• Title/Summary/Keyword: Temperature stability time

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Physical Properties of Hybrid Poplar Flakeboard Bonded with Alkaline Phenolic Soy Adhesives

  • Yang, In;Kuo, Monlin;Myers, Deland J.
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.5 s.133
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    • pp.66-75
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    • 2005
  • Soybean-based adhesives have recently been reconsidered as alternatives to petroleum-based adhesives due to the uncertainty of availability of petrochemical products and the increased demand for wood adhesives. This study was conducted to investigate the adhesive properties of alkaline phenolic soy (APS) resin for hybrid poplar flakeboard. The APS resin was formulated by crosslinking an alkaline soy flour hydrolyzate with lab-prepared PF resin in the soy hydrolyzate to PF resin weight ratios of 70/30, 60/40, and 50/50. The APS resins were used to fabricate homogeneous hybrid poplar flakeboards with different resin solid levels (5%, 7%, and 9%), press temperatures (175 and $200^{\circ}C$), and press times of 8 and 10 minutes. The IB, wet MOR, and dimensional stability properties of board improved with increasing press time, press temperature, and PF level in APS resins. Increasing press time can be used to offset poor IB strength associated with a 9% resin solid level and the excessive moisture content in the mat. The following conditions were concluded to meet the requirements of the CSA standard for exterior-grade flakeboard: a 50% PF level, a 5% resin content, a $200^{\circ}C$ press temperature, and an 8 minute press time.

Effect of Reverse Transformation on the Damping Capacity of High Manganease Austenitic Stainless Steel (고 Mn 오스테나이트계 스테인리스강의 감쇠능에 미치는 역변태의 영향)

  • Kang, C.Y.
    • Journal of Power System Engineering
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    • v.16 no.4
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    • pp.60-65
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    • 2012
  • This study was carried out to investigate the effect of reverse transformation on the damping capacity in high manganese austenitic stainless steel. ${\alpha}^{\prime}$-martensite was formed with the specific direction and surface relief by deformation. Over 95% of the austenite phase was transformed to deformation-induced ${\alpha}^{\prime}$-martensite by 70% cold rolling. Reverse transformation became rapid above an annealing temperature of $550^{\circ}C$, but there was no significant transformation above $700^{\circ}C$. In addition, with increasing annealing time at $700^{\circ}C$, reverse transformation was induced rapidly, but the transformation was almost completed at 10 min. Damping capacity was increased up to $700^{\circ}C$, and than unchanged with the increasing annealing temperature. Damping capacity increased steeply with an increasing reverse treatment time up to 10min, whereas there were no significant change with a treatment time of more than 10 min. Damping capacity increased with an increasing the reversed austenite and was strongly affected by reversed austenite.

Effect of Reverse Transformation on the Mechanical Properties of High Manganease Austenitic Stainless Steel (고 Mn 오스테나이트계 스테인리스강의 기계적 성질에 미치는 역변태의 영향)

  • Kang, C.Y.;Hur, T.Y.
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.413-418
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    • 2012
  • This study was carried out to investigate the effect of reverse transformation on the mechanical properties in high manganese austenitic stainless steel. Over 95% of the austenite was transformed to deformation-induced martensite by 70% cold rolling. Reverse transformation became rapid above an annealing temperature of $550^{\circ}C$, but there was no significant transformation above $700^{\circ}C$. In addition, with an increasing annealing time at $700^{\circ}C$, reverse transformation was induced rapidly, but the transformation was almost completed at 10 min. There was a rapid decrese in strength and hardness with annealing at temperature above $550^{\circ}C$, while elongation increased rapidly above $600^{\circ}C$. At $700^{\circ}C$, hardness and strength decreased rapidly, and elongation increased steeply with an increasing reverse treatment time up to 10 min, whereas there were no significant change with a treatment time after 10 min. The reverse-transformed austenite showed an ultra-fine grain size less than $0.2{\mu}m$, which made it possible to strengthen the high manganese austenitic stainless steel.

Physico-mechanical Properties and Optimum Manufacturing Conditions of Bi-Sn Metal Alloy Impregnated Wood Composites (Bi-Sn 용융합금주입 목재복합체의 최적제조조건 및 물리·기계적 특성)

  • Park, Kye-Shin;Lee, Hwa-Hyoung;Kang, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.6
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    • pp.691-699
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    • 2014
  • In order to improve the dimensional stability and durability of wood, this study attempted to impregnate bismuth (Bi) - tin (Sn) alloy metal with low melting temperature into solid woods of three species such as radiata pine, red oak and white oak, and investigated to determine an optimum condition of manufacturing the metal alloy-wood composites with natural wood grains. These Bi-Sn alloys were chosen for this study because they were harmless to human and melting at low temperatures. The composites resulted in high dimensional stability and low thickness swelling, and also showed much improved performance such as high bending strength, high hardness, high electric conductivity, and high thermal conductivity as floor materials. A proper impregnating condition of all specimens was determined as 10 minutes of the preliminary vacuum time, and $185^{\circ}C$ of the heating temperature. The proper processing condition for radiata pine wood was 2.5 minutes of the pressuring time at the pressure of $10kgf/cm^2$. For red oak wood, 10 minutes of the pressuring time at the pressure of $30kgf/cm^2$ were the proper condition. The proper manufacture conditions for white oak wood was determined as 10 minutes of the pressuring time at the pressure of $50kgf/cm^2$.

Residual Stress on Concentric Laminated Fibrous Al2O3-ZrO2 Composites on Prolonged High Temperature Exposure

  • Sarkar, Swapan Kumar;Lee, Byong Taek
    • Korean Journal of Materials Research
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    • v.23 no.9
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    • pp.531-536
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    • 2013
  • This paper investigates the effect of prolonged high temperature exposure on concentric laminated $Al_2O_3-ZrO_2$ composites. An ultrafine scale microstructure with a cellular 7 layer concentric lamination with unidirectional alignment was fabricated by a multi-pass extrusion method. Each laminate in the microstructure was $2-3{\mu}m$ thick. An alternate lamina was composed of 75%$Al_2O_3$-(25%m-$ZrO_2$) and t-$ZrO_2$ ceramics. The composite was sintered at $1500^{\circ}C$ and subjected to $1450^{\circ}C$ temperature for 24 hours to 72 hours. We investigated the effect of long time high temperature exposure on the generation of residual stress and grain growth and their effect on the overall stability of the composites. The residual stress development and its subsequent effect on the microstructure with the edge cracking behavior mechanism were investigated. The residual stress in the concentric laminated microstructure causes extensive micro cracks in the t-$ZrO_2$ layer, despite the very thin laminate thickness. The material properties like Vickers hardness and fracture toughness were measured and evaluated along with the microstructure of the composites with prolonged high temperature exposure.

Analytical solution for scale-dependent static stability analysis of temperature-dependent nanobeams subjected to uniform temperature distributions

  • Ebrahimi, Farzad;Fardshad, Ramin Ebrahimi
    • Wind and Structures
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    • v.26 no.4
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    • pp.205-214
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    • 2018
  • In this paper, the thermo-mechanical buckling characteristics of functionally graded (FG) size-dependent Timoshenko nanobeams subjected to an in-plane thermal loading are investigated by presenting a Navier type solution for the first time. Material properties of FG nanobeam are supposed to vary continuously along the thickness according to the power-law form and the material properties are assumed to be temperature-dependent. The small scale effect is taken into consideration based on nonlocal elasticity theory of Eringen. The nonlocal governing equations are derived based on Timoshenko beam theory through Hamilton's principle and they are solved applying analytical solution. According to the numerical results, it is revealed that the proposed modeling can provide accurate critical buckling temperature results of the FG nanobeams as compared to some cases in the literature. The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of the several parameters such as material distribution profile, small scale effects and aspect ratio on the critical buckling temperature of the FG nanobeams in detail. It is explicitly shown that the thermal buckling of a FG nanobeams is significantly influenced by these effects. Numerical results are presented to serve as benchmarks for future analyses of FG nanobeams.

Analysis of Inner Temperature in High Strength Concrete under Standard Temperature-time Curve (표준화재곡선에 의한 고강도 콘크리트 부재의 내부온도 예측)

  • Song, Hun;Lee, Sea-Hyun;Mun, Kyung-Ju;Do, Jeong-Yun;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.469-472
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    • 2005
  • With all ensuring the fire resistance structure as a method of setting the required cover thickness to fire, the RC is significantly affected from the standpoint of its structural stability that the compressive strength and elastic modulus is reduced by fire. Normally, the degradation of concrete member exposed to fire is largely dependent on the fire scale and fire condition. There is therefore a need to precisely predict the deterioration and fire damage of the exposed member. Thus, this work estimated the temperature distribution inside a member taking into consideration of the thermal properties by means of finite element method(FEM). The estimation results in a little higher prediction value than the experimental value in surface layer and is almost coincident with the experiment as the heating depth increase. From this work it can be known that the simulation application of FEM using the thermal properties of concrete member in high temperature gives rise to the confident prediction in the prediction of temperature distribution.

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A Study on Synthesis Catalysts for Vinylester Resin (비닐에스테르 수지의 합성촉매에 관한 연구)

  • Hong, Suk-Pyo;Choi, Sang-goo
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.229-237
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    • 1991
  • Vinylester was syntheszed in the presence of amine and metal catalysts, such as triethylamine(TEA), triethylbenzyl ammonium chloride (TEBAC), cetyltrimethyl ammonium bromide (CTMAB), chromium acety] acetate (CAA), and triphenylantimony (TPA). Apropriate use of amine and organometal catalysts were 1.7~2.2 % (Wt. %), 2.5~3.1 % (Wt %) of charged methacrylic acid (MAA) in respect of reactivity, gel-time, and storage stability. The Order of reactivity was TEA>TEBAC>CTMAB>CAA>TPA. Temperature independence of catalyst showed more large deviation above $110^{\circ}C$. Storage stability could be improved without delay of gel-time by adding TPA in 2.0 % (Wt %) of charged MAA after synthesis.

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Preparation of Fe(III)-Coated Starfish and Evaluation of the Removal Capacity of Copper (3가철 코팅 불가사리 흡착제 제조 및 구리 제거 특성 평가)

  • Yang, Jae-Kyu;Yu, Mok-Ryun;Lee, Seung-Mok
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.172-176
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    • 2006
  • Fe(III)-Coated Star Fish (ICSF) was prepared by reaction of calcined Star Fish (SF) with Fe(III) solution at an elevated temperature. To investigate the stability of ICSF at acidic condition, dissolution of Fe was studied at pH 2 as a function of time. Extracted iron was negligible over the entire reaction time. This stability test suggests the applicability of ICSF in the treatment of wastewater even at low pH. Adsorption capacity of Cu(II) onto SF and ICSF was investigated in a batch and a column test. In the pH-edge adsorption, adsorption of copper onto SF and ICSF was quite similar over the entire pH range due to the presence of an important amount of Fe in SF itself. From the adsorption isotherm obtained with variation of the concentration of Cu(II), ICSF showed 1.6 times greater adsorption capacity than SF. Also, ICSF showed a greater removal capacity of Cu(II) in the column test.

Thermal stability analysis of interferometric snapshot spectro-polarimeter (간섭기반 스냅샷 분광편광위상측정의 열 안정성 분석)

  • Choi, Inho;Dembele, Vamara;Paul, Madhan Jayakumar;Choi, Sukhyun;Kim, Junho;Baek, Byung-Joon;Kim, Daesuk
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.3
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    • pp.70-74
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    • 2018
  • In typical spectroscopic ellipsometry, the optical and geometrical properties of thin film and nano pattern can be obtained by measuring the polarization state of light reflected/transmitted from the object by rotating a analyzer or a compensator. We proposed a snapshot spectroscopic ellipsometric system based on a modified Michelson interferometer to overcome the time-consuring measurement principle due to rotating part. The proposed system provides spectral ellipsometric parameters (psi, delta) in real time by using a single spectral interference signal generated in the interferometric polarization module. However, it has a long-term stability problem resulting in delta(k) drift. In this paper, it is experimentally proved that the drift problem is caused by anisotropic refractive index change of the beam intersection layer in beam splitter of interferometer.