• Title/Summary/Keyword: TEM analysis

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TEM Analysis of Interfaces between Cr Film Sputtered with RE Bias and Photosensitive Polyimide (RE 바이어스 스퍼터링한 Cr 박막과 감광성 폴리이미드 사이의 계면 TEM 분석)

  • 조성수;김영호
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.2
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    • pp.39-47
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    • 2003
  • Cr thin films were deposited on photosensitive polyimide substrates by RF bias sputtering and DC sputtering and the interfaces between Cr thin film and polyimide were observed using TEM. When the polyimide surface was in-situ RF plasma cleaned at the RF power density of 0.13-2.12 $W/cm^2$, increasing of RF power density changed the morphology of polyimide surfaces from round dig to sharp shape, and surface roughness increased by anisotropic etching. The intermixed layer-like interfaces between Cr and polyimide were observed in the RF bias sputtered specimens. This interface seems to be formed due to the RF cleaning effect; the polyimide surface was RF plasma cleaned while RF power was increased to the setting point before Cr deposition.

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Effect of Preparation Method for Pd/C Catalysts on Pd Characterization and their Catalytic Activity (Pd/C 촉매 제조 방법에 따른 Pd 금속의 특성 및 촉매 활성)

  • Kim, Ji Sun;Hong, Seong-Soo;Kim, Jong-Hwa;Lee, Man Sig
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.575-580
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    • 2015
  • Pd/C catalysts were prepared by various preparation methods such as ion exchange, impregnation and polyol method and also characterized by nitrogen adsorption-desorption isothermal, XRD, FE-TEM and CO-chemisorption. The activities of these catalysts were tested in the hydrogenation of cyclohexene to cyclohexane. Catalytic activities of Pd/C catalysts were found to be effected by the chosen preparation methods. Pd dispersions of each Pd/C catalysts prepared by ion exchange, impregnation and polyol method were 17.55, 13.82% and 1.35%, respectively, confirmed by CO-chemisorption analysis. These were also in good agreement with the FE-TEM results. The Pd/C catalyst prepared by ion exchange method exhibits good performance with the cyclohexene conversion rate of 71% for 15 min. These results indicate that Pd/C catalyst having higher dispersion and lower particle size is in favor of hydrogenation cyclohexene and also Pd dispersion increases with the increment of catalytic activity.

An Investigation on Structural Analysis of Feldspars by Electron Diffraction Patterns (전자회절도형을 이용한 장석의 구조 분석에 대한 고찰)

  • 김윤중;이영부;박병규;이정후
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.2
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    • pp.177-187
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    • 2004
  • Measurements of the lattice parameters of albite and oligoclase from electron diffraction patterns with the Au internal standard resulted in errors of less than 1 %. An electron diffraction map for natural oligoclase samples was constructed and 11 stations of zone-axes diffraction patterns were obtained. This process is indispensible for reliable TEM studies of triclinic feldspars. Utilizing the [001] cleavage plane of feldspar and the double-tilting TEM holder the following information is obtainable: Si-Al ordering and chemistry of alkali feldspars could be estimated from the $\alpha$* - * plot, where * is measured from the [001] orientation, while $\alpha$* is measured from the [100] orientation. Si-Al ordering of Na-rich plagioclase could be estimated from * [001] patterns. Structure and chemistry or Na-poor plagioclase could be estimated from existence of e-reflections, their intensity variations as well as their positional changes.

Analysis of the antibiotic resistance gene in Salmonella Typhimurium isolates from diseased pigs in Gyeongbuk province (경북지역 환돈 유래 Salmonella Typhimurium의 약제내성 유전자 분석)

  • Kim, Joo-Hyung;Kim, Seong-Guk;Kim, Seon-Soo;Kim, Jeong-Hwa;Park, Sye-Hee;Nam, Ki-Hu;Kim, Hyoung-Bae
    • Korean Journal of Veterinary Service
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    • v.36 no.2
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    • pp.73-78
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    • 2013
  • This study was conducted to investigate antibiotic resistance among Salmonella Typhimurium isolates from diseased pigs in Gyeongbuk province during the period 1998~2011. One hundred forty one isolates were tested for antibiotic resistance using the standard disk diffusion method and were examined for presence of resistance gene by PCR method. S. Typhimurium showed high drug resistance rates to tetracycline (95.7%), streptomycin (93.6%), ampicillin (86.5%), cephalothin (80.1%), gentamicin (79.4%), and trimethoprim/sulfamethoxazole (72.3%). Resistance gene, blaTEM, blaPSE1, tetA, tetB, tetG, sul1, sul2, aadA, strA, grm, and temA were detected among the antibiotic resistance isolates and temB, tetC, aadB gene were not detected. One hundred twenty one (89.6%) tetA, two (1.5%) tetB and one (0.7%) tetG gene were detected in the 135 tetracycline resistant isolates. Two (1.6%) temA gene were detected in one hundred twenty two ampicillin resistance isolates and temB was not detected.

Types of Extended-Spectrum β-Lactamase Produced in Enteric Bacteria Isolated from Sewage Plant Drain Water (하수처리수에서 분리된 장내세균의 광범위 베타락탐분해효소의 유형)

  • Kim, Gun-Do;Lee, Hun-Ku
    • Journal of Life Science
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    • v.20 no.5
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    • pp.676-682
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    • 2010
  • This study focused on typing of the extended-spectrum $\beta$-lactamase (ESBL) produced in organisms isolated from a natural environment, rather than a clinical setting. Samples were collected from drain water issuing from a sewage plant in Kwanganri (Busan, Korea). Following double disk synergy testing, 29 strains were selected as potential ESBL positive strains. Of these, 15 strains were transconjugants of the sodium azide resistant recipient strain Escherichia coli J53 and analyzed biochemically including indole, methyl-red, Voges-Proskauer, Simmon's citrate, decarboxylase-dihydrolase and sugar-fermentation tests. The tests classified the 15 strains as Klebsiella pneumoniae (n=13) and Escherichia coli (n=2). The type of ESBL from each strain was deduced by isoelectric focusing point analysis and DNA sequencing. The results indicated that the types of ESBL were SHV-12 (n=4) and SHV-12/TEM-1 (n=9) from K. pneumoniae and TEM-1 (n=2) from E. coli strains.

Effects of Al in TRIP steels on microstructure and phase transformation (TRIP강에서 Al이 미세구조와 상변태에 미치는 영향)

  • Lim, N.S.;Kim, S.I.;Park, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.213-216
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    • 2009
  • In this study, three cold-rolled TRIP steels containing different Al content (0.04wt%, 1.0 wt.% and 2.00wt%) were fabricated to understand the complex effects of Al in TRIP steel. The influences of Al on microstructural evolution of cold-rolled TRIP steels have been analyzed by using advanced analysis techniques, such as transmission electron microscope (TEM) and three dimensional atom probe tomography (3D-APT). TEM results revealed that second phases such as bainte and retained austenite decrease with increase of Al content. In addition, 3D-APT was used to characterize atomic-scale distribution of alloying elements at the constituent phases. Through these analysis techniques, the advanced characteristics of constituent microstructure in TRIP steels were identified depending on Al contents in TRIP steels.

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Characteristics of ZnO Nanowire Fabricated by Thermal Evaporation Method Depending on Different Temperatures and Oxygen Pressure (Thermal Evaporation법으로 제작한 ZnO 나노선의 온도와 산소유량에 따른 성장 특성)

  • Oh, Won-Seok;Jang, Gun-Eik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.8
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    • pp.766-769
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    • 2008
  • Zinc oxide (ZnO) nanowires were prepared on Si substrates by a thermal evaporation method at different temperatures and $O_2$ pressure. Microstructural analysis of the obtained ZnO nanowires was performed by using transmission electron microscopy(TEM) and scanning electron microscopy(SEM). Phase analysis was done using X-ray diffraction(XRD). As the deposition temperature and oxygen pressure were increased, the diameter and length of ZnO nanowires had a tendency to increase. Based on TEM and XRD analyses, the nanowires are single crystalline in nature and consist of a single phase. According to the measurements, the ZnO nanowires grown at 1100$^{\circ}C$, Ar 50 sccm, $O_2$ 10 sccm have good properties.

Response of Angled two-Strip Transmission Lines to the Incident Angle of an External Electromagnetic Field, II : Modal Analysis on an Equivalent Structure (외부 전자파의 입사방향에 대한 각진 두 스트립으로 구성된 전송선의 반응, II:등가구조의 모드해석)

  • 홍성용;김세윤;나정웅
    • The Proceeding of the Korean Institute of Electromagnetic Engineering and Science
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    • v.4 no.1
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    • pp.3-9
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    • 1993
  • A new method is developed for analysis of the electromagnetic coupling to an angled two-strip transmission line. It consists of solving the cylindrical transmission line equations an- alytically, and then adjusting the involved parameters to support the cylindrical TEM mode along its equivalent model of the angled two-plate transmission line. Its analytic solution agrees with the numerical value obtained by using the circuit-concept approach.

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Experimental Analysis on Particle Growth in TEOS/O2 Plasma Reactor (TEOS/O2용 플라즈마 반응기에서의 미립자 성장에 대한 실험적 분석)

  • Hong, Sung-Taik;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.23 no.A
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    • pp.175-179
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    • 2003
  • A study on the particle growth in $TEOS/O_2$ plasma was performed by observing the particle size and its morphology by TEM. The qualitative chemical analysis of particles was also determined by the EDS (Energy Dispersive X-Ray Spectrometer). The effects of process variables such as the plasma on-time and bubbler temperature on the particle growth were investigated. The particle size becomes larger as the plasma on-time because of the longer coagulation, and also as the bubbler temperature increases because of the faster coagulation between particles.

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A study for development of high speed hard chrome plating solution (고속 경질 크롬 도금 용액 개발에 관한 연구)

  • 추현식;이홍로
    • Journal of the Korean institute of surface engineering
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    • v.25 no.5
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    • pp.263-269
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    • 1992
  • To enhancing efficiency of hard chrome plating solution more highly, cathode current efficiency were surveyed connected with hardness of deposits, surface morphology, TEM analysis and corrosion test of anode materials. Efficiency war increased up to 26% values by adding catalyst and two kind of additives. With given bath composition and 6$0^{\circ}C$, 60A/d$\m^2$ electrolosis conditionss bright and micro cracked deposits were well obtained, which showed HV 1000 values. From corrosion tests, anode materials such as Pb-Te (0.02%) and Pb-Ag(1%) showed most anti-corrosive results. Through SEM micrograph observations, ef-fects of additives on levelling, brightness and micro crack properties of hard chrome deposits could be con-firmed. Also, through TEM analysis the fact that deposits from crack free solution or high speed solution were more fine than from sargent solution could be confirmed.

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