• Preventive Nutrition and Food Science
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• v.9 no.3
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• pp.222-226
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• 2004

Hydrocarbons induced by gamma-irradiation of green, black, and oolong teas were analyzed to determine whether the hydrocarbons can be used as markers for detecting post-irradiation of these teas. The samples were irradiated at 0, 2.5, 5, 7.5, and 10 kGy. Detection was attempted by extracting fat from the teas, separation of hydrocarbons with florisil column chromatography, and identification of hydrocarbons by gas chromatography-mass spectroscopy (GC-MS). Concentration of hydrocarbons increased with the irradiation dose. The major hydrocarbons in irradiated green, black, and oolong teas were 1-tetradecence (14:1), pentadecane (15:0), 1,7-hexadecadiene (16:2), 1-hexadecene (16:1), 8-heptadecene (17:1), and heptadecane (17:0). Radiation-induced hydrocarbons in teas were 1,7-hexadecadiene and 8-heptadecene. These compounds were not detected in non-irradiated samples, so the hydrocarbons (16:2, 17:1) can be used as markers for detecting post-irradiation of the teas. Furthermore, detection of hydrocarbons after 12 months storage at room temperature remains a suitable method for identifying irradiated teas.

• Korean Journal of Remote Sensing
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• v.22 no.3
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• pp.175-182
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• 2006

Because of the phenological variation of vegetation growth in temperate region, it is often difficult to accurately assess the surface conditions of agricultural croplands, grasslands, and disturbed forests by multi-spectral remote sensor data. In particular, the spectral similarity between soil and dry vegetation has been a primary problem to correctly appraise the surface conditions during the non-growing seasons in temperature region. This study analyzes the spectral characteristics of the mixture of dry vegetation and soil. The reflectance spectra were obtained from laboratory spectroradiometer measurement (GER-2600) and from EO-1 Hyperion image data. The reflectance spectra of several samples having different level of dry vegetation fractions show similar pattern from both lab measurement and hyperspectral image. Red-edge near 700nm and shortwave IR near 2,200nm are more sensitive to the fraction of dry vegetation. The use of hyperspectral data would allow us for better separation between bare soils and other surfaces covered by dry vegetation during the leaf-off season.

• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.259-266
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• 2019

Tuning of electro-optical properties of nano-structured $SnO_2:Ga$ powders in a micro drop fluidized reactor (MDFR) was highly effective to enhance the activities of powders to be used as sensor materials. The tuning was conducted continuously in a facile one-step process during the formation of powders. The microscopic hydrodynamic forces affected the band gap structure and charge transfer of $SnO_2:Ga$ powders through the oxygen and interfacial tin vacancies by providing plausible pyro-hydraulic conditions, which resulted in the decrease in the electrical resistance of the materials. The analyses of room-temperature photoluminescence (PL) spectra and FT-IR exhibited that the tuning could improve the surface activities of $SnO_2:Ga$ powders by adjusting the excitation as well as separation of electrons and holes, thus maximizing the oxygen vacancies at the surface of the powders. The scheme of photocatalytic mechanism of $SnO_2:Ga$ powders was also discussed.

• Electronic Materials Letters
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• v.14 no.6
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• pp.739-748
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• 2018

ZnS nanowalls, microspheres and rice-shaped nanoparticles have been successfully grown on graphene oxide (GO) sheets by the hydrothermal method. The morphologies, structures, chemical compositions and optical properties of the as-synthesized GO/ZnS have been characterized by X-ray power diffraction, energy dispersive spectrometer, scanning electron microscope, Raman spectra, photoluminescence spectroscopy and ultraviolet-visible absorption spectroscopy. It was found that the concentration of CTAB and the reaction temperature were important in the formation of GO/ZnS microstructures. The photocatalytic activity of the as-synthesized GO/ZnS was investigated through the photocatalytic degradation of textile dyeing waste. Results showed that the catalytic activity of the GO/ZnS porous spheres to methyl orange and methylene blue is higher than those of other samples. The degradation rates of methyl orange and methylene blue by porous spheres in 50 min were 97.6 and 97.1%, respectively. This is mainly attributed to the large specific surface area of GO/ZnS porous spheres and high separation efficiency between photogenerated electron and hole pairs.

• Progress in Superconductivity and Cryogenics
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• v.20 no.4
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• pp.1-5
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• 2018

A high gradient magnetic (HGM) separator prototype with the $2^{nd}$ generation high temperature superconducting (2G HTS) magnetic system operated in sub-cooled nitrogen is presently under development at NRC "Kurchatov Institute" (Moscow, Russia). The main goal of the project is an attempt to shift away from the complicated liquid helium cryostats towards simple cryocooler-based nitrogen cryogenics as much more convenient for HGM separators industrial applications. Using of commercial HTS tapes allows to get a sufficient level of magnetic fields and extraction forces with low energy consumption. The expected operational parameters of the device are 1.2-1.5 T in the empty operational gap and up to 3 T on the ferromagnetic filters. In this paper we briefly describe the design of the HTS rotary separator prototype with the horizontally oriented rotor axis and propose different types of ferromagnetic filters intended for weakly magnetic ores enrichment.

• Journal of Hydrogen and New Energy
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• v.30 no.4
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• pp.347-355
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• 2019

As a solution to the growing concern on the global warming, researches are being actively carried out to apply carbon dioxide capture and storage technology to power generation systems. In this study, the integrated gasification combined cycle (IGCC) adopting oxy-combustion carbon capture was modeled and the effect of replacing the conventional air separation unit (ASU) with the ion transport membrane (ITM) on the net system efficiency was analyzed. The ITM-based system was predicted to consume less net auxiliary power owing to an additional nitrogen expander. Even with a regular pressure ratio which is 21, the ITM-based system would provide a higher net efficiency than the optimized ASU-based system which should be designed with a very high pressure ratio around 90. The optimal net efficiency of the ITM-based system is more than 3% higher than that of the ASU-based system. The influence of the operating pressure and temperature of the ITM on system efficiency was predicted to be marginal.

• Korean Journal of Materials Research
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• v.31 no.2
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• pp.92-96
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• 2021

We report the growth and enhanced photoelectrochemcial (PEC) water-splitting reactivity of few-layer MoS2 nanosheets on TiO2 nanowires. TiO2 nanowires with lengths of ~1.5 ~ 2.0 ㎛ and widths of ~50~300 nm are synthesized on fluorine-doped tin oxide substrates at 180 ℃ using hydrothermal methods with Ti(C4H9O)4. Few-layer MoS2 nanosheets with heights of ~250 ~ 300 nm are vertically grown on TiO2 nanowires at a moderate growth temperature of 300 ℃ using metalorganic chemical vapor deposition. The MoS2 nanosheets on TiO2 nanowires exhibit typical Raman and ultraviolet-visible light absorption spectra corresponding to few-layer thick MoS2. The PEC performance of the MoS2 nanosheet/TiO2 nanowire heterostructure is superior to that of bare TiO2 nanowires. MoS2/TiO2 heterostructure shows three times higher photocurrent than that of bare TiO2 nanowires at 0.6 V. The enhanced PEC photocurrent is attributed to improved light absorption of MoS2 nanosheets and efficient charge separation through the heterojunction. The photoelectrode of the MoS2/TiO2 heterostructure is stably sustained during on-off switching PEC cycle.

• Journal of the Korean Institute of Gas
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• v.25 no.1
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• pp.7-13
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• 2021

The re-liquefaction drum is a product that installed spray nozzles at the top to directly spray overcooled LNG into evaporative gas and installed demistors to facilitate gas separation, which was developed to increase the re-liquidity efficiency of small scale re-liquefaction facilities. In the hydrostatic test of the drum, no leakage occurred even at a pressure of 1.5 times the design pressure, but during the BOR(Boil Off Rate) test, the bolt loosening occurred due to contraction and expansion by temperature change. For the continued use of the product, insulation construction on flange connections was developed to enable detachment and attachment, and the comparison of heat load with existing insulation confirmed that it was very small compared to the inlet flow rate in the drum.

• Membrane and Water Treatment
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• v.12 no.1
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• pp.1-9
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• 2021

This study optimized the chemical cleaning process of discarded RO membranes for reuse in less demanding separation processes. The effect of physicochemical parameters, including the temperature, cleaning time, pH of the cleaning solution, and addition of additives, on the cleaning process was investigated. The membrane performance was evaluated by testing the flux recovery rate and salt rejection before and after the cleaning process. High temperatures (45-50 ℃) resulted in a better flux recovery rate of 71% with more than 80% salt rejection. Equal time for acid and base cleaning 3-3 h presented a 72.43% flux recovery rate with salt rejection above 85%. During acid and base cleaning, the best results were achieved at pH values of 3.0 and 12.0, respectively. Moreover, 0.05% concentration of ethylenediaminetetraacetic acid presented 72.3% flux recovery, while 69.2% flux was achieved using sodium dodecyl sulfate with a concentration of 0.5%; both showed >80% salt rejection, indicating no damage to the active layer of the membrane. Conversely, 0.5% concentration of sodium percarbonate showed 83.1% flux recovery and 0.005% concentration of sodium hypochlorite presented 85.2% flux recovery, while a high concentration of these chemicals resulted in oxidation of the membrane that caused a reduction in salt rejection.

• Analytical Science and Technology
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• v.36 no.4
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• pp.152-160
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• 2023

Adenosine and cordycepin are bioactive compounds with health benefits. Therefore, both substances are often used to assess the quality of Cordyceps products. Optimization and validation of the HPLC/DAD method for determining two nucleosides were studied. The samples were prepared using an ultrasound-assisted extraction (ultrasonic bath). The result was optimal conditions for aqueous extraction, an extraction time of 35 min, and an extraction temperature of 40 ℃. The Chromatographic separation was achieved using a reverse phase column (InfinityLab Poroshell 120 EC-C18, 4.6 × 250 mm, 2.7 ㎛) at 30 ℃ with a mobile phase gradient elution of water and methanol at a flow rate of 0.7 mL/min. The eluents were monitored via a diode array detector at 260 nm. Two nucleosides were separated by less than 12 min after injection. The developed method was found to be excellent linear (r² > 0.9999), accurate (% recovery 95.34-98.51), and precise (% relative standard deviation < 2.0). The limit of detection (LOD) and quantification (LOQ) were 0.45 and 1.38 mg/mL for adenosine and 0.47 and 1.43 mg/mL for cordycepin, respectively. This method was satisfactory for simultaneously quantitating two nucleoside contents, which were used to evaluate Cordyceps products.