• Title/Summary/Keyword: Thermal Aging

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A Study on Acceleration Aging Characteristics of B-KNO3 Igniter (B-KNO3 점화제의 가속 노화 특성 연구)

  • Paik, Jong Gyu;Ryu, Byung Tae;Kwon, Mira
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.166-174
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    • 2014
  • This research investigated the aging properties of the $B-KNO_3$ system as the igniter. The $B-KNO_3$ system showed the degradation in ignition properties depending on the method and period of storage. It should be found out the cause of the degradation to predict the reliability of the igniters. The changes of the properties by the degradation after aging tests were analyzed by microstructure analysis, XRD analysis and thermal analysis using DSC. It was found out that the lattice parameters of the $KNO_3$ as the oxidizer in the ignition system was changed into the JCPDS values as the aging time increased. Conclusively, the changes of the crystal structure of oxidizer affected the activation energy increasing as aging time increased.

Research of Accelerated Aging According to Long-term Stability of Vegetable Oil (식물성절연유의 가속열화에 따른 장기적 안정성 분석)

  • Choi, Sun-Ho;Huh, Chang-Su
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.8
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    • pp.1148-1152
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    • 2012
  • The vegetable-based insulating oils are substitutes for mineral oils in oil-filled transformer. The important properties of vegetable insulating oil is their higher flash/fire point and biodegradability than conventional mineral oils. The large oil-filled transformer eliminate the risk of explosion and fire should the transformer fail and oil ignite owing to high flash/fire point of vegetable insulating oil. In addition, higher biodegradability of vegetable insulating oils can let the oil spill damage reduced. In this experiment, the real oil-filled transformers using mineral oil and vegetable oil have accelerated aging. After working on the 100% accelerated aging experiment were conducted comparing the transformer. The hottest-spot temperature using thermal coefficients were calculated to determin the degree of accelerated aging. As a result, apply mineral oil transformer in accordance with the accelerated aging life come to an end. In contrast, vegetable insulating oils showed the opposite characteristics. Vegetable insulating oil compared to the mineral oil are found to be an long life. As a result, the vegetable oil has a long-term stability.

Natural Aging Properties Analysis of HTPB Propellant (HTPB계 고체추진제의 자연노화 물성 분석)

  • Park, Jung-Ho;Ryu, Nam-Sun;Park, Jae-Beom;Jung, Gyoo-Dong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.9-14
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    • 2019
  • Hydroxy-terminated polybutadiene (HTPB) propellants of solid rocket motors age differently under different storage temperatures. The shelf life of a solid rocket motor depends on the aging ratio of the HTPB propellant; it can be estimated through the viscoelastic properties by an aging test. This study analyzed the initial and natural aging properties during long-term storage. The initial properties were obtained from characterization and accelerated test results. The test results were obtained by analyzing the strain on cylindrical grains when a thermal load was applied.

Effect of Exhaust Heat Exchanger on Catalytic Converter Temperature in an SI Engine (가솔린 엔진의 배기 열교환기가 촉매 온도에 미치는 영향에 관한 연구)

  • 이석환;배충식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.2
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    • pp.9-16
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    • 2004
  • Close-coupled catalyst (CCC) can reduce the engine cold-start emissions by utilizing the energy in the exhaust gas. However, in case the engine is operated at high engine speed and load condition, the catalytic converter may be damaged and eventually deactivated by thermal aging. Excess fuel is sometimes supplied intentionally to lower the exhaust gas temperature avoiding the thermal aging. This sacrifices the fuel economy and exhaust emissions. This paper describes the results of an exhaust heat exchanger to lower the exhaust gas temperature mainly under high load conditions. The heat exchanger was installed between the exhaust manifold and the inlet of close-coupled catalytic converter. The exhaust heat exchanger successfully decreased the exhaust gas temperature, which eliminated the requirement of fuel enrichment under high load conditions. However, the cooling of the exhaust gas through the heat exchanger may cause the deterioration of exhaust emissions at cold start due to the increment of catalyst light-off time.

Development of Preventive Diagnosis Techniques for Transformer Oil by Capacitive Sensor (전기용량형 센서를 이용한 변압기 절연유 열화진단용 예방진단기법 개발)

  • Kim, Ju-Han;Han, Sang-Ok
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.2061_2062
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    • 2009
  • Within serviced period of time in transformer, thermal stress is the most influential parameter affecting the aging behavior of an insulation system. The thermal stress on the insulation system may occur from operation in a high temperature environment due to Joule's heat at winding coils. This paper describes a development of capacitive sensor and preventive diagnosis techniques for electrical insulating oil, widely used for power and distribution transformer. To survey the dielectric properties of the virgin and used mineral insulating oil, we utilized the highly precise measuring system of KRISS. And the results were used to determine the design factors of the sensor. To evaluate diagnosis by the sensor, we performed accelerated aging test about insulating oils. The condition of aged specimens were investigated by measurements of relative permittivity i.e. capacitance change by capacitive sensor.

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Behaviors of Mechanical Properties of Filament-Winding-Laminated Composites due to Environmental Aging (필라멘트 와인딩 복합재의 환경노화에 따른 기계적물성 평가)

  • Choi Nak-Sam;Yun Young-Ju;Lee Sang-Woo;Kim Duck-Jae
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.31-35
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    • 2006
  • Degradation characteristics of filament-winded composites due to accelerated environmental aging have been evaluated under high temperature, water immersion and thermal impact conditions. Two kinds of laminated composites coated by an urethane resin have been used: carbon-fiber reinforced epoxy(T700/Epon-826, CFRP) and glass-fiber reinforced phenolic (E-glass/phenolic, GFRP). For tensile strength of $0^{\circ}$ composites, CFRP did high reduction by 25% under the influence of high temperature and water while CFRP showed little degradation. However for water-immersed $90^{\circ}$ composites both CFRP and GFRP showed high reduction in tensile strength. Bending strength and modulus of $90^{\circ}$ composites were largely reduced in water-immersion as well as high temperature environment. Urethane coating on the composite surface improved the bending properties by 20%, however hardly showed such improvement for water-immersed $90^{\circ}$ composites.

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Evaluation of Strength Characteristics of HoneyComb Sandwitch Structure Due to the Repeated Curing Cycle in Repair Process (하니콤 샌드위치 구조물의 수리 시 반복 경화에 따른 강도 특성 평가)

  • 손영준;이기현;김국진;한중원;김윤해
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.83-87
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    • 2002
  • Aerospace industries are widely using honeycomb sandwich structures that it has high specific strength and stiffness, chemical material resistance and fatigue resistance. But, in repairing process of damaged areas, one of the problems is that delamination can be occurred in the sound areas during and/or after the exposure to the elevated curing temperature in case that the repair process is repeated. Therefore, this study was conducted Flatwise tensile, Drum peel and Long beam flexural strength tests to evaluate the degree of degradation of mechanical properties of the honeycomb sandwich structures by affecting thermal aging. As the results, the decrease of mechanical strength was observed at the specific specimen which is exposed over 50hrs at $127^{\circ}C$.

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Environmental aging characteristics of carbon/epoxy composite for train carbody (철도차량 차체용 탄소섬유/에폭시 복합재의 환경노화 특성 평가)

  • Oh, Jin-Oh;Yoon, Sung-Ho;Kim, Jung-Suk;Han, Seong-Ho
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.824-829
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    • 2007
  • Mechanical and thermal analysis properties of carbon fiber/epoxy composite for train carbody were evaluated by varying with environmental factors such as ultraviolet, temperature, and moisture. Accelerated environmental aging tester was utilized for this study. Testing temperature was set to $80^{\circ}C$ and ultraviolet was obtained through xenon-arc lamp. To consider moisture, water sprayed on specimen for 18 minutes every 2 hour. All the specimens were made of CF1263/Epoxy composite. Mechanical properties such as tensile, bending, and shear properties were evaluated through a material testing system. Also, thermal analysis properties such as storage shear modulus, loss shear modulus, and tan ${\delta}$ were measured through dynamic mechanical analyzer. Finally surfaces of the composite exposed to environmental factors were examined using a scanning electron microscope. From experimental results, those properties of CF1263/Epoxy composite were shown to be slightly decreased due to environmental factors.

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De-NOx Characteristics of V2O5 SCR according to the Ratio of TiO2 Crystal Structures

  • Seo, Choong-Kil;Bae, Jaeyoung
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.26-32
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    • 2015
  • The purpose of this study is to investigate the de-NOx performance characteristics according to the $TiO_2$ crystal structures ratio of $V_2O_5$ SCR catalysts. The anatase(100%) SCR catalyst showed the highest desorption peak of 80ppm at about $250^{\circ}C$, and $NH_3$ was not desorbed at $500^{\circ}C$. It can be confirmed that there was many $NH_3$ desorbed at a high temperature among other various crystal structures, which is because the catalyst was more acidized to increase the intensity of acid sites as the content of subacid sulfate ions($NH_2SO_4$) in the rutile phase increases. The anatase/rutile(7%/93%) SCR had the smallest width of de-NOx performance drop according to thermal aging, and had strong durability against thermal aging.

Analysis of Photovoltaic module's Phenomena of aging with Acceleration Test (외부환경적 가속시혐에 의한 PV모듈의 열화성능 분석)

  • Kang, Gi-Hwan;Kim, Kyung-Soo;Park, Chi-Hong;Yu, Gwon-Jong;Ahn, Hyung-Gun;Han, Deuk-Young
    • Proceedings of the KIEE Conference
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    • 2006.07b
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    • pp.1151-1152
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    • 2006
  • In this paper, we examined 10 domestic samples of three different model using thermal, humidity freeze, thermal-endurance and damp heat test under IEC61215 photovoltaic module environmental endurance test condition. Three was almost no changes on power generation. Insulation resistance capacity was much higher than judgement standard but, showed unstable results depending on environmental test items. On external appearance test, there were two models which showed bubble, humidity penetration, seal melted frame phenomenon. From this results, the degree of aging under the external environment is a main cause that shortens photovoltaic module life time. So it is considered that the efforts for finding optimum condition of manufacturing process should be needed.

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