• Title/Summary/Keyword: Synthetic adhesive

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Characterization of Plasma Proteins from Bloods of Slaughtered Cow and Pig and Utilization of the Proteins as Adhesives (도축혈액 혈장 단백질의 특성 및 접착제로의 응용)

  • Park, Eun-Hee;Lee, Hwa-Hyoung;Song, Kyung-Bin
    • Applied Biological Chemistry
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    • v.39 no.2
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    • pp.123-126
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    • 1996
  • Simple and rapid method of purification of plasma proteins from bloods of slaughtered animals was developed and the proteins were applied to plywood products as a blood 히ue to utilize waste materials. Plasma protein was obtained by adding 2% trichloroacetic acid (TCA) or 0.6 N HCI as optimal concentration to the supernatant, after centrifugation of bloods. Molecular properties of beef and pig plasma proteins were examined on SDS-PAGE. Application of blood glue to plywood was quite satisfactory compared to the synthetic amino resin by tensile-shear test for the strength of adhesive bonding.

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Synthesis of Renewable Resource-derived Furan-based Epoxy Compounds and Their Adhesive Property (재생자원 유래 퓨란계 에폭시 화합물의 합성 및 접착 특성)

  • Lee, Jae-Soung;Lee, Sang-Hyeup;Jeong, Jaewon;Kim, Baekjin;Cho, Jin Ku;Kim, Hyun Joong
    • Journal of Adhesion and Interface
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    • v.11 no.2
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    • pp.41-49
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    • 2010
  • Furan-containing epoxide monomers (8, 9) were designed and synthesized as carbon-neutral, environment-friendly adhesion material. Bicyclic skeleton were constructed using the Diels-Alder reaction of furan and methyl acrylate, both readily accessible starting material from a biomass via bio-refinery process. After reduction of ester functionality, resulting hydroxyl moieties were coupled to epichlorohydrin to provide the epoxy-functionalized furanic monomers (8, 9). The structure of new furanic monomers was confirmed by $^1H$ and $^{13}C$ NMR spectroscopy. As UV-curable monomers, basic properties such as UV curing time and the extent of UV curing were evaluated by photo DSC. Photo-curing shrinkages were measured by linear variable differential transformer transducer (LVDT) and the effect of molecular structure on shrinkage was considered. In addition, new synthetic compounds showed the shear strength over 3 MPa when they were photo-cured between polycarbonate plates, which indicates these compounds are feasible to use as photo-curable adhesive materials.

Adhesion Performance of Natural Rubber-based Pressure-Sensitive Adhesives for Protecting of Opto-functionalized Sheet (광기능성시트 보호용 천연고무계 점착제의 점착 물성)

  • Park, Young-Jun;Lim, Dong-Hyuk;Kim, Hyun-Joong;Song, Hyun-Suk;Kwon, Hyuk-Jin
    • Journal of Adhesion and Interface
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    • v.8 no.2
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    • pp.15-21
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    • 2007
  • To prepare a natural rubber-based pressure-sensitive adhesive (PSA) for protection film of opto- functionalized sheet, natural rubber (NR) was blended with a DCPD type tackifier and three types of aliphatic hydrocarbon resins, respectively. Also, to supply low cohesion strength of NR, in the fixed ratio of tackifier, synthetic rubber, styrene-isoprene-styrene (SIS) block copolymer was blended with NR as a function of SIS contents. PSA performance of prepared PSAs was evaluated using probe tack and peel strength. Probe tack of NR/tackifier blends was increased with increasing tackifier contents, and showed maximum peak. In addition, probe tack of NR/tackifier blends slightly increased with increasing softening point of aliphatic hydrocarbon resins. Their peel strength increased up to 50 wt% of tackifier contents, but in the over contents of tackifier, they showed stick-slip failure mode. Finally, probe tack of NR/SIS/tackifier blends showed the maximum values at 20~40 wt% of tackifier contents, but at 20 wt% of tackifier contents, they showed fibrillation. For this reason, peel strength showed maximum values at 40 wt% of tackifier contents.

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A Study on Conservation and Manufacturing Techniques of a Seated Avalokiteshvara with a Thousand Hands of Goryeo Dynasty (고려시대 금동제십일면천수관음보살좌상의 보존처리 및 제작기술 연구)

  • Gwak, Hong In;Kwon, Mi Hye
    • Journal of Conservation Science
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    • v.35 no.3
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    • pp.253-258
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    • 2019
  • The gilt bronze statue, Seated Avalokiteshvara with a Thousand Hands, of the Goryeo dynasty, is the only one in Korea of its kind that has undergone a conservation process for the special exhibition entitled GORYEO: The Glory of Korea. For the conservation treatment, first, a component analysis (XRF) was conducted, and a manufacturing technique (CT) was analyzed. The results of the investigation revealed that the statue was alloyed with Cu, Sn, and Pb ternary bronze. Its surface, except for the detached plating layers, was originally plated using the mercury amalgam method. This statue was assembled after separately casting each part of the body, such as the left and right arms and the wrists, including the hands, with objects. In particular, each wrist was cast and fitted with a metal nail to express each object in the hands more precisely. Inside the statue, there were five iron cores: two for the head, one for the left elbow, one for the right flank, and one for the right waist. For the preservative treatment, natural adhesive agents, including vegetable gelatin and glue (20%), were mixed with alcohol to protect the base metal and adhere to the plating layers. Using synthetic resin (CDK 520+SN-sheet) for the damaged parts, the restored parts could be attached and detached to/from the statue. Eventually, the compositional analysis and conservation treatment left the statue in a stable condition and ready for exhibitions and future studies.

Manufacture and Qualification of Composite Main Reflector of High Stable Deployable Antenna for Satellite (위성용 전개형 고안정 반사판 안테나 주반사판 제작 및 검증)

  • Dong-Geon Kim;Hyun-Guk Kim;Dong-Yeon Kim;Kyung-Rae Koo;Ji-min An;O-young Choi
    • Composites Research
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    • v.37 no.3
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    • pp.219-225
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    • 2024
  • It is essential to develop a light-weight, high-performance structure for the deployable reflector antenna, which is the payload of a reconnaissance satellite, considering launch and orbital operation performance. Among them, the composite main reflector is a key component that constitutes a deployable reflector antenna. In particular, the development of a high-performance main reflector is required to acquire high-quality satellite images after agile attitude control maneuvers during satellite missions. To develop main reflector, the initial design of the main reflector was confirmed considering the structural performance according to the laminate stacking design and material properties of the composite main reflector that constitutes the deployable reflector antenna. Based on the initial design, four types of composite main reflectors were manufactured with the variable for manufacturing process. As variables for manufacturing process, the curing process of the composite structure, the application of adhesive film between the carbon fiber composite sheet and the honeycomb core, and the venting path inside the sandwich composite were selected. After manufacture main reflector, weight measurement, non-destructive testing(NDT), surface error measurement, and modal test were performed on the four types of main reflectors produced. By selecting a manufacturing process that does not apply adhesive film and includes venting path, for a composite main reflector with light weight and structural performance, we developed and verified a main reflector that can be applied to the SAR(Synthetic Aperture Rader) satellite.

A Study on the Performance Evaluation of Water(wash out) Resistance of 5-Type Repair Materials in Water Leakage of Underground Concrete Structures (지하 콘크리트 구조물 누수부위에 시공되는 5계열 보수재료의 유실 저항 성능 평가 연구)

  • Kim, Soo-Yeon;Yoo, Jae-Yong;Oh, Sang-Keun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.5
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    • pp.61-68
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    • 2020
  • In this study, the international standard ISO TS 16774 Part 3 Test Method for Water (wash out) Resistance and KS F 4935 「Sealant Injection type for water leakage maintenance of adhesive flexible rubber asphalt series」, which are standardized as a quality control method of injection type repair materials used for water leakage cracks in underground concrete structures, are currently used in Korea. As a result, considering the performance criteria of "mass change rate -0.1%" stipulated in KS F 4935, the remaining 13 types repair materials, excluding RG-2 of synthetic rubber and UG-1 of urethane, need to be reviewed for stabilization of the loss resistance due to the flow of ground water. The results of this study are determined to be available as a basic indicator for the selection of repair materials used for cracks in concrete structures. In addition, it is expected that the results of this study can be utilized as reference data that can be reflected in the improvement of the quality of repair materials that will be researched and developed later.

Effect of Mixing Ratio of Amphoteric and Anionic Latices on Print Quality of Coated Papers (라텍스의 혼합비율이 도공지 품질에 미치는 영향)

  • 강태근;박규재;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.72-79
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    • 1999
  • The binder plays important roles in determining the quality of pigment coating. In addition to its primary role of binding the pigment to the base paper, the binder performs several other important functions. The binder, also referred to as the adhesive, is the dominant in the aqueous phase of the formulation. Thus it plays a major role in determining viscosity, rheology, water release, and setting time for the coating. Latices based on styrene-butadiene dominate the market for synthetic paper coating binders. Consumption is high and is expected to increase further due to the present tendeyncy toward high-solids coating. The purpose of this study is understanding the impact of various parameters of latex(i.e. Tg, Particle size) affecting prontabilities and optical properties of the coated papers, as well as providing basic information on the use of amphoteric latex for improving print qualities of coated papers. Recently, amphoteric latices, Which are cationic at low pH's but turn anionic at high pH's have attracted interests of paper scientists and engineers. Therefore we investigated the effect of the Tg(glass transition temperature) and particle size of amphoteric latex on the coating qualities. We also studied the effect of mixing ratios (Amphoteric / Anionic)of latex on the coating qualities. Our results showed that Tg and particle size of amphoteric latex have to be controlled for optimizing coated paper qualities. The formulation consisting of 10 parts of amphoteric latex and 5 parts of anionic latex gave best results in ink receptivity, smoothness, air permeability, opacity and sheet gloss. If the results hold for the industrial paper coatings, the amount of expensive amphoteric latex can be reduced while achieving best available printing quality.

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Phonosurgery after Laser Cordectomy (레이저 성문절제술 후의 음성수술)

  • So, Yoon-Kyung;Son, Young-Ik
    • Journal of the Korean Society of Laryngology, Phoniatrics and Logopedics
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    • v.19 no.1
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    • pp.11-15
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    • 2008
  • Endoscopic laser cordectomy is known as an oncologically sound procedure for T1 and selected T2 glottic carcinoma ; it has comparable local control rate and better long-term laryngeal preservation rate when compared with those of radiotherapy. Even if results of the reported voice outcome studies after surgery or radiotherapy are diverse and controversial, resection deeper than the body layer of the vocal fold (type III, IV, V cordectomy) usually leads to aerodynamic insufficiency during phonation and results in poor voice quality. A keyhole defect or development of synechiae at the anterior commissure after type VI cordecomy may also result in unsatisfactory vocal outcome. However, many advances in phonosurgical techniques are reported to be successfully applied in the reconstruction of glottal defect that is subsequent to endoscopic laser cordectomy. In case of glottal insufficiency, voice restoration can be achieved by means of augmentation of the paraglottic space or medialization of the excavated vocal fold. Injection laryngoplasty with synthetic materials or autologous fat is gaining its popularity for restoring minor glottal volume defect because of its convenience. Laryngeal framework surgery, especially type I thyroplasty with premade implant systems or Gore-Tex, is most frequently used to correct larger glottic volume defect. In case of anterior commissural keyhole defect, additional procedure including laryngofissure may be required. For anterior commissural synechiae, laryngeal keel may be inserted for several weeks or mitomycin-C may be repeatedly applied after the division of adhesive scar to prevent restenosis. In this paper, current concepts and the authors' experiences of phonosurgical reconstruction of vocal function after endoscopic cordectomy will be introduced.

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Pressure Sensitive Adhesion Performances of SIS/SBS based UV-curable Pressure Sensitive Adhesives using Thiol-ene Reaction (Thiol-ene 반응을 이용한 UV경화형 SIS/SBS계 점착제의 점착물성)

  • Lim, Dong-Hyuk;Do, Hyun-Sung;Kim, Hyun-Joong;Yoon, Goan-Hee;Bang, Jung-Suk
    • Journal of Adhesion and Interface
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    • v.6 no.3
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    • pp.19-25
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    • 2005
  • Synthetic rubber based pressure-sensitive adhesives (PSAs) usually containing SIS or SBS block copolymer, tackifier, plasticizer, and other additives are now widely used on various applications. As these PSAs are physically crosslinked and can be applied without the use of solvent, they are thermally processable and environmentally friendly. However these PSAs cannot be used in high temperature applications and in applications where solvent and chemical resistance properties are required. We developed the PSA adding UV curable system, such as thiol-ene system, to increase adhesion properties at elevated temperature. The adhesion properties such as probe tack, peel strength, shear adhesion failure temperature (SAFT) were evaluated. The probe tack test was conducted with varying probe materials and coating thickness of PSAs. Using the contact angle, the surface property of the cured PSAs was also observed.

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The effect of denture adhesives on the retention of complete denture (의치 접착제가 총의치의 유지력에 미치는 영향에 관한 연구)

  • Yoon, Yu-Mi;Choi, Yu-Sung;Lee, Joon-Seok
    • The Journal of Korean Academy of Prosthodontics
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    • v.48 no.2
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    • pp.87-93
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    • 2010
  • Purpose: The purpose of this study was to compare the retention of the two denture adhesives with a silicone edentulous model and a resin denture base in vitro study. Material and methods: The experimental groups were used two denture adhesives and classified into 5 subgroups each. Subgroups were divided by the number of times the saliva sprayed. The control group was used synthetic saliva only. Dislodging tensile strengths were applied to the resin denture base using Instron in 3 directions ; vertical, lateral, and anterior-posterior. Results: The retention of two denture adhesives was increased significantly than saliva alone (P <.05). In each denture adhesives, the retention of saliva sprayed first was decreased than denture adhesive alone, but it didn't have significant differences. Whenever saliva sprayed repeated, the retention was decreased significantly than saliva sprayed first (P <.05). In each denture adhesives, vertical retentive force was highest than lateral and anterior-posterior retentive forces, and anterior-posterior retentive force was higher than lateral retentive force. This results were significantly different (P < .05). Significant differences of the retentive ability among two denture adhesives were not observed. Conclusion: From the results, use of the denture adhesives resulted in improved retentive ability of denture. Especially retentive force was highest in vertical direction.