• Title/Summary/Keyword: The Quaternary

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Low Temperature Dyeing Process by Intercellular diffusion through Cell Membrane Complex Modification of Wool. - Technology based on CSIRO and ICI (양모의 저온 염색 소개 - Sirolan LTD Process from ICI)

  • 윤일남
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2001.11a
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    • pp.3-11
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    • 2001
  • Fundamental studies at the CSIRO division of Wool technology and ICI on the diffusion of dyes into wool〔1,2〕have let to development of a new approach to wool dyeing. In this method, the cell membrane complex of wool is modified before dyeing by treatment under mildly alkaline conditions with a special chemicals. Wool pretreated with ethoxylated quaternary ammonium salt has an increased rate of dyebath exhaustion and dye penetration early in the dyeing cycle. This enables the treated material to be dyed below the boil for a similar time to the conventional cycle. This technique can be used on untreated and shrinkresist-treated wool and wool/nylon blends. In addition to good macro-levelness and excellent coverage of tippiness, the low temperature dyeing process give higher exhaustion levels of dyestuffs and insect-resist agent and hence cleaner effluent liquors, compared with conventional dyeing process. Low Temperature Dyeing process cause significantly less fiber damage than conventional way. The reduction in damage is reflected in improved processing performance of the dyed wool.

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The Effect of Sulfurization Temperature on CuIn(Se,S)2 Solar Cells Synthesized by Electrodeposition

  • Kim, Dong-Uk;Yun, Sang-Hwa;Yu, Bong-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.97-97
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    • 2014
  • The properties of thin film solar cells based on electrodeposited $CuIn(Se,S)_2$ were investigated. The proposed solar cell fabrication method involves a single-step $CuInSe_2$ thin film electrodeposition followed by sulfurization in a tube furnace to form a $CuIn(Se,S)_2$ quaternary phase. A sulfurization temperature of $450-550^{\circ}C$ significantly affected the performance of the $CuIn(Se,S)_2$ thin film solar cell in addition to its composition, grain size and bandgap. Sulfur(S) substituted for selenium(Se) at increasing rates with higher sulfurization temperature, which resulted in an increase in overall band gap of the $CuIn(Se,S)_2$ thin film. The highest conversion efficiency of 3.12% under airmass(AM) 1.5 illumination was obtained from the $500^{\circ}C$-sulfurized solar cell. The highest External Quantum Efficiency(EQE) was also observed at the sulfurization temperature of $500^{\circ}C$.

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Chemistry of the 3a,7a-Dihydro-1H-indole Esters. Aromatization by Bromine$^\dag$

  • Lee, Chang-Kiu;Ahn, Yu-Mi;Han Lee, In-Sook
    • Bulletin of the Korean Chemical Society
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    • v.7 no.4
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    • pp.311-314
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    • 1986
  • A series of tetramethyl 1-substituted benzyl-3a,7a-dihydro-1H-indole-2,3,3a,4-tetracarboxylates were prepared and their reactions with bromine were examined. The initial reaction seemed to be the formation of the intermediate N-bromo quaternary ammonium bromide. This intermediate underwent aromatization with loss of the 3a-methoxycarbonyl group. Bromine replaced the N-substituent of the p-methoxybenzyl compound and addition of bromine occurred across the $C_6-C_7$ double bond of the indole ring. Bromination of the benzyl ring and aromatization occurred for the m-methoxybenzyl compound.

A Low Power UART Design by Using Clock-gating (클록 게이팅을 이용한 저전력 UART 설계)

  • Oh, Tae-Young;Song, Sung-Wan;Kim, Hi-Seok
    • Proceedings of the IEEK Conference
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    • 2005.11a
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    • pp.865-868
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    • 2005
  • This paper presents a Clock-gating technique that reduces power dissipation of the sequential circuits in the system. The Master Clock of a Clock-gating technique is formed by a quaternary variable. It uses the covering relationship between the triggering transition of the clock and the active cycles of various flip-flops to generate a slave clock for each flip-flop in the circuit. At current RTL designs flip-flop is acted by Master clock's triggering but the Slave Clock of Clock-gating technique doesn't occur trigger when external input conditions have not matched with a condition of logic table. We have applied our clocking technique to UART controller of 8bit microprocess

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Antimicrobial and Water Repellency Effect of Functional Cotton Fiber with ODDMAC(octadecyl dimethyl(3-triethoxy silylpropyl) ammonium chloride) (ODDMAC를 이용한 항균성 및 발수성 동시 발현이 가능한 기능성 면섬유)

  • Jeon, Hyeji;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.31 no.4
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    • pp.276-287
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    • 2019
  • In this study, cotton fibers were coated with a different weight percentage of octadecyl dimethyl(3-triethoxy silylpropyl) ammonium chloride(ODDMAC) to improve antimicrobial and water repellent properties. First, the ODDMAC dissolved in ethanol to prepare a solution. Then the cotton fibers were immersed in the ODDMAC/ethanol solution for 10 minutes at ambient temperature and dried at 80℃ for 3 minutes followed by curing. The treated cotton fibers were characterized by scanning electron microscopy(SEM) and x-ray photoelectron spectroscopy(XPS). The treated cotton fibers revealed sufficient antimicrobial activity against Klebsiella pneumoniae(ATCC 4352) and Staphylococcus aureus(ATCCBAA-1707). The hydrophobic nature of the treated cotton fibers was characterized by contact angle measurement. The results showed that the cotton fibers treated with the ODDMAC showed excellent hydrophobic properties which improved to 121°.

Microstructural and Mechanical Characterization of Nanocomposite Ti-Al-Si-N Films Prepared by a Hybrid Deposition System (하이브리드 증착 시스템에 의해 합성된 나노복합체 Ti-Al-Si-N 박막의 미세구조와 기계적 특성)

  • 박인욱;최성룡;김광호
    • Journal of Surface Science and Engineering
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    • v.36 no.2
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    • pp.109-115
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    • 2003
  • Quaternary Ti-Al-Si-N films were deposited on WC-Co substrates by a hybrid deposition system of arc ion plating (AIP) method for Ti-Al source and DC magnetron sputtering technique for Si incorporation. The synthesized Ti-Al-Si-N films were revealed to be composites of solid-solution (Ti, Al, Si)N crystallites and amorphous Si3N4 by instrumental analyses. The Si addition in Ti-Al-N films affected the refinement and uniform distribution of crystallites by percolation phenomenon of amorphous silicon nitride, similarly to Si effect in TiN film. As the Si content increased up to about 9 at.%, the hardness of Ti-Al-N film steeply increased from 30 GPa to about 50 GPa. The highest microhardness value (~50 GPa) was obtained from the Ti-Al-Si-N film haying the Si content of 9 at.%, the microstructure of which was characterized by a nanocomposite of nc-(Ti,Al,Si) N/a$-Si_3$$N_4$.

Liquid-Liquid Phase Separation in a Quaternary System of PolysuIfone/Polyethersulfone/N-Methyl-2-pyrrolidone/water (사성분계 시스템의 액액상분리에 관한 연구 (폴리술폰/폴리에테르술폰/NMP/물))

  • 백기전;김제영;이환광;김성철
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.22-24
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    • 1998
  • 1. INTRODUCTION : The phase inversion method is widely used to prepare a variety of polymeric membranes ranging from micro-filtration to gas separation. The final morphology obtained by immersion precipitation strongly reflects the thermodynamics and kinetics of the system involved. The equilibrium thermodynamics of the ternary system of polymer/solvent/ nonsolvent is still very important to understand and predict membrane structure. Polysulfone (PSf) and polyethersulfone (PES) are important polymers as membrane materials due to the chemical resistance, mechanical strength, thermal stability and transport properies. There are several reports on the experimental phase diagrams in ternary mixtures of PSf/solvent/nonsolvent, and PES/solvent/nonsolvent. It would be interesting to investigate the solution thermodynamics containing these two polymers since PES is slightly less hyclrophobic than PSf.

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Studies on the Treatment of Weight Loss of PET Fibers by Alkyldimethylbenzylammonium Chlorides (알킬디메틸벤질암모늄 클로라이드에 의한 PET섬유의 감량가공에 관한 연구)

  • Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.2
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    • pp.29-33
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    • 1993
  • n-Octyldimethylbenzylammonium chloride, dodecyldimethylbenzylammonium chloride, and octadecyldimethylbenzylammonium chloride were synthesized to be used as the accelerating weight loss agent. These synthesized compounds were used for the weight loss treatment of PET textile with sodium hydroxide. From the treatments, it was found that the lower carbon number of high alkyl group existed in quaternary ammonium salts, the better effect of weight loss was acquired. The proper concentration of accelerating weight loss agent was $8{\sim}10g/l$, the proper treatment time was $60{\sim}90$ minutes, the proper treating bath ratio was 1 : 50. It is proved that n-octyldimethylbenzylammonium chloride and dodecyldimethylbenzylammonium chloride are good accelerating weight loss agent.

Stereoselective Synthesis and Antiviral Activity of Novel 4′(α)-Hydroxymethyl and 6′(α)-Methyl Dually Branched Carbocyclic Nucleosides

  • Kim, Jin-Woo;Choi, Bo-Gil;Hong, Joon-Hee
    • Bulletin of the Korean Chemical Society
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    • v.25 no.12
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    • pp.1812-1816
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    • 2004
  • The stereoselective synthesis 4′,6′-dually branched carbocyclic nucleosides was accomplished in this study. The introduction of a methyl group in the 6′$({\alpha})$-position was accomplished by Felkin-Anh controlled alkylation. The construction of the required 4′$({\alpha})$-quaternary carbon was carried out using a [3,3]-sigmatropic rearrangement. Bis-vinyl 6 was successfully cyclized using a Grubbs' catalyst II. The natural bases (adenine, cytosine) were efficiently coupled using a Pd(0) catalyst. When the synthesized compounds were examined for their activity against several viruses such as the HIV-1, HSV-1, HSV-2 and HCMV, the cytosine analogue 13 exhibited good antiviral activity against the HCMV.

Synthesis and Antiviral Activity of Novel 4',5'-Branched Pyrimidine Nucleosides (4',5'-측쇄를 가진 새로운 피리미딘 뉴크레오사이드의 합성 및 항바이러스 약효검색)

  • Kim Aihong;Kooh Dae-Ho;Ko Ok Hyun;Hong Joon Hee
    • YAKHAK HOEJI
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    • v.49 no.1
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    • pp.20-24
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    • 2005
  • The synthesis of 4',5'-doubly branched carbocyclic nucleosides was accomplished in this study. The selective methylation in the 5'-position was made by Felkin-Anh controlled Grignard addition. The construction of the required 4'-quaternary carbon was carried out by using a [3,3]-sigmatropic rearrangement. Bis-vinyl 6 was successfully cyclized using a Grubbs' catalyst II. The natural pyrimidine bases (cytosine, uracil, thymine) were efficiently coupled using a Pd(0) catalyst. When the synthesized compounds were examined for their activity against several viruses such as the HIV-1, HSV-1, HSV-2 and HCMV, the cytosine analogue 13 exhibited weak antiviral activity against the HCMV.