post-cracking characteristics are significantly influenced by the reinforcing parameters and interface characteristics, it would be fundamentally incorrect to use indirect tensile tests for determining the tensile properties of fiber reinforced concrete. The present investigation represents a systematic look at the failure and toughening mechanisms and macroscopic stress - strain ($\sigma$-$\varepsilon$) characteristics of fiber reinforced concrete in the uniaxial tension test. Results from an experimental parametric study involving used fiber quantity, type, and mechanical properties in the uniaxial tension test are presented and discussed.