DOI QR코드

DOI QR Code

Mechanical Characteristics of CF Laminated Prepreg with UV-thermal Dual Curable Epoxy Resin

광·열경화형 수지를 이용한 탄소섬유 프리프레그의 물리적 특성

  • Received : 2016.10.07
  • Accepted : 2016.12.14
  • Published : 2017.03.27

Abstract

An issue of major concern in the utilization of laminated composites based epoxy resin is associated with the occurrence of delaminations or interlaminar cracks, which may be related to manufacturing defects or are induced in service by low-velocity impacts. A strong interfacial filament/brittle epoxy resin bonding can, however, be combined with the high fracture toughness of weak interfacial bonding, when the filaments are arranged to have alternate sections of shear stress. To improve this drawback of the epoxy resin, UV-thermal dual curable resin were developed. This paper presents UV-thermal dual curable resin which were prepared using epoxy acrylate oligomer, photoinitiators, a thermal-curing agent and thermoset epoxy resin. The UV curing behaviors and characteristics of UV-thermal dual curable epoxy resin were investigated using Photo-DSC, DMA and FTIR-ATR spectroscopy. The mechanical properties of UV-thermal dual curable epoxy resin impregnated CF prepreg by UV curable resin content were measured with Tensile, Flextural, ILSS and Sharpy impact test. The obtained results showed that UV curable resin content improves the epoxy toughness.

Keywords

References

  1. D. K. Seo, N. R. Ha, J. H. Lee, H. G. Park, and J. S. Bae, Property Evaluation of Epoxy Resin based Aramid and Carbon Fiber Composite Materials, Textile Coloration and Finishing, 27(1), 11(2015). https://doi.org/10.5764/TCF.2015.27.1.11
  2. J. M. Park, Y. G. Park, Y. H. Lee, D. J. Seo, J. H. Lee, and H. D. Kim, Properties of Randomly Oriented Chopped E-glass Reinforced Unsaturated Polyester based Resin Composite, Textile Coloration and Finishing, 27(3), 165(2015). https://doi.org/10.5764/TCF.2015.27.3.165
  3. Y. J. Park, D. H. Lim, H. J. Kim, D. S. Park, and I. K. Sung, UV- and Thermal-curing Behaviors of Dual-curable Adhesives based on Epoxy Acrylate Oligomers, Adhesion and Adhesives, 29, 710(2009). https://doi.org/10.1016/j.ijadhadh.2009.02.001
  4. K. Dietliker, P. K. T. Oldring, J. Griffith, and J. Guthire, Chemistry and Technology of UV and EB Formulation for Coatings Inks and Paints, SITA Technology, 3(3), 113(1991).
  5. M. Sangermano, S. Pegel, P. Potschke, and B. Voit, Antistatic Epoxy Coatings with Carbon Nanotubes Obtained by Cationic Photopolymerization, Macromolecular Rapid Communication, 29, 396(2008). https://doi.org/10.1002/marc.200700720
  6. D. Kunwong, N. Sumanochitraporn, and S. Kaewpirom, CuringBehavior of a UV-curableCoating based on Urethane Acrylate Oligomer: the Influence of Reactive Monomers, SJST, 33(2), 201(2011).
  7. F. Chen and D. Cook, Curing Kinetics and Morphology of IPNs from a Flexible Dimethacrylate and a Rigid Epoxy via Sequential Photo and Thermal Polymerization, European Polymer J., 44, 1796(2008). https://doi.org/10.1016/j.eurpolymj.2008.03.001
  8. S. Garoushi, P. K. Vallittu, and V. J. Lassila, Short Glass Fiber Reinforced Restorative Composite Resin with Semi-inter Penetrating Polymer Network Matrix, Dental Materials, 23, 1356(2007).
  9. D. Abraham and R. Mcllhagger, Glass Fibre Epoxy Composite Cure Monitoring using Parallel Plate Dielectric Analysis in Comparisonwith Thermal and Mechanical Testing Techniques, Composites Part A, 29A, 811(1998).
  10. Y. C. Kim and B. H. Lee, Synthesis and Characterization of UV-curable Aliphatic Epoxy Acrylate, J. of Adhesion and Interface, 10(4), 191(2009).
  11. G. H. Koo and J. H. Kang, Breathable Waterproof Finish of PET Fabrics via Microporous UV Coating of Polyurethane Diacrylate, Textile Coloration and Finishing, 22(3), 239(2010). https://doi.org/10.5764/TCF.2010.22.3.239
  12. J. Y. Choi, D. J. Lee, and H. D. Kim, Preparation and Properties of UV-Curable Polyurethane Acrylates(I), J. of the Korean Society of Dyers and Finishers, 11(4), 1(1999).
  13. S. M. Krishnan, Studies on Corrosion Resistant Properties of Sacrificial Primed IPNCoating Systems in Comparison with Epoxy-PU Systems, Progress in Organic Coatings, 57, 383(2006). https://doi.org/10.1016/j.porgcoat.2006.09.019
  14. S. Ebnesajjad, "Handbook of Adhesives and Surface Preparation", Elsevier, Nederland, pp.221-243, 2011.
  15. S. Fawzia, R. Al-Mahaidi, and X. Zhao, Experimental and Finite Element Analysis of a Double Strap Joint between Steel Plates and Normal Modulus CFRP, Composite Structures, 75, 156(2006). https://doi.org/10.1016/j.compstruct.2006.04.038
  16. S. H. Kim, H. S. Chang, S. H. Park, and K. G. Song, Study on the Curing Properties of Photo-curable Acrylate Resins, Polymer(Korea), 34(5), 469(2010).