• Journal of Electrochemical Science and Technology
• /
• v.10 no.2
• /
• pp.196-205
• /
• 2019

Ni-rich layered oxides $Li(Ni_xCo_yMn_z)O_2$ (x + y + z = 1) have been extensively studied in recent times owing to their high capacity and low cost and can possibly replace $LiCoO_2$ in the near future. However, these layered oxides suffer from problems related to the capacity fading, thermal stability, and safety at high voltages. In this study, we use surface coating as a strategy to improve the thermal stability at higher voltages. The uniform and conformal $Al_2O_3$ coating on prefabricated electrodes using atomic layer deposition significantly prevented surface degradation over prolonged cycling. Initial capacity of 190, 199, 188 and $166mAh\;g^{-1}$ is obtained for pristine, 2, 5 and 10 cycles of ALD coated samples at 0.2C and maintains 145, 158, 151 and $130mAh\;g^{-1}$ for high current rate of 2C in room temperature. The two-cycle $Al_2O_3$ modified cathode retained 75% of its capacity after 500 cycles at 5C with 0.05% capacity decay per cycle, compared with 46.5% retention for a pristine electrode, at an elevated temperature. Despite the insulating nature of the $Al_2O_3$ coating, a thin layer is sufficient to improve the capacity retention at a high temperature. The $Al_2O_3$ coating can prevent the detrimental surface reactions at a high temperature. Thus, the morphology of the active material is well-maintained even after extensive cycling, whereas the bare electrode undergoes severe degradation.

• Journal of the Korean Solar Energy Society
• /
• v.34 no.6
• /
• pp.19-25
• /
• 2014

Alternative sources of energy take a higher interest in order to reduce the greenhouse gas under the Climate Change Convention, fossil fuel consumption, and lower social anxiety about nuclear power such as crisis involving the Fukushima plant, problem of obsolete equipment. The energy consumption of agriculture, forestry and fisheries in South Korea is 3,082,000toe by 2011, reliance on electrical energy(35%) and oil(57.2%) is very high with 92.2%. In this study, we examined reserves and available capacity of temperature difference energy for thermal discharge from plant, treated sewage, river water, dam, and agricultural reservoir in rural community. Reserves of unutilized energy are 455,735Tcal/yr in rural community, these accounts for 78% of total reserves 582,385Tcal/y. Thermal discharge from plant has the most reserves of unutilized energy in rural community, it is estimated that it has the reserves of 277,410Tcal/y. Available capacity of unutilized energy in rural community is total 134,147Tcal/y, thermal discharge from plant available for heating is the most 128,035Tcal/y, and it shows in the order of treated sewage 4,318Tcal/y, river water 1,653Tcal/y, and reservoir 141Tcal/y. Elevating temperature area of green house by 2012 is 21,208ha. The amount of energy required for heating the greenhouse a year is dbout 11,365Tcal/y with 8.5% of the total available capacity of unutilized energy.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2010.09a
• /
• pp.263-268
• /
• 2010

Thermal characterization of geomaterials has significant implication on the geothermal energy, disposal of nuclear wastes, geological sequestration of carbon dioxides and recovery of hydrocarbon resources. Heat transfer in multiphase materials is dominated by the thermal conductivity of consisting components, porosity, degree of saturation and overburden pressure, which have been investigated by the empirical correlation at macro-scale. The thermal measurement by Transient Plane Source (TPS) and associated algorithm for interpretation of thermal behavior in geomaterials corroborate the robustness of sensing techniques. The method simultaneously provides thermal conductivity, diffusivity and volumetric heat capacity. The newly introduced thermal network model enables estimating thermal conductivity of geomaterials subjected to the effective stress, which has not been evaluated using previous thermal models. The proposed methods shows the applicability of reliability of TPS technique and thermal network model.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.57 no.11
• /
• pp.1922-1928
• /
• 2008

The thermal rating of a conductor are maximum continuous current capacity and short time emergency current capacity. The overload operation for a faults have an effect on a conductor lifetime. Its time duration and overload level are limited to facility conditions of transmission lines. The short time emergency current capacity in KOREA observe the KEPCO's DESIGN RULE 1210, but its rules are not included to concept of an allowable short time duration. This papers are described to the calculation concept of short time emergency current capacity considering a time duration and an overload level. And we suggested a operation grouping and its maximum conductor temperature considering facility conditions - conductor lifetime, stability of connection points, conductor height above ground and clearance, in the operating and new T/L.

• Journal of Environmental Health Sciences
• /
• v.29 no.2
• /
• pp.45-49
• /
• 2003

In this study, lots of methods have been studing to utilize energy and decrease contaminated effluents. There has been great progress on IGCC (Integrated gasification combined cycle) to reduce thermal energy losses. The following results have been conducted from desulfurization experiments using waste shell to remove H$_2$S. According to TGA results, temperature had influenced on H$_2$S removal efficiency. As desulfurization temperature increased, desulfurization efficiency increased. Also, maximum desulfurization efficiency was observed at 80$0^{\circ}C$. Desulfurization was related to calcination temperature. Considering temperature ranges of exhausted gas from hot gas gasification equipment were 400~80$0^{\circ}C$. Thus, desulfurization efficiency would be increased desulfurization temperature situation at highly. Experiments by TGA showed that particle size of sorbents had influenced on desulfurization capacity. Maximum desulfurization capacity was observed at 0.631 mm for oyster and clam. Rest of sorbents showed similar capacity within 0.171~0.335 mm particle size range. So, particle size would be considered. When would be used waste shells as IGCC sorbents. According to the results about desulfurization capacity by TGA, oyster had the best desulfurization capacity among limestone and waste shell. We would be identify to substituted oyster for existing sorbents

• Journal of IKEEE
• /
• v.16 no.1
• /
• pp.1-6
• /
• 2012

Thermal rating or lifetime evaluation for aged overhead transmission line becomes more important concerns with respect to keeping power delivery stable having proper capability. Both load rating and dip/clearance are essential factors to determine transmission capacity. In order to evaluate thermal rating and conductor lifetime for domestic transmission lines with double-circuit, the dip/ground clearance standards as well as the electrical equipment technical standard are examined. Conductor temperature and dip are calculated under the assumption of a contingency, and then, a method to up-rate load capacity is searched. As thermal rating and limit dip for aged conductor are properly evaluated, an improved strategy in order to guarantee the existing power system reliability is presented in this paper.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.30 no.12 s.255
• /
• pp.1543-1550
• /
• 2006

Since the performance of joints usually determines the structural efficiency of composite structures, an extensive knowledge of the behavior of adhesive joints and the related effect on joint strength is essential for design purposes. In this study, the torque capacity of adhesive joints was predicted using the combined thermal and mechanical analyses when the adherend was a composite tube. A finite element analysis was performed to evaluate residual thermal stresses developed in the joint, and mechanical s stresses in the adhesive were calculated including both the nonlinear adhesive behavior and the behavior of composite tubes. Three different joint failure modes were considered to predict joint failure: interfacial failure, adhesive bulk failure, and adherend failure. The influence of the composite adherend stacking angle on the residual thermal stresses was investigated, and how the residual thermal stresses affect the joint strength was also discussed. Finally, the predicted results were compared with experimental results available in literature.

• KEPCO Journal on Electric Power and Energy
• /
• v.5 no.3
• /
• pp.215-222
• /
• 2019

This work is experimental study of 10 kW specialized Combined Ocean Thermal Energy Conversion. We propose a C-OTEC technology that directly uses exhaust thermal energy from power station condensers to heat the working fluid (R134a), and tests the feasibility of such power station by designing, manufacturing, installing, and operating a 10 kW-pilot facility. Power generation status was monitored by using exhaust thermal energy from an existing power plant located on the east coast of the Korean peninsula, heat exchange with 300 kW of heat capacity, and a turbine, which can exceed enthalpy efficiency of 45%. Output of 8.5 kW at efficiency of 3.5% was monitored when the condenser temperature and seawater temperature are $29^{\circ}C$ and $7.5^{\circ}C$, respectively. The evaluation of the impact of large-capacity C-OTEC technology on power station confirmed the increased value of the technology on existing power generating equipment by improving output value and reducing hot waste water. Through the research result, the technical possibility of C-OTEC has been confirmed, and it is being conducted at 200 kW-class to gain economic feasibility. Based on the results, authors present an empirical study result on the 200 kW C-OTEC design and review the impact on power plant.

• Journal of Information Processing Systems
• /
• v.15 no.2
• /
• pp.386-398
• /
• 2019

The transmission capacity of transmission lines is affected by environmental parameters such as ambient temperature, wind speed, wind direction and so on. The environmental parameters can be measured by the installed measuring devices. However, it is impossible to install the environmental measuring devices throughout the line, especially considering economic cost of power grid. Taking into account the limited number of measuring devices and the distribution characteristics of environment parameters and transmission lines, this paper first studies the environmental parameter estimating method of inverse distance weighted interpolation and ordinary Kriging interpolation. Dynamic thermal rating of transmission lines based on IEEE standard and CIGRE standard thermal equivalent equation is researched and the key parameters that affect the load capacity of overhead lines is identified. Finally, the distributed thermal rating of transmission line is realized by using the data obtained from China meteorological data network. The cost of the environmental measurement device is reduced, and the accuracy of dynamic rating is improved.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.20 no.3
• /
• pp.357-364
• /
• 2022

The safety of a KTC-360 transport cask, a large-capacity pressurized heavy-water reactor transport cask that transports CANDU spent nuclear fuel discharged from the reactor after burning in a pressurized heavy-water reactor, must be demonstrated under the normal transport and accident conditions specified under transport cask regulations. To confirm the thermal integrity of this cask under normal transport and accident conditions, high-temperature and fire tests were performed using a one-third slice model of an actual KTC-360 cask. The results revealed that the surface temperature of the cask was 62℃, indicating that such casks must be transported separately. The highest temperature of the CANDU spent nuclear fuel was predicted to be lower than the melting temperature of Zircaloy-4, which was the sheath material used. Therefore, if normal operating conditions are applied, the thermal integrity of a KTC-360 cask can be maintained under normal transport conditions. The fire test revealed that the maximum temperatures of the structural materials, stainless steel, and carbon steel were 446℃ lower than the permitted maximum temperatures, proving the thermal integrity of the cask under fire accident conditions.