• Korean Chemical Engineering Research
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• v.44 no.6
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• pp.650-658
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• 2006

The recycling of TDA from solid waste of TDI plant(TDI-R) by near-critical hydrolysis reaction had been studied by means of a statistical design of experiment. The main and interaction effects of process variables had been defined from the experiments in a batch reactor and the correlation equation with process variables for TDA yield had been obtained from the experiments in a continuous pilot plant. It was confirmed that the effects of reaction temperature, catalyst type and concentration, and the weight ratio of water to TDI-R(WR) on TDA yield were significant. TDA yield decreased with increases in reaction temperature and catalyst concentration, and increased with an increase in WR. As a catalyst, NaOH was more effective than $Na_2CO_3$ for TDA yield. The interaction effects between catalyst concentration and temperature, WR and temperature, catalyst type and reaction time on TDA yield had been defined as significant. Although the effect of catalyst concentration on TDA yield at $300^{\circ}C$ as subcritical water was insignificant, the TDA yield decreased with increasing catalyst concentration at $400^{\circ}C$ as supercritical water. On the other hand, the yield increased with an increase in WR at $300^{\circ}C$ but showed negligible effect with WR at $400^{\circ}C$. The optimization of process variables for TDA yield has been explored with a pilot plant for scale-up. The catalyst concentration and WR were selected as process variables with respect to economic feasibility and efficiency. The effects of process variables on TDA yield had been explored by means of central composite design. The TDA yield increased with an increase in catalyst concentration. It showed maximum value at below 2.5 of WR and then decreased with an increase in WR. However, the ratio at which the TDA yield showed a maximum value increased with increasing catalyst concentration. The correlation equation of a quadratic model with catalyst concentration and WR had been obtained by the regression analysis of experimental results in a pilot plant.

• Geomechanics and Engineering
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• v.22 no.3
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• pp.197-206
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• 2020

Reutilization of solid waste such as Tire Derived Aggregate (TDA) and mixing it with soft soil for backfill material not only reduces the required volume of backfill soil (i.e., sand-mining procedures; reinforcement), but also preserves the environment from pollution by recycling. TDA is a widely-used material that has a good track record for improving sustainable construction. This paper attempted to investigate the performance of Kaolin-TDA mixtures as a backfill material underneath a strip footing and close to a retaining wall. For this purpose, different types of TDA i.e., powdery, shredded, small-size granular (1-4 mm) and large-size granular (5-8 mm), were mixed with Kaolin at 0, 20, 40, and 60% by weight. Static surcharge load with the rate of 10 kPa per min was applied on the strip footing until the failure of footing happened. The behaviour of samples K80-G (1-4 mm) 20 and K80-G (5-8 mm) 20 were identical to that of pure Kaolin, except that the maximum footing stress had grown by roughly three times (300-310 kPa). Therefore, it can be concluded that the total flexibility of the backfill and shear strength of the strip footing have been increased by adding the TDA. The results indicate that, a significant increase in the failure vertical stress of the footing is observed at the optimum mixture content. In addition, the TDA increases the elasticity behaviour of the backfill.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.513-513
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• 2012

핵 융합로의 대면재질(Plasma Facing Material; PFM)은 고온의 플라즈마와 고 에너지의 이온들에 지속적으로 노출 된다. 특히 PFM은 흡착되는 기체 등에 의한 부식과 변형이 발생할 수 있다. 현재 핵 융합로 내부의 PFM으로 고려되고 있는 재질 중 하나인 고순도 탄소타일의 경우 고온의 수소동위원소 플라즈마에 직접적으로 노출되므로 이에 의한 탄소타일에 흡착되는 수소 등의 기체에 대한 정량적인 분석방법이 필요하다. 본 연구는 고순도 탄소타일 등과 같은 플라즈마 대면재료에 흡착되어 있는 물질의 정량적 분석이 가능한 TDA (Thermal Desorption Analyzer)의 개념 설계에 관한 것이다. TDA는 고온 가열($800^{\circ}C$ 이상) 및 시료 장착부 및 초고진공(~10-9 torr) 및 측정부의 두 부분으로 구성 하였다. TDA 설계시 고온 가열 및 시료 장착부는 시료 내부에 흡착되어 있는 기체의 효과적 탈착을 위한 가열 및 시료의 모양에 영향을 받지 않는 장착방법, 시료 장착부의 outgassing rate를 최소화 하는 재질 선정 등을 고려하였으며, 초고진공(~10-9 torr) 및 측정부는 초고진공 유지방법, 터보펌프 배기속도 실측을 위한 구조, 진공측정 ion 게이지, 잔류가스분석기(Residual Gas Analyzer)의 최적위치 설정 등을 고려하여 설계하였다. 개념 설계된 TDA에 대하여 발표하고자 한다.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.27 no.4
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• pp.324-341
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• 2023

Topological data analysis (TDA) is a data analysis technique, recently developed, that investigates the overall shape of a given dataset. The mapper algorithm is a TDA method that considers the connectivity of the given data and converts the data into a mapper graph. Compared to persistent homology, another popular TDA tool, that mainly focuses on the homological structure of the given data, the mapper algorithm is more of a visualization method that represents the given data as a graph in a lower dimension. As it visualizes the overall data connectivity, it could be used as a prediction method that visualizes the new input points on the mapper graph. The existing mapper packages such as Giotto-TDA, Gudhi and Kepler Mapper provide the descriptive mapper algorithm, that is, the final output of those packages is mainly the mapper graph. In this paper, we develop a simple predictive algorithm. That is, the proposed algorithm identifies the node information within the established mapper graph associated with the new emerging data point. By checking the feature of the detected nodes, such as the anomality of the identified nodes, we can determine the feature of the new input data point. As an example, we employ the fraud credit card transaction data and provide an example that shows how the developed algorithm can be used as a node prediction method.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1996.04a
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• pp.184-187
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• 1996

본 연구에서는 산업 현장에서 중장비 엔진마운트를 설계함에 있어서 벤치상태에서의 번거로움과 비현실성을 해결하고 실차상태의 하중 조건에 맞는 적절한 엔진마운트를 설계하기 위해 TDA(Time Domain Analysis) 기법을 도입하여 굴삭기 모델에 응용하여 이론치와 실험치를 비교 검토하고 승차감향상을 도모하였다.

• Journal of Radiation Protection and Research
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• v.36 no.3
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• pp.154-159
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• 2011

To evaluate the radiation exposure of workers participating in task where high radiation exposure is expected, two-dosimeter is typically provided radiation workers, one on the chest and the other on the back, at Korean nuclear power plants (NPPs). In a previous study, the NCRP (55:50) algorithm was selected as the optimal two-dosimeter algorithm (TDA) with various field tests and this TDA has been applied to all Korean NPPs since 2006. In 2007, the International Commission on Radiological Protection (ICRP) published the new ICRP recommendation, ICRP 103, which provides the revised weighting factors for both radiation and tissues and the new reference phantom. In this study, the applicability of current NCRP (55:50) algorithm at Korean NPPs for ICRP 103 was analyzed. As a result, it was found that the NCRP (55:50) algorithm is still effective to estimate the effective dose of workers under ICRP 103.

• Journal of the Korean Chemical Society
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• v.63 no.2
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• pp.73-77
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• 2019

We compared methodologies based on the density functional theory (DFT), e.g., time-dependent DFT (TD-DFT), TD-DFT within Tamm-Dancoff approximation (TDA-DFT), and spin-unrestricted DFT (UDFT), that are usually employed to optimize the geometries of ${\pi}$-conjugated molecules in their lowest lying triplet excited ($T_1$) state. As a model system for ${\pi}$-conjugated molecules, we employed 1,2,3,4,5-pentacyano-6-phenyl-benzene. In conjunction with 6-31G(d) basis sets, we made use of gap-tuned range-separated ${\omega}B97X$ functional which is often employed recently in the calculations of molecular excited states. Near the equilibrium geometries, we found that the important difference between the geometries derived at UDFT level and those at TD-DFT or TDA-DFT methods: more stable ground-state energies but higher triplet excitation energies for UDFT derived geometries. In the studies, we discuss such differences in more detail.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.26 no.2
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• pp.178-187
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• 2016

Objectives: Diisocyanates are a potent inducer of diseases of the airways, especially asthma. In this study, toluenediamine(TDA) and methylenedianiline(MDA) in urine were evaluated as biomarkers of exposure to tolunenediisocyanate(TDI) and methylenediphenyl diisocyanate(MDI), respectively. Methods: Workers exposed to TDI and MDI, as well as non-occupationally exposed subjects, were studied and pre- and post-shift urine samples were collected from 8 control subjects and 8 workers from a factory which manufactures polyurethane products for reducing noise and vibration in automobiles. Airborne TDI and MDI(n=8) were sampled on solvent-free glass filters impregnated with n-butylamine and detected by liquid chromatography atmospheric pressure ionization tandem mass spectrometry. Urinary TDA and MDA were detected as pentafluoropropionic acid anhydride(PFPA) derivatives by liquid chromatography electrospray ionization tandem mass spectrometry. Results: The median levels of urinary 2,6-TDA(p<0.001), 2,4-TDA(p=0.001), and MDA(p<0.001) of workers in post-shift samples were significantly higher than those of controls. The median levels of urinary 2,6-0TDA($0.63{\mu}g/g$ creatinine vs $0.34{\mu}g/g$ creatinine, p=0.017) and MDA($4.21{\mu}g/g$ creatinine vs $3.18{\mu}g/g$ creatinine, p=0.017) of workers in post-shift samples were significantly higher than those of the pre-shift samples. There were significant correlations between the urinary 2,6-TDA, 2,4-TDA, and MDA of workers in post-shift samples and the airborne 2,6-TDI(rho=0.952, p<0.001), 2,4-TDI(rho=0.833, p=0.001), and MDI(rho=0.952, p<0.001). Conclusions: These urinary diamines, metabolites of diisocyanates, in post-shift samples were useful biomarkers to assess occupational exposure to diisocyanates.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.15 no.12
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• pp.4584-4599
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• 2021

In IEEE 802.11p-based wireless access in vehicular environments (WAVE) communication systems, channel estimation (CE) is one of the important issues to provide stable communication service. It is hard to apply conventional CE schemes based on data pilot to real systems, because error propagation occurs in high mobility and modulation order environments, resulting in degrading the CE performance. In this paper, we propose one data pilot using multiple receive antennas (ODPM) CE scheme based on the weighted sum using update matrix (WSUM) with time-domain averaging (TDA) to overcome this problem. Within the process of WSUM-TDA in the proposed scheme, the maximum ratio combining (MRC) technique is applied so as to create more accurate one data pilot. Moreover, a new reliability test criterion is proposed as the fashion of utilizing MRC, which makes it possible to apply selective TDA that guarantees performance improvement. In simulation results, the packet error rate (PER) performance of the proposed ODPM is compared with that of conventional CE methods and its superiority is demonstrated.

• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.1036-1042
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• 1998

It was investigated that the extraction of Cr(VI) from aqueous solution into the organic TDA and the stripping(back extraction) of Cr(VI) from the Cr(VI)-TDA complex into NaOH aqueous solution by hydrophobic hollow fiber membrane. It was found that the mass transfer rates of stripping process were smaller than those of the extraction process. This result was expected that membrane resistance, neglected in the extraction process, acts on the stripping process when organic phase flow in the tube side of the hydrophobic membrane. Hollow fiber modules were made by potting the desired number(60, 100, 150, 300fibers). We also examined the effect of flow rates of aqueous and organic phase on the mass transfer rate in the membrane modules. From these experiments, we identified for the extraction process by using hydrophobic membrane, the effect of flow rate of aqueous phase on the mass transfer rate was significant, but that of organic phase was negligible one. In the stripping process, however, mass transfer rate depend neither flow rate of aqueous(stripping solution) phase nor that of organic(Cr-TDA complex) phase.