• Macromolecular Research
• /
• v.17 no.1
• /
• pp.37-43
• /
• 2009

To fabricate dental nanocomposites containing finely dispersed silica nanoparticles, nearly monodispersed silica nanoparticles smaller than 25 nm were synthesized without forming any aggregates via a modified sol-gel process. Since silica nanoparticles synthesized by the Stober method formed aggregates when the particle size is smaller than 25 nm, the synthetic method was modified by changing the reaction temperature and adding poly(1-vinyl-2-pyrrolidinone) (PVP) to the reaction mixture. The size of the formed silica nanoparticles was reduced by increasing the reaction temperature or adding PVP. Furthermore, the formation of aggregates with primary silica nanoparticles smaller than 25 nm was prevented by increasing the amount of PVP added to the reaction mixture. To enhance the dispersion of the silica particles in an organic matrix, the synthesized silica nanoparticles were treated with 3-methacryloxypropyltrimethoxysilane ($\gamma$-MPS). A dental nanocomposite containing finely dispersed silica nanoparticles could be produced by using the surface-treated silica nanoparticles.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.1
• /
• pp.76-82
• /
• 2012

A novel and efficient tetrahydrofuranyl ring opening method was developed using the highly reactive TFAT reagent in the presence of an acid scavenger, 2,6-di-tert-butyl-4-methylpyridine. Various acid sensitive groups are compatible with the reaction condition, making it generally applicable to many tetrahydrofuranyl steroids. Moreover, it is a synthetic equivalent of 'Marker degradation' affording an efficient synthesis of C17-OH rockogenin acetate.

• Proceedings of the Acoustical Society of Korea Conference
• /
• 1994.06a
• /
• pp.949-956
• /
• 1994

In this paper, we introduce a new speech synthesis method for Japanese and Korean arbitrary sentences using the natural speech data-base. Also, application of this method to a CAI system is discussed. In our synthesis method, a basic sentence and basic accent-phrases are selected from the data-base against a target sentence. Factors for those selections are phrase dependency structure (separation degree), number of morae, type of accent and phonemic labels. The target pitch pattern and phonemic parameter series are generated using those selected basic units. As the pitch pattern is generated using patterns which are directly extracted form real speech, it is expected to be more natural than any other pattern which is estimated by any model. Until now, we have examined this method on Japanese sentence speech and affirmed that the synthetic sound preserves human-like features fairly well. Now we extend this method to Korean sentence speech synthesis. Further more, we are trying to apply this synthesis unit to a CAI system.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.04a
• /
• pp.457-460
• /
• 2008

It was predicted that the most recent technological developments in concrete technology rely on enhanced admixture efficiency rather than on improvement in cement manufacturing. Four major commercially available of organic chemical admixtures are modified lignosulfonates (LS), sulfonated naphthalene-formaldehyde resins (SNF), sulfonated melamine-formaldehyde resins(SMF) and polycarboxylate(PC). In this study, various sulfonated melamine-formaldehyde (SMF) superplasticizers were synthesized via four synthetic steps and reaction conditions such as the mole ratio of melamine to formaldehyde was changed. After application of SMF superplasticizer to cement concrete, the physical properties including workability, slump loss, compressive strength were compared with SNF

• Journal of Power Electronics
• /
• v.16 no.3
• /
• pp.960-969
• /
• 2016

High-power three-level voltage-source converters are widely utilized in high-performance AC drive systems. In several ultra-power instances, the harmonics on the grid side should be reduced through multiple rectifications. A combined harmonic elimination method that includes a dual primary-side series-connected winding transformer and selective harmonic elimination pulse-width modulation is proposed to eliminate low-order current harmonics on the primary and secondary sides of transformers. Through an analysis of the harmonic influence caused by dead time and DC magnetic bias, a synthetic compensation control strategy is presented to minimize the grid-side harmonics in the dual primary side series-connected winding transformer application. Both simulation and experimental results demonstrate that the proposed control strategy can significantly reduce the converter input current harmonics and eliminates the DC magnetic bias in the transformer.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
• /
• 2003.10a
• /
• pp.213-217
• /
• 2003

In this paper, we studied electric Insulation characteristics of synthetic Laminated Polypropylene Paper (LPP) in liquid nitrogen (L$N_2$) for the application to high temperature super-conducting (HTS) cable. And, we selected the insulation paper/L$N_2$composite insulation type for the electric insulation design of a HTS cable. Furthermore, we compared the breakdown characteristics of the butt gap and bended mini-model cable that comes into being in this kind of cryogenic insulation type. It is necessary to understand the winding parameter of insulation paper/L$N_2$composite insulation.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2019.05a
• /
• pp.6-7
• /
• 2019

In order to solve problems such as scattered dust, dust and chemicals harmful to the human body, workability in a confined space, quality performance, and the like generated during the field construction of the conventional waterproof sheet construction method, a waterproof sheet is used as a PC formwork, Which is produced by pouring concrete after PC installation, and evaluating the applicability of the development method in comparison with the construction method of polypropylene waterproof sheet construction method and the construction period, safety, quality, construction cost.

• Korean Journal of Microbiology
• /
• v.28 no.3
• /
• pp.243-248
• /
• 1990

Genetically engineered strains of Pseudomonas, which could degrade the various aromatic hydrocarbons, were acclimated to the synthetic wastewater with increasing substrate concentration. All of the tested strains except KUD101 showed 70-90% of the COD removal efficiencies. Acclimated strains, Pseudomonas putida KUD106, KUD107 and KUD108 were inoculated into the ordinary activated sludge and these sludges were used in the dyeing or alkylbenzene wastewater treatment system. In the case of the wastewater containing alkylbenzene compounds, COD removal efficiency was 12-14% higher than that of the ordinary activated sludge, while it was not effective for dyeing wastewater. On the other hand, the floc formation of the activated sludge inoculated with genetically engineered strains was more rapid in both wastewaters tested than that of the activated sludge by the ordinary natural strains.

• KSBB Journal
• /
• v.25 no.5
• /
• pp.409-420
• /
• 2010

Biopolymer-based materials recently have garnered considerable interest as they can decrease dependency on fossil fuel. Biopolymers are naturally obtainable macromolecules including polysaccharides, polyphenols, polyesters, polyamides, and proteins, that play an important role in biomedical applications such as tissue engineering, regenerative medicine, drug-delivery systems, and biosensors, because of their inherent biocompatibility and biodegradability. However, the insolubility of unmodified biopolymers in most organic solvents has limited the applications of biopolymer-based materials and composites. Ionic liquids (ILs) are good solvents for polar organic, nonpolar organic, inorganic and polymeric compounds. Biopolymers such as cellulose, chitin/chitiosan, silk, and DNA can be fabricated from ILs into films, membranes, fibers, spheres, and molded shapes. Various biopolymer/biopolymer and biopolymer/synthetic polymer composites also can be prepared by co-dissolution of polymers into IL mixtures. Heparin/biopolymer composites are especially of interest in preparing materials with enhanced blood compatibility.

• Journal of Environmental Health Sciences
• /
• v.23 no.4
• /
• pp.50-56
• /
• 1997

Applied for Drug Delivery System, polymer drug was prepared with chitosan and phthalylsulfathiazole. In spite of various application of chitin derivatives, commercial use of chitin has been limited due to highly resistance to chemicals and the absense of proper solvents. In this study, Chitosan were prepared from chitin which were deacetylated under various condition. The synthetic procedures of polymer drug were performed by acid chloride methods. The antibiotic activities of polymer drug exhibited growth-inhibitory activity against Staphylococcus aureus, Staphylococcus epidermidis, E. coli, Salmonella typhimurium, Klebsiella pneumoniae at the concentration of 471-514 $\mu$g/ml in general. Comparatively, Polymer drug exhibited broad antibacterial activity on MICs 897-1280 $\mu$g/ml against Gram-positive and Gram-negative bacteria including Staphylococcus aureus, Staphylococcus epidermidis and E. coli.