• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.05a
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• pp.366-369
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• 1999

Synthetic diamond films have been deposited on the silicon(100) surface and molybdenum substrates using an microwave plasma enhanced vapor deposition (MWPECVD) method. The effect of deposition time, surface morphology, X-ray diffraction pattrm, infrared transmittance and Raman Scattering have been studied, The diamond film deposited on Mo substrate for (100) hours at 40 torr H$_2$-CH$_4$O$_2$ gas system have been shown 1${\mu}{\textrm}{m}$/h of growth rate and good crystallization

• Bulletin of the Korean Chemical Society
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• v.30 no.11
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• pp.2669-2674
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• 2009

Controlled reduction of silver alkylcarbamate complexes with hydrogen gas was investigated as a facile synthetic method for high concentrations of silver nanocolloids in organic solvent. Polyvinylpyrrolidone (PVP) was used to stabilize the silver colloids obtained from the chemical reduction. To determine optimum conditions for preparation of the stable and controlled silver colloids with the narrowest particle size and distribution, a large number of experiments were carried out involving variations in the concentrations of the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, and 2-propanol. The initial colloid had a mean particle diameter between 5$\sim$50 nm, as measured by transmission electron microscopy, and exhibited a sharp absorption band in the UV region with a maximum size near 420 nm. After treatment with a reducing agent, the colloids were characterized by ultraviolet-visible spectroscopy, X-ray diffraction, and high-resolution transmission electron microscopy.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.53-56
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• 2015

A combined experimental and numerical study has been conducted to investigate the downstream interaction between simulated SNG-air premixed flames in fuel composition of 91% $CH_4$ + 6% $C_3H_8$ + 3% $H_2$. In this study, the effects of fuel molar concentration(lean-rich) and strain rate($a_g$) were major parameters. A main focus is to investigate flames behavior and chemical interaction at flames downstream. The numerical results were calculated by OPPDIF application. The reaction mechanism adopted was USC-II model including C3 reaction.

• Nuclear Engineering and Technology
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• v.32 no.5
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• pp.504-513
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• 2000

The adsorption characteristics of methyl iodide generated from the simulated off-gas stream on various adsorbents such as silver ion-exchanged zeolite (AgX), zeocarbon and activated carbon were investigated. An extensive evaluation was made on the optimal silver ion-exchanged level for the effective removal of methyl iodide at temperature up to 38$0^{\circ}C$. The degree of adsorption efficiency of methyl iodide on silver ion-exchanged zeolite is strongly dependent of silver ion-amount and process temperature. The influence of temperature, methyl iodide concentration and silver ion-exchanged level on the adsorption efficiency is closely related to the pore characteristics of adsorbents. It would be facts that the effective silver ion-exchanged level was about 10 wt%, based on the degree of silver utilization for the removal of methyl iodide.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.5
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• pp.480-483
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• 2004

Butylene carbonate(4-ethyl-l,3-dioxolan-2-one), one of the cyclic carbonate was synthesized by the thermal degradation of poly(butylene carbonate). The poly(butylene carbonate) was made from 1,2-Epoxybutane and carbon dioxide which is one of the main green house gas. The prepared cyclic carbonate was identified by GC-Mass. This synthetic method is an alternative way to prepare cyclic carbonates.

• Journal of Hydrogen and New Energy
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• v.30 no.1
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• pp.67-75
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• 2019

An experimental study was conducted to measure laminar burning velocity and Markstein length of SNG fuel with 3% of hydrogen contents from spherical propagating flames at normal and elevated initial pressure. These results were compared with numerical calculations by Premix code with GRI-mech 3.0, USC II and UC San Diego to provide suitable mechanism for SNG fuel. As a result of this work, it was found that the burning velocities and Markstein lengths of SNG fuel decrease with increase of initial pressure regardless of equivalence ratio. In addition, numerical calculations with GRI-mech 3.0 were coincided with experimental results.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.02a
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• pp.238-244
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• 2004

The relationship between the leaching and gap inventory of spent fuel has been studied. When a specimen of J44H08 spent PWR fuel with 38 GWD/MTU has been leached in the synthetic granitic groundwater in Ar atmosphere, the released fraction of cesium was increased rapidly up to 0.7% at around 500 days and stayed below 0.8% until 3 years. This 0.7% of cesium might be released from the gap in this fuel. The measurement of gap inventory with C15I08 spent PWR fuel, having 35 GWD/MTU and 0.22% of fission gas release, was also determined near 0.6% for the cesium, which is a similar fraction of cesium released from the leaching experiment with J44H08 fuel. Its gap inventories of strontium and iodine were about 0.03 and less than 0.2% respectively. Respective fractions of cesium and strontium in grain boundary of C15I08 were 0.78, 0.09%.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.9
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• pp.733-742
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• 2016

In recent years, gas engines fueled with LNG or synthetic gas have been attracting considerable attention for marine use owing to their potential to facilitate better fuel economy and to reduce emissions. It has been confirmed that gas engines using the Otto cycle, which involves premixed combustion, can satisfy Tier III regulations without the EGR or SCR system. The objective of this study is to acquire simulation technologies for predicting gas engine performances in industrial fields. Using the commercial software BOOST, the simulation is conducted on a gasoline engine rather than a marine engine due to the gasoline engine's easier accessibility. This study consists of two stages. In the first stage published previously, the optimal modeling techniques for representing the behavior of the gas in the intake and exhaust systems were determined. In the current study, we formulated a method to evaluate the combustion and heat transfer processes in the cylinder and to ultimately determine the major performance parameters, given that the analytical model derived from the previous stage has been applied. Through this study, we were able to determine a combustion and heat transfer model and a valve discharge coefficient that are less reliant on empirical data: we were also able to formulate a methodology through which relevant constants are decided. We confirmed that the values of transient cylinder pressure variation, indicated mean effective pressure, and air supply can be successfully predicted using our modeling techniques.

• The Journal of Natural Sciences
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• v.5 no.1
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• pp.67-75
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• 1992

In the our country, especially in Yeongil and Wolsung area, abundant authigenic zeolites are found from the tuffaceous sediments and volcanic rocks of Miocene age showing wide variation in their mineralogy and abundance from horizon to horizon. The principal zeolite species identified are clinopti-lolite. mordenite. heulandite. ferrierite, and erionite. etc. Zeolite minerals are widely used in many countries in the following applications; (a) in air separation adsorption processes; (b)as desiccants; (c)in inorganic building materials; (d)in papermaking; (e)in fertilizers; (f)as soilconditioners-this application is based upon the ability of the zeolite to ion exchange with soil nutrients; (g)in the treatment of radioactive wastes; and (h)as adsorbents for toxic gases, etc. In the present paper, using natural zeolite mordenite treated with IN hydrochloric acid or IN sodium chloride solution as column packings, separation characteristics of argon, nitrogen, carbon monoxide, and methane gases have been studied by gas chromatography. By the use of mordenite treated with hydrochloric acid solution, the tailing peak of methane showed from untreated mordenite was satisfactorily reduced, although it was difficult to separate it from carbon monoxide with a column activated at $300^{\circ}C$. Using a column activated at $350^{\circ}C$, methane could be separated from carbon monoxide easily but only carbon monoxide eluted as a bad defined peak. Mordenite treated with sodium chloride solution was generally similar to chromatograms obtained by using the untreated mordenite. Both the above chemical treatments of mordenite had little effect on the separations of argon and nitrogen. The separations and the HETP values obtained from natural zeolite mordenite treated with continuously hydrochloric acid and sodium chloride solutions were almost identical with those obtained with synthetic molecular sieve 5A zeolite. On the other hand, the efficiency of column was good in the range 20~3Oml/min of the carrier helium gas rate.

• Fire Science and Engineering
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• v.30 no.2
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• pp.7-18
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• 2016

This study evaluated the toxicity of the burning gas from the synthetic wood products used in housings or warehouses. The combustion products of five materials, viz. impregnated laminated board, MDF, Douglas fir plywood, core plywood, and Lauan retardant, were analyzed using SEM, FTIR and a Cone Calorimeter. For the Lauan retardant, 256,965 ppm of carbon dioxide ($CO_2$) and 1,475 ppm of sulfur dioxide ($SO_2$) were measured, which are 2.5 times and 3.6 times as high as their lethal concentrations of 100,000 ppm and 400 ppm, respectively. For the impregnated laminated board, 1,569 ppm of nitrogen dioxide ($NO_2$) was measured, which is 6 times as high as its lethal concentration of 250 ppm. For MDF, 795 ppm of ammonia ($NH_3$) was measured, which is higher than its lethal concentration of 750 ppm. As a result, most internal-finishes generated toxic combustion products at levels higher than their lethal concentrations, which underlines the importance of the selection and manufacturing of internal-finish materials.