• Title/Summary/Keyword: THERMAL AGING

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Influence of Molecular Size of Liquid BR on Properties of Silica-Filled SBR Compounds (액상 BR의 분자 크기가 실리카로 보강된 SBR 배합물의 특성에 미치는 영향)

  • Choi, Sung-Seen
    • Elastomers and Composites
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    • v.36 no.3
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    • pp.162-168
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    • 2001
  • Low molecular weight polybutadiene (liquid BR) improves the filler dispersion in a silica-filled styrene-butadiene rubber (SBR) compound. In the present work, influence of molecular weight or the liquid BR on properties of a silica-filled SBR compound was studied. Minimum and maximum torques in the rheocurve for the compound containing the liquid BR with higher molecular weight (HLBR) are lower than those for the compound containing the liquid BR with lower one (LLBR) while the delta torques are nearly the same. Mooney scorch time of the compound containing HLBR is faster than that of the compound containing LLBR. Modulus or the compound containing HLBR is lower than that of the compound containing LLBR while tensile strength of the former is higher than that of the latter. The elongation at break of the former is also longer than that of the latter. Stability for the thermal aging at $90^{\circ}C$ for 3 days is less favorable for the former than for the latter.

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Experimental Research Application to each Types of Insulation Materials in Rural Houses (농촌주택의 단열 재료별 현장 적용을 위한 실험 연구)

  • Kwon, Soon-Chan;Kim, Eun-Ja
    • Journal of the Korean Institute of Rural Architecture
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    • v.19 no.4
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    • pp.57-65
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    • 2017
  • Life quality in farming areas is declining these days on account of decrease in population with the outflow of young generations, advent of aging society, and also lack of social and physical infrastructure. To reverse this, the central and local governments have been devising policies in many ways; however, the vulnerable class in farming area suffering from financial difficulty is not supported with that properly. The results of applying insulation materials applicable to rural houses, EPS, e-board, and glass wool, actually to rural houses are summed as follows. EPS is the most inexpensive among the three installations in terms of material cost and expenses. The indoor and outdoor temperature difference increased from $0.9^{\circ}C$ to $2.5^{\circ}C$, and the temperature change reduced as $0.04^{\circ}C$. With e-board, the indoor and outdoor temperature difference increased from $3.3^{\circ}C$ to $7.5^{\circ}C$; however, the temperature change increased as $0.09^{\circ}C$. Unlike the other two methods, glass wool requires the additional installation of wooden frames. The material cost is highest, and the indoor and outdoor temperature difference increased from $1.1^{\circ}C$ to $8.0^{\circ}C$, and the temperature change reduced as $0.01^{\circ}C$. According to the results of measuring temperature, glass wool's temperature difference is measured to be the highest, but temperature change is found to be the most effective in EPS. Among the three insulation methods, EPS is the most economically advantageous as the material supply is easy and the cost is low. The material is easily processible, so ordinary town residents can install it easily, and it is effective at improving insulation performance, too. But this method cannot be applied when the house has walls that are not even. Also, as the insulator is thick, after the installation, the living space may be narrower as a result.

Thermal and Electrical Properties of Poly(vinylidenefluoride-hexafluoropropylene)-based Gel-Electrolytes (Poly(vinylidenefluoride-hexafluoropropylene)계 겔-전해질의 열적, 전기적 특성)

  • 김영완;최병구;안순호
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.382-388
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    • 2000
  • Polymer electrolyte films consisting of poly(vinylidenefluoride-hexafluoropropylene) (PVdF-HFP), LiClO$_3$ and a mixture of ethylene carbonate (EC) and ${\gamma}$-butyrolactone (GBL) were examined in order to obtain the best compromise between high ionic conductivity, homogeniety, dimensional and electrochemical stability. Measurements of ionic conductivity, differential scanning calorimetry and linear sweep voltammetry have been carried out for various compositions. The highest conductivity of 3.8$\times$10$^{-3}$ S$cm^{-1}$ / at 3$0^{\circ}C$ were obtained for a film of 30(PVdF-HFP)+7.8LiClO$_4$+62.2EC/GBL. From the DSC study, it has been found that the PVdF-HFP gels are stable up to 10$0^{\circ}C$, and the salt lowers the melting temperature of crystalline part of PVdF by interacting sensitively with polymer segments. When Lithium metal is in contact with the gel films, it tends to undergo corrosion and the reaction products accumulate resulting in the formation of a passive film on Li electrode. As the aging time progresses, the interfacial resistance increases continuously. Anodic stability is measured to extend up to about 4.5 V vs. Li.

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Structural evaluation of all-GFRP cable-stayed footbridge after 20 years of service life

  • Gorski, Piotr;Stankiewicz, Beata;Tatara, Marcin
    • Steel and Composite Structures
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    • v.29 no.4
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    • pp.527-544
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    • 2018
  • The paper presents the study on a change in modal parameters and structural stiffness of cable-stayed Fiberline Bridge made entirely of Glass Fiber Reinforced Polymer (GFRP) composite used for 20 years in the fjord area of Kolding, Denmark. Due to this specific location the bridge structure was subjected to natural aging in harsh environmental conditions. The flexural properties of the pultruded GFRP profiles acquired from the analyzed footbridge in 1997 and 2012 were determined through three-point bending tests. It was found that the Young's modulus increased by approximately 9%. Moreover, the influence of the temperature on the storage and loss modulus of GFRP material acquired from the Fiberline Bridge was studied by the dynamic mechanical analysis. The good thermal stability in potential real temperatures was found. The natural vibration frequencies and mode shapes of the bridge for its original state were evaluated through the application of the Finite Element (FE) method. The initial FE model was created using the real geometrical and material data obtained from both the design data and flexural test results performed in 1997 for the intact composite GFRP material. Full scale experimental investigations of the free-decay response under human jumping for the experimental state were carried out applying accelerometers. Seven natural frequencies, corresponding mode shapes and damping ratios were identified. The numerical and experimental results were compared. Based on the difference in the fundamental natural frequency it was again confirmed that the structural stiffness of the bridge increased by about 9% after 20 years of service life. Data collected from this study were used to validate the assumed FE model. It can be concluded that the updated FE model accurately reproduces the dynamic behavior of the bridge and can be used as a proper baseline model for the long-term monitoring to evaluate the overall structural response under service loads. The obtained results provided a relevant data for the structural health monitoring of all-GFRP bridge.

Finite Element Analysis of Residual Stress after Quenching and Element Removal of A1 Ring Rolls (알루미늄 링롤재의 급냉 및 요소제거 후 잔류응력의 유한요소해석)

  • 박성한;구송회;이방업;조원만;은일상
    • Journal of the Korean Society of Propulsion Engineers
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    • v.2 no.1
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    • pp.31-40
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    • 1998
  • To predict residual stresses of aluminum ring rolls after quenching and element removal, 2-D and 3-D thermal elasto-plastic analyses were performed. Strains measured by three step sectioning method were directly compared to those analysed using ABAQUS's element removal. Numerical residual stresses after quenching had similar tendency to measured ones after 2 step aging, but the difference between numerical and measured ones was large. The difference is the reason why there are nonuniform residual stress distributions to ring height direction due to small height of ring, It is judged that the increase of ring height will improve the accuracy of measured ones and decrease the difference. By direct comparison between 3-D numerical strains to simulate three step sectioning method and measured ones, the accuracy of measurement and analysis can be improved. It is concluded that there can be predicted the deformation behavior on machining complex shaped large structures with residual stresses.

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A Study on the Lifetime Estimation and Leakage Test of Rubber O-ring in Contacted with Fuel at Accelerated Thermal Aging Conditions (가속노화조건 하 연료접촉 고무오링의 수명예측 및 누유시험 연구)

  • Chung, Kunwoo;Hong, Jinsook;Kim, Young-wun;Han, Jeongsik;Jeong, Byunghun;Kwon, Youngil
    • Tribology and Lubricants
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    • v.35 no.4
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    • pp.222-228
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    • 2019
  • As rubber products such as O-rings, which are also known as packings or toric joints, come in regular, long term contact with liquid fuel, they can eventually swell, become mechanically weakened, and occasionally crack; this diminishes both their usefulness and intrinsic lifetime and could cause leaks during the steady-state flow condition of the fuel. In this study, we evaluate the lifetime of such products through compression set tests of FKM, a family of fluorocarbon elastomer materials defined by the ASTM international standard D141; these materials have great compression, sunlight, and ozone resistance as well as a low gas absorption rate. In this process, O-rings are immersed in the liquid fuel of airtight containers that can be expressed as a compression set, and the liquid fuel leakage in a flow rig tester at variable temperatures over 12 months is investigated. Using the Power Law model, our study determined a theoretical O-ring lifetime of 2,647 years, i.e. a semi-permanent lifespan, by confirming the absence of liquid fuel leakage around the O-ring assembled fittings. These results indicate that the FKM O-rings are significantly compatible for fuel tests to evaluate long-term sealing conditions.

Study on the Degradaion Behavior of Acrylonitrile Rubber(NBR) O-ring by Intermittent CSR and Time-Temperature Superposition Principle (간헐 압축응력완화 시험법과 시간-온도 중첩 이론을 이용한 NBR 오링의 노화 거동 분석 연구)

  • Lee, Jin Hyok;Bae, Jong Woo;Choi, Myung Chan;Yun, Yu Mi;Kim, Wonho;Park, Sung Han;Jo, Nam-Ju
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.46-51
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    • 2019
  • Intermittent CSR testing was used to investigate the degradation of a NBR O-ring, and also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. Degradation of O-rings by thermal aging was observed between $40^{\circ}C$ and $120^{\circ}C$. O-rings showed non-linear degradation behavior under $80^{\circ}C$. At 20% of failure condition, predicted life-times were 32.5 years by Arrhenius plot and 22.6 years by WLF plot.

Solidification Structure of Superalloy René 80 and Variation of Tensile Properties after Heat-Treatment (초내열합금 René 80의 응고 조직과 열처리 후 인장특성의 변화)

  • Woo, Hanbyeol;Shin, Jongho;Joo, Yunkon;Lee, Jehyun
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.678-686
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    • 2020
  • Microstructural characteristics of directionally solidified René 80 superalloy are investigated with optical microscope and scanning electron microscope; solidification velocity is found to change from 25 to 200 μm/s under the condition of constant thermal gradient (G) and constant alloy composition (Co). Based on differential scanning calorimetry (DSC) measurement, γ phase (1,322 ℃), MC carbide (1,278 ℃), γ/γ' eutectic phase (1,202 ℃), and γ' precipitate (1,136 ℃) are formed sequentially during cooling process. The size of the MC carbide and γ/γ' eutectic phases gradually decrease with increasing solidification velocity, whereas the area fractions of MC carbide and γ/γ' eutectic phase are nearly constant as a function of solidification velocity. It is estimated that the area fractions of MC carbide and γ/γ' eutectic phase are determined not by the solidification velocity but by the alloy composition. Microstructural characteristics of René 80 superalloy after solid solution heat-treatment and primary aging heat-treatment are such that the size and the area fraction of γ' precipitate are nearly constant with solidification velocity and the area fraction of γ/γ' eutectic phase decreases from 1.7 % to 0.955 %, which is also constant regardless of the solidification velocity. However, the size of carbide solely decreases with increasing solidification velocity, which influences the tensile properties at room temperature.

Analysis of Fish Activity in Relation to Feeding Events Using Infrared Cameras (적외선 카메라를 활용한 급이 유무에 따른 어류 활동성 분석)

  • Roh, Tae Kyoung;Ha, Sang Hyun;Kim, Ki Hwan;Kang, Young Jin;Jeong, Seok Chan
    • The Journal of Information Systems
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    • v.32 no.4
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    • pp.137-147
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    • 2023
  • Purpose The domestic aquaculture industry in South Korea utilizes both formulated feeds and live feeds for the cultivation of fish. While nutrient-rich live feeds, particularly using fry, have been preferred since the past, formulated feeds are gaining attention due to issues related to overfishing and environmental concerns. Formulated feeds are advantageous for storage and supply but require a sustained feeding regimen due to the comparatively slower growth rate compared to live feeds. As the aging population in rural areas leads to a shortage of labor, automated feeding systems are increasingly being adopted in aquaculture facilities. To enhance the efficiency of such systems, it is crucial to quantitatively analyze the behavioral changes in fish based on the presence or absence of feed. Design/methodology/approach In the study, RGB cameras and infrared cameras were used to analyze fish activity according to feeding, and an outline extraction algorithm was applied to analyze the differences resulting from this. Findings Unlike RGB cameras, infrared cameras are more suitable for analyzing underwater fish activity as they convert objects' thermal energy into images. It was observed that Canny, Sobel, and Prewitt filters showed the most distinct identification of fish activity.

Pomegranate extract on eroded dentin: antioxidant action, bond strength and morphology of the adhesive interface after aging

  • Thiago Vinicius Cortez;Nathalia Mancioppi Cerqueira;Julia Adornes Gallas;Wanderley Pereira Oliveira;Silmara Aparecida Milori Corona;Aline Evangelista Souza-Gabriel
    • Restorative Dentistry and Endodontics
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    • v.49 no.1
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    • pp.9.1-9.14
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    • 2024
  • Objectives: This study aimed to evaluate the effect of pomegranate solution (Punica granatum) on eroded dentin through antioxidant action, shear bond strength (SBS) and interface morphology. Materials and Methods: The 10% pomegranate peel extract was prepared by the lyophilization method. Punicalagin polyphenol was confirmed by high-performance liquid chromatography. Antioxidant activity was evaluated by capturing the 2,2-diphenyl1-picrylhydrazyl (DPPH) radical. For the SBS, 48 dentin fragments were divided into sound or eroded, and subdivided according to the pretreatment (n = 12): water or P. granatum. The surfaces were restored with self-etch adhesive and a bulk-fill resin (Ecosite; DMG). The SBS was done immediately (24 hours) and after thermal cycling + water storage (12 months). For scanning electron microscopy, 48 dentin fragments (24 sound and 24 eroded) received the same treatments as for SBS (n = 6), and they were analyzed after 24 hours and 12 months. Results: The P. granatum had antioxidant action similar (p = 0.246) to the phenolic standard antioxidants. After 24 hours, eroded dentin had lower SBS than sound dentin (p < 0.001), regardless of the pretreatment. After 12 months, P. granatum maintained the SBS of sound dentin (13.46 ± 3.42 MPa) and eroded dentin (10.96 ± 1.90 MPa) statistically similar. The lowest values were found on eroded dentin treated with water (5.75 ± 1.65 MPa) (p < 0.001). P. granatum on eroded dentin caused peritubular demineralization and hybrid layer with resin tags. Conclusions: The pomegranate extract had antioxidant action and preserved the adhesive interface of the eroded dentin.