• Metals and materials international
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• v.24 no.6
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• pp.1256-1261
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• 2018

Both thermoplastic formability and electrical conductivity of Al-Ni-Y metallic glass with 12 different compositions have been investigated in the present study with an aim to apply as a functional material, i.e. as a binder of Ag powders in Ag paste for silicon solar cell. The thermoplastic formability is basically influenced by thermal stability and fragility of supercooled liquid which can be reflected by the temperature range for the supercooled liquid region (${\Delta}T_x$) and the difference in specific heat between the frozen glass state and the supercooled liquid state (${\Delta}C_p$). The measured ${\Delta}T_x$ and ${\Delta}C_p$ values show a strong composition dependence. However, the composition showing the highest ${\Delta}T_x$ and ${\Delta}C_p$ does not correspond to the composition with the highest amount of Ni and Y. It is considered that higher ${\Delta}T_x$ and ${\Delta}C_p$ may be related to enhancement of icosahedral SRO near $T_g$ during cooling. On the other hand, electrical resistivity varies with the change of Al contents as well as with the change of the volume fraction of each phase after crystallization. The composition range with the optimum combination of thermoplastic formability and electrical conductivity in Al-Ni-Y system located inside the composition triangle whose vertices compositions are $Al_{87}Ni_3Y_{10}$, $Al_{85}Ni_5Y_{10}$, and $Al_{86}Ni_5Y_9$.

• Elastomers and Composites
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• v.45 no.4
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• pp.245-249
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• 2010

Much interest on the thermoplastic elastomers (TPEs) has recently been attracted in commercial fields as well as scientific and applied research. The TPEs have their own characteristic area especially in relation with block copolymers as well as many other polymeric materials, since they show interesting features displayed by the conventional vulcanized rubber, and at the same time, by the thermoplastics. In addition, they are characterized by a set of interesting properties inherent to block and graft copolymers, variety of blends and vulcanized materials. The importance of TPE as organic materials can be evaluated by the number of published reports (papers, patents, technical reports, etc). For the suitable introduction of the TPE, historic, scientific, technical and commercial considerations should be taken into account. This review article starts with a brief discussion on historical considerations, followed by a introduction of the main preparations and analytical techniques utilized in chemical, structural, and morphological studies. The properties, processing tools, the position among organic materials, and applications of TPEs are also briefly reviewed. Finally, the most probable trends of their future development are discussed in a short final remarks.

• Elastomers and Composites
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• v.45 no.3
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• pp.170-187
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• 2010

Much interest on the thermoplastic elastomers (TPEs) has recently been attracted in commercial fields as well as scientific and applied researches. The TPEs have their own characteristic area especially in relation with block copolymers as well as many other polymeric materials, since they show interesting features displayed by the conventional vulcanized rubber, and at the same time, by the thermoplastics. In addition, they are characterized by a set of interesting properties inherent to block and graft copolymers, variety of blends and vulcanized materials. The importance of TPE as organic materials can be evaluated by the number of published reports (papers, patents, technical reports, etc). The input of the concept 'thermoplastic elastomer' to SciFinderScholar yields 18,508 results between 1939 and July 10, 2010, and the number increased exponentially after the mid of 1990. For the suitable introduction of the TPE, historic, scientific, technical and commercial considerations should be taken into account. This review article starts with a brief discussion on historical considerations, followed by a introduction of the main preparations and analytical techniques utilized in chemical, structural, and morphological studies. The properties, processing tools, the position among organic materials, and applications of TPEs are also briefly reviewed. Finally, the most probable trends of their future development are discussed in a short final remarks.

• Textile Coloration and Finishing
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• v.31 no.4
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• pp.354-362
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• 2019

In order to apply thermoplastic composites using PETG resin to various industrial fields such as bicycle frames and industrial parts, it is necessary to verify the impact resistance, durability and mechanical properties of the manufactured composite materials. To improve the mechanical properties, durability and impact resistance of PETG resin, an amorphous resin, in this study, compound and injection molding process were carried out using various additives such as TiO2, carbon black, polyolefin elastomer, and PETG amorphous resin. The thermal and mechanical properties of the thermoplastic composites, and the Charpy impact strength. The analysis was performed to evaluate the characteristics according to the types of additives. DSC and DMA analyzes were performed for thermal properties, and tensile strength, flexural strength, and tensile strength change rate were measured using a universal testing machine to evaluate mechanical properties. Charpy impact strength test was conducted to analyze the impact characteristics, and the fracture section was analyzed after the impact strength test. In the case of POE material-added thermoplastic composites, thermal and mechanical properties tend to decrease, but workability and impact resistance tend to be superior to those of PETG materials.

• Composites Research
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• v.37 no.2
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• pp.68-75
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• 2024

Polypropylene (PP), a thermoplastic resin with excellent mechanical, thermal, chemical, and water resistance properties, has been attracting attention due to its economic efficiency and recyclability. However, repeated processing of thermoplastic resins can lead to property degradation, and the point at which quality degradation occurs varies depending on the processing conditions. In this study, we evaluated the performance changes of composite materials with repeated processing by blending PP resin with various additives and conducting extrusion and injection processes repeatedly. In addition, we evaluated the mechanical properties of composite materials to evaluate the effect of MFI value change during repeated processing on fiber impregnation in composite material processing.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.15 no.5
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• pp.1-7
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• 2016

In the present study, a plastic surface end-milling was implemented to investigate the effects of processing parameters on surface quality. The end milling can be considered an efficient method for rapid prototyping of thermoplastic bio-systems since it exhibits several beneficial functions including short fabrication time and high dimensional accuracy. In this regard, putative biocompatible thermoplastic materials, such as PMMA, PET, and PC, were chosen as workpiece materials. Among the relevant processing parameters influencing the surface quality of the final product, depth of cut, feed rate, and spindle speed were considered in the present study. The roughness of surfaces machined under various conditions was measured to elucidate the effect of each parameter. We found that the cut depth was the most significant factor. Heat generation during machining also had a remarkable effect. From these investigations, an appropriate combination of processing conditions specific to each type of use and end-product could be found. This optimization can be useful in end-milling of thermoplastic bio-systems.

• Journal of the Korean Society of Radiology
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• v.15 no.2
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• pp.181-189
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• 2021

This study is a prior research to manufacture a thermoplastic mask, which is a fixture used in radiation therapy, by 3D printing. It proceeded to analyze the filament material that can replace the thermoplastic. Among the commercially available filament materials, a material having similar characteristics to that of a thermoplastic mask was selected and the radiation dose was compared and analyzed. The experiment used Monte Carlo simulation. The shape in which the mask fixed the head was simulated for the ICRU sphere. The photon fluence was calculated at the skin Hp (0.07), the lens Hp (3), and the whole body Hp (10) by applying a thermoplastic plastic material and a filament material. As a result, when looking at the relative dose based on the thermoplastic plastic material, the difference was approximated within 4%. The material showing the most similar dose was PA-nylon. In selecting an appropriate filament material, it should be selected by comprehensively considering various conditions such as economical efficiency and radiation effects. It is thought that the results of this study can be used as basic data.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.05a
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• pp.122-125
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• 2001

The objective of this research is to develop hybridized yarns for thermoplastic composites, and to examine tile effect of cooling rate on mechanical properties of the composites. The co-braided yarn utilizing carbon fibers as reinforcements and Nylon 66 fibers as matrix materials has been fabricated. Thermoplastic composites have been manufactured by the hot-press forming process. For the processing conditions, cooling rates of $-2.5^{\circ}C$/min and $-60^{\circ}C$/min have been considered. Three-point bending test and losipescu shear test were performed to investigate the effect of the cooling rate and the surface treatment of carbon fibers. SEM photographs were used to investigate the fracture surfaces of the tested samples. The cooling rate of $-60^{\circ}C$/min resulted in the higher strength and elastic modulus for bending and shear tests. The composites of the epoxy-sized carbon fibers showed the lowest strength due to the degradation of the sizing material during the thermoforming process.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.10a
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• pp.29-32
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• 2001

The objective of this work was to optimize processing parameters of hybrid thermoplastic composites in compression molding. The mechanical properties of the composites manufactured with various forming conditions were measured to characterize processing parameters. Polypropylene(PP) composites containing randomly oriented long carbon fiber and carbon black were used in this work. The composite materials contained 5%, 10%, 15%, and 20% carbon fiber and 5%, 10%, 15%, 20%, and 25% carbon black by weight. Compression molding was conducted at various mold temperatures. The temperature of the material in the mid-plain was monitored during the forming. Crystallinity was also measured by using XRD. The tensile modulus of the composites increase, with increasing the mold temperature. However, the impact strength of the composites decreases as mold temperature increases.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1997.04a
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• pp.513-517
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• 1997

Glass fiber reinforced thermoplastic composite materials have considerable promise for increased use in low cost high volum applications because of the potential for processing by solid phase forming. However, the forming characteristics of these materials have not been well known. The primary focus of this research is the investigation of the bendability of these composites and spring-back phenomena in pure bending. The materials tested contained 10, 35, and 40 percent by weight of randomly oriented glass fiber in a polypropylene matrix. The bending tests were performed at temperatures ranging form 75 ".deg. c" to 150 ".deg. c" and at punch speeds of 2.54 mm/sec and 0.0254 mm/sec. The measured bendability and spring back angle in pure bending werw compared with the predictions based on the simple analyical models. Goog agreement between experimental and analytical results was observed.esults was observed.