• Title/Summary/Keyword: The Quaternary

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Efficient Ring Opening Reaction of Epoxides with Oxygen Nucleophiles Catalyzed by Quaternary Onium Salt

  • Kim, Jin Won;Cho, Dae Won;Park, Gyoosoon;Kim, Sung Hong;Ra, Choon Sup
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2286-2290
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    • 2013
  • Ring opening reactions of epoxides with oxygen nucleophiles catalyzed by a variety of quaternary onium salt, such as ammonium or phosphonium salt were explored. The results showed that tetrabutylphosphonium bromide (TBPB) among salts serves as the most efficient catalyst for this process and that expoxide ring opening reactions with a variety of oxygen nucleophiles including carboxyic acid and phenol, promoted using this salt, lead to generate readily purifiable products in excellent yields.

Synthesis and In Vitro Antibacterial Activity of Quaternary Ammonium Cephalosporin Derivatives Bearing Oxazolidinone Moiety

  • Chung, In-Hwa;Kim, Choong-Sup;Seo , Jae-Hong;Chung, Bong-Young
    • Archives of Pharmacal Research
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    • v.22 no.6
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    • pp.579-584
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    • 1999
  • Several oxazolidinones having amine moiety were prepared to form a quaternay ammonium salt with cephalosporin nucleus, and antibacterial activity of the quaternary ammonium cephalosporin derivatives bearing oxazolidinone moiety were examined particularly with expectation of dual activity. However, the cephalosporin-oxazolidinone compounds revealed rather weaker antibacterial activity in vitro than their parent oxazolidinone and cephalosporin without showing any characteristic activity as expected.

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Quaternized Polyamidoamine Dendrimers as Novel Gene Delivery System: Relationship between Degree of Quaternization and Their Influences

  • Lee, Jung-Hoon;Lim, Yong-Beom;Choi, Joon-Sig;Choi, Myung-Un;Yang, Chul-Hak;Park, Jong-Sang
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1637-1640
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    • 2003
  • Quaternary ammonium groups were introduced to Starburst polyamidoamine (PAMAM) dendrimers for a gene carrier. These quaternary dendritic carriers exhibited reduced cytotoxicity on 293T cells compared to parent dendrimers examined and their transfection efficiency were similar with parent dendrimers. Quaternization could be a promising tool to improve properties of dendrimers as a gene delivery carrier.

Development History of Neotectonic Fault Zone in the Singye-ri Valley, Oedong-eup, Gyeongju, Korea (경주시 외동읍 신계리 계곡에 발달하는 신기 단층대 발달사)

  • Kang, Ji-Hoon;Son, Moon;Ryoo, Chung-Ryul
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.4
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    • pp.349-359
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    • 2020
  • The Ulsan Fault Zone (UFZ) of NNW trend is developed in the Gyeongsang Basin, the southeastern part of the Korean Peninsula, and the Quaternary faults have been found around the UFZ. The faults generally thrust the Bulguksa igneous rocks of Late Cretaceous-Early Tertiary upon the Quaternary deposits or are developed within the Quaternary deposits. They mainly show the reverse-slip sense of top-to-the west movement. The lines connecting the their outcrop sites show a zigzag-form which is similar to the orientation of their fault surfaces which show the various trends, like (W)NW, N-S, (E)NE, ENE trends. The E-W trending dextral strike(-slip) fault is found in the Quaternary deposits of the Singye-ri valley. It cuts the N-S trending reverse fault and are cut by the N-S trending thrust fault again. Two types of at least two times of Quaternary tectonic movements related to the formation of neotectonic fault zone in the Singye-ri valley are considered from such the geometric and kinematic characteristics of Quaternary faults. One is the reverse faulting of N-S trend by the E-W directed 1st compression and associated the strike-slip tear faulting of E-W trend, and then the thrust faulting of N-S trend by the E-W directed 2nd compression. The other is the reverse faulting of N-S trend, and then the dextral strike-slip faulting of E-W trend by the NW-SE directed compression, and then the thrust faulting of N-S trend. In this paper is suggested the development history of Singye-ri neotectonic fault zone on the basis of the various orientations of Quaternary fault surfaces around the UFZ, and the zigzag-form connecting line of their outcrop sites, and the compressive arc-shaped lineaments which convex to the west reported recently in the Yangsan Fault Zone.

Distribution and characteristics of Quaternary faults in the coastal area of the southeastern Korean Peninsula: Results from a marine seismic survey (해양 탄성파 탐사 결과로 본 한반도 남동부연안 4기 단층의 분포와 특성)

  • Kim Han-Joon;Jou Hyeong-Tae;Hong Jong-Kuk;Park Gun-Tae;Nam Sang-Heon;Cho Hyun-Moo
    • 한국지구물리탐사학회:학술대회논문집
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    • 2002.09a
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    • pp.46-66
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    • 2002
  • High-resolution multichannel seismic data were collected in the coastal area near the Gori nuclear power plant to investigate Quaternary fault pattern and timing. A 12 channel streamer, a sparker, and a portable recorder were used for data acquisition. Because the group interval of the streamer was 6.25 m and the sparker can generate acoustic waves with the frequency content of up to 500 Hz, the data show a significant improvement both in horizontal and vertical resolution. The area surveyed is covered with 30-40 m thick Holocene sediments that constitute the mud belt along the southeastern coast of Korea. The survey area is characterized by the well discriminated Pleistocene and Holocene boundary and shallow gas-charged zones. A number of Quaternary faults were found in the sediment column, that are nearly vertical and extend north-south. The Quaternary faults, arranged at a spacing of a few hundred meters, suggest that they were formed in response to compression, although some of them reveal extensional characteristics. Locally, faults disrupt Incised-channel fills that are interpreted to have formed in the early stage of transgression after the beginning of the Holocene. Seismic sections suggest that shallow gas in the mud belt sediments made its way upward through the fractured fault planes. The tectonism responsible for the opening of the East Sea has not persisted since the late Miocene, but vigorous Quaternary faulting activity in the vicinity of the southeastern Korean Peninsula indicates that tectonic stability has yet to be achieved in this region underlain by the hotter than normal mantle.

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The Representation of the Neolithic Rock Art of Bangu-dae, South Korea

  • Lee, Sang-Mog
    • The Korean Journal of Quaternary Research
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    • v.18 no.2 s.23
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    • pp.87-92
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    • 2004
  • The rock engraving of the Korea are dated by a very few direct archaeological contexts by linking their images to objects of known prehistoric date-although many of the figures are 'abstract'. This paper focuses on the rock art of Bangu-dae, located in the south-east of Korea. I try to the date of engravings from their contexts and the ways in which they can be studied.

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Permafrost Condition in Mongolia

  • Jambaljav, Ya.
    • The Korean Journal of Quaternary Research
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    • v.17 no.2
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    • pp.71-74
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    • 2003
  • Permafrost study in Mongolia officially began in the end of 1950 years. At the first time our senior researchers concentrated on the regional characteristics of permafrost distribution and on the engineering geocryological problems. At present time we concentrate on permafrost mapping using the GIS, on permafrost monitoring based on the temperature measurement in boreholes, on permafrost phenomena monitoring in same permafrost regions and on engineering geocryological problems.

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REPRESENTATIONS BY QUATERNARY QUADRATIC FORMS WITH COEFFICIENTS 1, 2, 11 AND 22

  • Bulent, Kokluce
    • Bulletin of the Korean Mathematical Society
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    • v.60 no.1
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    • pp.237-255
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    • 2023
  • In this article, we find bases for the spaces of modular forms $M_2({\Gamma}_0(88),\;({\frac{d}{\cdot}}))$ for d = 1, 8, 44 and 88. We then derive formulas for the number of representations of a positive integer by the diagonal quaternary quadratic forms with coefficients 1, 2, 11 and 22.

Direct Organocatalytic Regioselective α-Hydroxyamination of α-Branched Aldehydes

  • Kim, Sung-Gon;Ahn, Eun-Ju;Park, Tae-Ho
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1665-1669
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    • 2007
  • A direct regioselective α-hydroxyamination of α-branched aldehydes with nitrosobenzene using cis-5-benzylproline as catalyst has been developed for the preparation of α-hydroxyamino aldehydes possessing a quaternary carbon center. Such compounds are versatile building blocks for the synthesis of quaternary α- amino acids, β-amino alcohols, and 1,2-diamines.