• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2005.10a
• /
• pp.178-181
• /
• 2005

Quaternary Ti-Si-C-N coatings were deposited on WC-Co substrates by a hybrid coating system of arc ion plating (AIP) and sputtering techniques using Ti and Si targets, in an $Ar/N_2/CH_4$ gaseous mixture. The crystallinity, bending status, and microstructure of the Ti-Si-C-N coatings were measured by X-ray diffractometer (XRD) and X-ray photoelectron spectroscope (XPS), The micro-hardness of Ti(C,N) and Ti-Si-N coatings were about 30 and 40 GPa, respectively. As the Si was incorporated into Ti(C,N) coatings, the Ti-Si-C-N coatings having Si content of $8.9\;at.\%$ showed the maximum hardness value of about 55 GPa. In this work, the microstructure and mechanical properties of Ti-Si-C-N coatings were systematically investigated.

• Journal of the Korean Applied Science and Technology
• /
• v.12 no.1
• /
• pp.81-86
• /
• 1995

Some weight loss accelerating agents, dodecyltrimethylammonium chloride(DTAC), dodecyltrimethylammonium bromide(DTAB), dodecyldimethylammonium chloride(DDBAC), polyoxyethylene(2) dodecylbenzylammonium chloride(PDBAC), and 1-(2-hydroxyethyl)-1-benzyl-2-undecylimidazolinium chloride(AEUIC), were synthesized. As a result of weight loss treatment of the weight loss accelerating agents with NaOH to PET fiber, the increase of weight loss was the order of PDBAC > DDBAC > DTAC > DTAB > AEUIC. Among the weight loss accelerating agents, AEUIC hardly showed weight loss effect, and it was separated into two layer in the NaOH solution at the treatment concentration above 6g/L, but POBAC showed good weight loss effect of 21% that approach almost to a theoretical weight loss, 21.6%, at the concentration above 8g/L.

• Macromolecular Research
• /
• v.12 no.1
• /
• pp.38-45
• /
• 2004

A highly flexible polyimide (PI) was synthesized successfully from ethylene glycol bis(anhydrotrimellitate) (TMEG) and 1,3-bis(4-aminophenoxy)benzene (TPER) for its application in electronics. To enhance the thermal stability and mechanical properties of this novel PI, we prepared PI nanocomposite films using nanoparticles of clays that had been treated with organic intercalating agents (organoclays). We used two types of organoclays: montmo-rillonite (MMT) treated with hexadecylamine (C$\_$16/) and MMT treated with dimethyl dihydrogenated tallow quaternary ammonium (l5A). PI/organoclay hybrid films were obtained by first preparing poly(amic acid) (PAA)/organoclay films and then converting the PAA to polyimide by thermal conversion. PAA was characterized by FT-IR and $^1$H-NMR spectroscopy and the conversion of PAA to PI was confirmed by FT-IR spectroscopy. We analyzed the dispersion of the organoclays in the PI film by X-ray diffraction. The thermal stability and mechanical properties of the hybrid films were also investigated.

• Proceedings of the Earthquake Engineering Society of Korea Conference
• /
• 2006.03a
• /
• pp.33-40
• /
• 2006

Since early 1990's, several Quaternary faults have been found in the southeastern part of the Korean peninsula with reference to fault activity. Because some of these faults could be considered a capable fault, it is a very delicate matter, which need to be deal with carefully in assessing the seismic hazard. In determining whether or not a faults are capable, because of the low rate of seismicity and insufficient relationship between instrumental macro-seismicity and fault, there has been considerable debate among geologists and geophysicists in Korea. In this study, we discuss the criteria and probabilistic approaches that are used to assess whether or not a fault is seismogenic. And, we preliminarily also suggest the probability of fault activity from the spatial association between faults and earthquake epicenters, fault slip and tectonic stress, and geological evidence for multiple episodes of reactivation.

• Archives of Pharmacal Research
• /
• v.15 no.2
• /
• pp.187-189
• /
• 1992

In the preceding paper, we reported the synthessis and biological properties of cephalosporins having quinoliniumthiomethyls at the C-3 position and demonstrated that quinoliniumthiomethylcephalosporins exhibited an extended antibacterial spectrum including antipseudomonal activity, especially strong antiGram-positive activity. With the aim of elaboration to optimize the antibacterial potency of the quaternary ammonium cephalosporins, we have studied the modification of substituents in the pyrrolidine ring of cefepime 1 which is characterized by its potent activity.

• 한국석유지질학회:학술대회논문집
• /
• autumn
• /
• pp.2-16
• /
• 1999

This study includes structural analysis of the northern Pattani Basin, areal description of depositional facies, and their spatial relationships using 3-D seismic and well data. Well log data indicate that the representative depositional facies of the studied intervals are sandy, fluvial, channel-fill facies encased in shaly floodplain deposits. Seismic responses were predicted from a synthetic seismogram using a model of dominant depositional facies. Peak-to-trough amplitude and instantaneous frequency seismic attributes are used in depositional facies interpretation. Three Intervals A, B and C are interpreted on the successive stratal surfaces. The shallowest interval, A, is the Quaternary transgressive succession. Each stratal surface showed flow pattern variation of fluvial channel facies. Two transgressive cycles were identified in interval A. Interval B also indicated fluvial facies. Depositional facies architectures are described by interpreting seismic attributes on the successive stratal surfaces.

• Resources Recycling
• /
• v.8 no.3
• /
• pp.31-36
• /
• 1999

In the process of manufacturing acrylonitrile, azeotrope of water-acetonitrile is formed as by-product. To1uene-ethylacetate mixture was selected as solvent to determine the liquid-liquid equilibria for to1uene(l)-water(2)-acetomtrile(3)-ethyjacetate(4) system. The experimental he-line data were correlated with the UNIFAC model. The distribution and selectivity for quaternary system was also studied.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.11a
• /
• pp.150-153
• /
• 2009

Anion exchange polymer electrolyte pore-filling membranes consisting of the whole hydrocarbon materials were prepared by photo polymerization with various quaternary ammonium cationic monomers and characterized on the properties for applying to solid alkali fuel cell (SAFC). Hydrocarbon porous substrates such as polyethylene were used for the preparation of the pore-filling membranes. The hydroxyl ion conductivity of the polymer electrolyte membranes prepared in this research was dependent on the composition ratio of an electrolyte monomer and crosslinking agents used for polymerization. Furthermore, these pore-filling membranes have commonly excellent properties such as smaller dimensional affects when swollen in solvents, higher mechanical strength, lower fuel crossover through the membranes, and easier preparation process than those of traditional cast membranes.

• YAKHAK HOEJI
• /
• v.48 no.1
• /
• pp.88-92
• /
• 2004

In this study; a series of 2',4'-doubly branched carbocyclic nucleosides (8,9,10) were synthesized from simple acyclic ketone derivative as starting material. The installation of the 4'-quaternary carbon needed was carried out using a 〔3,3〕-sigmatropic rearrangement. In addition, the introduction of a methyl group in the 2'-position was accomplished by Grig-nard reaction. Bis-vinyl was successfully cyclized using a Grubbs' catalyst II. The natural bases (adenine, cytosine, uracil) were efficiently coupled with the use of a Pd(0) catalyst. Although all the synthesized compounds were assayed against several viruses, only cytosine analogue 9 showed weak antiviral viral activity (EC$_{50}$=45.4 $\mu$M) against CoxB3 virus.s.

• Applied Microscopy
• /
• v.27 no.3
• /
• pp.257-263
• /
• 1997

Microstructural characterizations of II-VI blue laser diodes which consist of quaternary $Zn_{1-x}Mg_xS_ySe_{l-y}$ cladding layer, ternary $ZnS_ySe_{l-y}$ guiding layer and $Zn_{0.8}Cd_{0.2}Se$ quantum well as active layer were carried out using the transmission electron microscope working at 300 kV. Even though the entire structure is pseudomorphic to GaAs substrate, the structure had contained numerous extended stacking faults and dislocations which had created at ZnSe/GaAs interfaces and then further grown to the top of the epilayers. These faults might be expected to cause the degradation and shortening the lifetime of laser devices.