• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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• pp.323-324
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• 2005

To found out the degradation characteristic of transformer insulation, insulation materials and electrodes are deposited into transformer oil. They used to heated and make flashover. Due to the thermal and electrical stress added to insulation materials, the density of carbon dioxide and hydrogen included in transformer oil was increased. The gas density can measured by using the gas density detection equipment of gas sensor and air circulation method.

• Environmental Engineering Research
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• 제17권3호
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• pp.157-165
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• 2012

This experimental study was performed to obtain thermal energy from the combustion of synthetic gas, produced by the pyrolysis of insulating oil containing polychlorinated biphenyls (PCBs) in a high temperature and high pressure reactor. The average synthetic gas generated was $59.67Am^3/hr$ via the steady state gasification of insulating oil waste (20 kg/hr) with average concentrations (standard deviation) of $CO_2$, CO, and $H_2$ in the synthetic gas of $38.63{\pm}3.11%$, $35.18{\pm}1.93%$, and $28.42{\pm}1.68%$, respectively. The concentrations of the PCBs in the transformer insulating oil and synthetic gas after its gasification, and the concentrations of the dioxins that could be produced from the incomplete degradation of PCBs were measured. It was revealed that the PCBs in the insulating oil were composed of the series from tetrachlorobiphenyl to octachlorobiphenyl. However, only the #49, #44, #52, and #47/75/48 congeners were detected from the synthetic gas after gasification of the insulating oil and in the flue gas from the combustor. In conclusion, the experimental conditions suggested in this study were very useful for the appropriate treatment of insulating oil containing PCBs. Also, fuel gas containing CO and $H_2$ can be obtained from the pyrolysis of insulating oil containing PCBs.

• Journal of Electrical Engineering and Technology
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• 제10권3호
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• pp.1114-1123
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• 2015

Bushing is the key link to connect outer and inner insulating systems and also the essential electric accessory in electric power system, especially in the high voltage engineering (AC 1000kV, DC 800kV). This paper presented the experimental research of thermal aging characteristic of oil-paper insulation used in bushing. A thermally accelerated aging experiment at 90℃ was performed. The bushing models containing five layers of paper were sealed into the aging vessels and further aged for 250 days. Then several important parameters associated with the aging were observed and evaluated. The results showed that the degree of polymerization (DP) of papers gradually decreased. The DP values of outermost layer and middle layer fit well into the second-order kinematic model and first-order kinematic model, respectively. Less deterioration speed of the inter-layer paper than outer layer was confirmed by the variation of DP. Hydrolysis was considered as the main cause to this phenomenon. In addition, the logarithm of the furfural concentrations in insulation oil was found to have good linear relationship with DP of papers. Interestingly, when the aging time is about 250 days and DP is 419, the aging process reaches an inflection point at which the DP approaches the leveling off degree of polymerization (LODP) value. Both tanδ and acid number of oils increased, while surface and volume resistivity of papers decreased. The obtained results demonstrated that thermal aging and moisture absorbed in papers brought great influence to the degradation of insulating paper, leading to rapid decrease of DP and increase of the tanδ. Thus, the bushing should be avoided from damp and real-time monitoring to the variation of tanδ and DP values of paper is an effective way to evaluate the insulation status of bushing.

• Elastomers and Composites
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• 제55권1호
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• pp.59-66
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• 2020

Herein, we investigated the thermal conductivity and thermal stability of natural rubber composite systems containing hybrid fillers of boron nitride (BN) and aluminum nitride (AlN). In the hybrid system, the bimodal distribution of polygonal AlN and planar BN particles provided excellent filler-packing efficiency and desired energy path for phonon transfer, resulting in high thermal conductivity of 1.29 W/mK, which could not be achieved by single filler composites. Further, polyethylene glycol (PEG) was compounded with a commonly used naphthenic oil, which substantially increased thermal conductivity to 3.51 W/mK with an excellent thermal stability due to facilitated energy transfer across the filler-filler interface. The resulting PEG-incorporated hybrid composite showed a high thermal degradation temperature (T₂) of 290℃, a low coefficient of thermal expansion of 26.4 ppm/℃, and a low thermal distortion parameter of 7.53 m/K, which is well over the naphthenic oil compound. Finally, using the Fourier's law of conduction, we suggested a modeling methodology to evaluate the cooling performance in thermal management system.

• KEPCO Journal on Electric Power and Energy
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• 제2권3호
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• pp.447-452
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• 2016

It is imperative to develop an effective pathway to depolymerize lignin into liquid fuel that can be used as a bioheavy oil. Lignin can be converted into liquid products either by a solvent-free thermal cracking in the absence air, or thermo-chemical degradation in the presence of suitable solvents and chemicals. Here we show that the solvent-assisted liquefaction has produced promising results in the presence of metal-based catalysts. The supercritical ethanol is an efficient liquefaction solvent, which not only provides better solubility to lignin, but also scavenges the intermediate species. The concentrated sulfuric acid hydrolysis lignin (CSAHL) was completely liquefied in the presence of solid catalysts (Ni, Pd and Ru) with no char formation. The effective deoxy-liquefaction nature associated with scEtOH with aid hydrodeoxygenation catalysts, resulted in significant reduction in oxygen-to-carbon (O/C) molar ratio up to 61%. The decrease in oxygen content and increase in carbon and hydrogen contents increased the calorific value bio-oil, with higher heating value (HHV) of $34.6MJ{\cdot}Kg^{-1}$. The overall process is energetically efficient with 129.8% energy recovery (ER) and 70.8% energy efficiency (EE). The GC-TOF/MS analysis of bio-oil shows that the bio-oil mainly consists of monomeric species such as phenols, esters, furans, alcohols, and traces of aliphatic hydrocarbons. The bio-oil produced has better flow properties, low molecular weight, and high aromaticity.

• 조명전기설비학회논문지
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• 제12권2호
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• pp.15-20
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• 1998

본 연구에서는 주상변압기용 절연유를 대상으로 가속 열화 실험을 수행하면서 절연유의 전기적 특성값인 유전정접과 절연유내의 금속의 양과 절연지의 분해로 생성되는 푸루푸랄양을 조사 연구하였다. 유전정접은 절연유에 변압기 구성재료가 모두 포함된 경우에 많은 영향을 받는 것으로 나타났다. 절연유의 산화에 촉매 작용을 하는 금속의 양을 측정한 결과, 구리의 양은 열화 시간이 지남에 따라서 증가하는 것을 볼 수 있었다. 유전정접과 구리측정값을 비교하여 볼 때 구리측정값이 0.2[ppm] 이상 되면 요주의 범위에 속하는 것으로 볼 수 있다. 푸루푸랄의 양을 측정한 결과 열화시간이 지남에 따라서 푸루푸랄의 양이 증가하는 경향을 보여주었다. 본 연구 결과로 볼 때 주상변압기 예방진단기초자료로 충분히 활용할 수 있었다.

• 전기학회논문지
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• 제59권5호
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• pp.912-917
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• 2010

It was known that oil-filled transformer's life depended on insulating paper which was applied to transformers for insulating of transformer. Therefore when paper was aged, its electrical, mechanical and chemical characteristics were changed. Especially if operating temperature was high, paper was quickly damaged. As cellulose paper which was mainly used for solid insulation of transformers was degraded, the cellulose polymer chains broke down into shorter lengths and gases such as CO, $CO_2$, $CH_4$, $C_2H_4$ and so on were produced from paper. Also by-product known as furan compounds were producted from paper and it were dissolved within insulating oil. In this paper accelerating aging cell was aged during 60 hours at 100, 150, 180 and $200^{\circ}C$, respectively, so evaluating the chemical characteristics of cellulose paper by thermal. An it were performed analysis such as tensile strength(TS), dissolved gas analysis(DGA) and high performance liquid chromatography(HPLC). Also for analyzing of correlation between insulating degradation characteristics, it was performed linear regression method as statistical treatment.

• 한국환경과학회지
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• 제13권4호
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• pp.403-412
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• 2004

Waste water-soluble cutting oil was treated with WI type #1 and WI type #2. The properties of the original water-soluble cutting oil were pH=l0.4, viscosity=1.4cP, CODcr=44,750 ppm, and TOC=10,569 ppm. However, the properties of the oil used for more than 3 months were changed to pH=7.82, viscosity=2.1cP, CODcr=151,000 ppm, and TOC=74,556 ppm. It might be attributed to the fact that molecular chains were cut due to thermal oxidation and impurities such as metal chips were incorporated in to the oil during the operation processes. To prevent the putrefaction of oil, the sterilization effect of ozone and UV on the microorganism in the oil was investigated. Ozone treatment showed that 99.99% of the microorganism was annihilated with 30 minutes contact time and 60 minutes were necessary for the same effect when UV was used. Ozone treatment could cut molecular chains of the oil due to strong sterilization power, which was evidenced by the increase of TOC from 25,132 ppm at instantaneous contact to 28,888 ppm at 30 minutes contact time. However, UV treatment didn't show severe changes in TOC values and thus, seemed to cause of severe cut of molecular chains. When the activated carbon was used to treat the waste water-soluble cutting oil, TOC decreased to 25,417 ppm with 0.lg carbon and to 15,946 ppm with 5.0g carbon. This results indicated that the waste oil of small molecular chains could be eliminated by adsorption. From the results, it could be concluded that these treatment techniques could be proposed to remove the waste oil of small molecular chains resulting in the degradation of the oil properties. In addition, these experimental results could be used for the correlation with future works such as investigation of the molecular distribution according to the sizes, lengths, and molecular weight of the chains.

• 한국해양환경ㆍ에너지학회지
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• 제15권1호
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• pp.19-21
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• 2012

내연 기관의 엔진오일은 열화작용에 의해서 수명이 짧아지고 대기오염을 유발하게 된다. 엔진오일의 상태를 정확히 측정하여 새오일로 교환함으로 엔진의 수명 연장 및 환경오염을 줄일 수 있다. 정전용량 프로브는 엔진오일과 같은 유체의 유전율을 측정하는데 사용 할 수 있다. 본 논문은 엔진 오일의 열화 정도에 따라서 달라지는 유전율 특성을 분석하였다. 오일의 상태에 따라서 달라지는 프로브의 정전용량을 각각 LCR Meter로 측정하여 엔진오일의 유전율을 계산하였다. 또한, 프로브의 크기에 따른 정전용량의 변화를 측정하여 유전율 측정의 정확도를 제시한다. 오염된 오일 일수록 유전율이 증가하며, 유전율로 오일의 오염정도를 판단하는 것이 가능하다.

• 한국식품과학회지
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• 제40권6호
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• pp.611-620
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• 2008

달걀 노른자에 함유된 인지질 중 PC와 PE를 추출, 분리하고 이를 토코페롤을 제거한 TSCO에 0, 200, 500, 2,000 ppm의 농도로 단독으로, 또는 1,000 ppm씩 혼합하여 첨가한 후 $180^{\circ}C$에서 12시간 동안 가열하여 함유된 인지질의 함량변화와 TSCO의 갈색화 정도를 살펴보고, TSCO의 가열산화에 미치는 영향을 지방산 조성, 공액이중산값, 아니시딘값으로 평가하였다. TSCO에 첨가된 인지질은 가열 시작 후 2-3시간 내에 매우 빠르게 소실되었고, 가열 중 PE의 분해속도가 PC에 비해 높았다. PC와 PE가함께 첨가된 TSCO를 가열할때 PE는 PC의 분해를 억제하였다. TSCO는 가열 시간이 증가함에 따라 갈색화가 증가하였고, PC와 PE는 갈색화를 촉진하였으며 PE가 PC보다 큰 영향을 주었다. 가열 중 TSCO의 P/L, P/Ln, 공액이중산값, 아니시딘값은 증가하였으며, PC의 첨가는 이들 값을 낮추어 가열 카놀라유의 산화방지제 역할을 하였으나 PE는 큰 영향을 나타내지 않았으며, PC와 PE는 TSCO의 가열산화 억제에 있어서 antagonism이 관찰되었다.