• 제목/요약/키워드: Synthesis parameters

검색결과 694건 처리시간 0.028초

V608 CASSIOPEIAE: A W UMA-TYPE ECLIPSING BINARY WITH TWO POSSIBLE CIRCUMBINARY COMPANIONS

  • Park, Jang-Ho;Lee, Jae Woo
    • 천문학회지
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    • 제55권1호
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    • pp.1-9
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    • 2022
  • We present the photometric properties of V608 Cas from detailed studies of light curves and eclipse timings. The light curve synthesis indicates that the eclipsing pair is an overcontact binary with parameters of ∆T = 155 K, q = 0.328, and f = 26%. We detected the third light ℓ3, which corresponds to about 8% and 5% of the total systemic light in V and R bands, respectively. Including our 6 timing measurements, a total of 38 times of minimum light were used for a period study. It was found that the orbital period of V608 Cas has varied in some combination of an upward parabola and two periodic variations. The continuous period increase with a rate of +3.99 × 10-7 d yr-1 can be interpreted as a mass transfer from the secondary component to the primary star at a rate of 1.51 × 10-7 M yr-1. The periods and semi-amplitudes of the two periodic variations are about P3 = 16.0 yr and P4 = 26.3 yr, and K3 = 0.0341 d and K4 = 0.0305 d, respectively. The most likely explanation of both cycles is a pair of light-traveling time effects operated by the possible presence of third and fourth components with estimated masses of M3 = 2.20 M and M4 = 1.27 M in eccentric orbits of e3 = 0.66 and e4 = 0.52. Because the contribution of ℓ3 is very low compared to the estimated masses of two circumbinary objects, they can be inferred as very faint compact objects.

Microbiome-metabolomics analysis of the effects of decreasing dietary crude protein content on goat rumen mictobiota and metabolites

  • Zhu, Wen;Liu, Tianwei;Deng, Jian;Wei, Cong Cong;Zhang, Zi Jun;Wang, Di Ming;Chen, Xing Yong
    • Animal Bioscience
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    • 제35권10호
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    • pp.1535-1544
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    • 2022
  • Objective: The objective of this study was to investigate the effects of decreasing dietary crude protein content on rumen fermentation, mictobiota, and metabolites in goats. Methods: In an 84-day feeding trial, a total of twelve male Anhui white goat kids with initial body weight 15.9±1.13 kg were selected and randomly classified into two groups, feeding a normal crude protein diet (14.8% CP, NCP) or a low crude protein diet (12.0% CP, LCP). At the end of the experimental trial (on day 84), six animals were randomly selected from each group and were slaughtered to collect rumen fluid samples for the analysis of rumen fermentation parameters, microbiome, and metabolome. Results: The concentrations of ammonia-nitrogen, total volatile fatty acid, acetate, and propionate were decreased (p<0.05) in the LCP group in comparison with those in the NCP group. The abundances of genera Prevotella, Campylobacter, Synergistetes, and TG5, which were associated with nitrogen metabolism, were lower (p<0.05) in the LCP group compared with those in the NCP group. The levels of 78 metabolites (74 decreased, 4 increased) in the rumen fluid were altered (p<0.05) by the treatment. Most of the ruminal metabolites that showed decreased levels in the LCP group were substrates for microbial protein synthesis. Metabolic pathway analysis showed that vitamin B6 metabolism was significantly different (p<0.05) in rumen fluid between the two treatments. Conclusion: Decreased dietary protein level inhibited rumen fermentation through microbiome and metabolome shifts in goat kids. These results enhance our understanding of ruminal bacteria and metabolites of goat fed a low protein diet.

Morphological study of porous aromatic schiff bases as a highly effective carbon dioxide storages

  • Rehab Hammoda;Naser Shaalan;Mohammed H. Al-Mashhadani;Dina S. Ahmed;Rahimi M. Yusop;Ali H. Jawad;Emad Yousif
    • 분석과학
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    • 제36권5호
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    • pp.236-249
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    • 2023
  • Carbon dioxide (CO2) capture and storage is a critical issue for mitigating climate change. Porous aromatic Schiff base complexes have emerged as a promising class of materials for CO2 capture due to their high surface area, porosity, and stability. In this study, we investigate the potential of Schiff base complexes as an effective media for CO2 storage. We review the synthesis and characterization of porous aromatic Schiff bases materials complexes and examine their CO2 sorption properties. We find that Schiff base complexes exhibit high CO2 adsorption capacity and selectivity, making them a promising candidate for use in carbon capture applications. Moreover, we investigate the effect of various parameters such as temperature, and pressure on the CO2 adsorption properties of Schiff base complexes. The Schiff bases possessed tiny Brunauer-Emmett-Teller surface areas (4.7-19.4 m2/g), typical pore diameters of 12.8-29.43 nm, and pore volumes ranging from 0.02-0.073 cm3/g. Overall, our results suggest that synthesized complexes have great potential as an effective media for CO2 storage, which could significantly reduce greenhouse gas emissions and contribute to mitigating climate change. The study provides valuable insights into the design of novel materials for CO2 capture and storage, which is a critical area of research for achieving a sustainable future.

Psychological and Pedagogical Principles of the Organization of Distance Learning of Primary School-Aged Children with Cognitive Development Disorder

  • Yuliia Sosnich;Kristina Torop;Tetiana Dehtiarenko;Oleksandr Kolyshkin;Yurii Kosenko;Iryna Omelchenko
    • International Journal of Computer Science & Network Security
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    • 제24권8호
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    • pp.184-190
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    • 2024
  • The research involved children and parents of primary school-aged children with cognitive development disorder, as well as scientific and pedagogical workers who organized the psychological and pedagogical principles for organizing distance learning. The purpose of the research lies in establishing how effectively children, parents and their teachers cope with online distance learning during the pandemic, as well as investigating the extent to which such educational technology affects the emotional and behavioural state of the child. The research methodology is based on complexity. In the course of the research, the method of pedagogical experiment was used; observation and questionnaire methods were also introduced; the descriptive method, analysis and synthesis were used to review the theoretical material. The hypothesis lies in the fact that distance online education increases academic difficulties, changes the behavioural and emotional picture of a child with cognitive development disorder; consequently, the behaviour and emotional background will be limited by certain parameters, and this requires the active involvement of parents and teachers in the distance work process. The results of the research have revealed that distance education causes a number of restrictions for children with cognitive development disorder, namely: concentration of attention has decreased, anxiety has increased, and sleep has worsened. Behavioural changes predicted increased restlessness and aggression. Parents and teachers have had methodological, academic and everyday difficulties; all participants in the educational process have been more limited in the conditions of online distance learning. difficulties and improving the behaviour and emotional states of all participants in the educational process.

Synthesis and Characterization of Magnetic Cellulose Powder from Sawdust Waste

  • Heru SURYANTO;Uun YANUHAR;Husni Wahyu WIJAYA;Joseph Selvi BINOJ;Azlin Fazlina OSMAN;Poppy PUSPITASARI;Jibril MAULANA;Nico Rahman CAESAR;Fajar NUSANTARA;Komarudin KOMARUDIN
    • Journal of the Korean Wood Science and Technology
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    • 제52권5호
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    • pp.504-523
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    • 2024
  • Timber industry waste is being examined for cellulose manufacturing to give important benefits. The study's goal is to investigate the properties of cellulose powder derived from sawdust waste after it has been reinforced with ferrous-ferric oxide nanoparticles (Fe3O4-NPs). Sawdust cellulose powder was produced from Sengon (Albizia chinensis) wood waste in this study. The crushed sawdust waste is handled with alkalization and bleaching. Cellulose powder is then reinforced with Fe3O4-NPs at 10 wt.%, 20 wt.%, and 30 wt.%. The magnetic cellulose powder was analysed by X-ray diffraction, Fourier Transform Infrared, scanning electron microscopy morphology, magnetic vibrating sample magnetometer, Brunauer-Emmett teller, and adsorption tests for Methylene Blue and Congo Red dyes. Structure study identifies sawdust as cellulose 1β, with peaks at 14°, 16°, and 22° diffraction angles. The addition of Fe3O4-NPs reduces the crystalline index of sawdust cellulose powder from 68.50% to 63.38%, and functional group bond analysis revealed many peak shifts indicating a change in the chemical bonds of magnetic cellulose powder. Incorporating Fe3O4-NPs into sawdust cellulose powder confers magnetic and superparamagnetic properties to the sawdust cellulose. Similarly, the surface texture of magnetic cellulose seems rougher as the surface area increases. These parameters imply a 31.8% increase in Congo Red adsorption, using adsorption kinetics based on the pseudo-first-order model.

A hybrid algorithm for the synthesis of computer-generated holograms

  • Nguyen The Anh;An Jun Won;Choe Jae Gwang;Kim Nam
    • 한국광학회:학술대회논문집
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    • 한국광학회 2003년도 하계학술발표회
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    • pp.60-61
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    • 2003
  • A new approach to reduce the computation time of genetic algorithm (GA) for making binary phase holograms is described. Synthesized holograms having diffraction efficiency of 75.8% and uniformity of 5.8% are proven in computer simulation and experimentally demonstrated. Recently, computer-generated holograms (CGHs) having high diffraction efficiency and flexibility of design have been widely developed in many applications such as optical information processing, optical computing, optical interconnection, etc. Among proposed optimization methods, GA has become popular due to its capability of reaching nearly global. However, there exits a drawback to consider when we use the genetic algorithm. It is the large amount of computation time to construct desired holograms. One of the major reasons that the GA' s operation may be time intensive results from the expense of computing the cost function that must Fourier transform the parameters encoded on the hologram into the fitness value. In trying to remedy this drawback, Artificial Neural Network (ANN) has been put forward, allowing CGHs to be created easily and quickly (1), but the quality of reconstructed images is not high enough to use in applications of high preciseness. For that, we are in attempt to find a new approach of combiningthe good properties and performance of both the GA and ANN to make CGHs of high diffraction efficiency in a short time. The optimization of CGH using the genetic algorithm is merely a process of iteration, including selection, crossover, and mutation operators [2]. It is worth noting that the evaluation of the cost function with the aim of selecting better holograms plays an important role in the implementation of the GA. However, this evaluation process wastes much time for Fourier transforming the encoded parameters on the hologram into the value to be solved. Depending on the speed of computer, this process can even last up to ten minutes. It will be more effective if instead of merely generating random holograms in the initial process, a set of approximately desired holograms is employed. By doing so, the initial population will contain less trial holograms equivalent to the reduction of the computation time of GA's. Accordingly, a hybrid algorithm that utilizes a trained neural network to initiate the GA's procedure is proposed. Consequently, the initial population contains less random holograms and is compensated by approximately desired holograms. Figure 1 is the flowchart of the hybrid algorithm in comparison with the classical GA. The procedure of synthesizing a hologram on computer is divided into two steps. First the simulation of holograms based on ANN method [1] to acquire approximately desired holograms is carried. With a teaching data set of 9 characters obtained from the classical GA, the number of layer is 3, the number of hidden node is 100, learning rate is 0.3, and momentum is 0.5, the artificial neural network trained enables us to attain the approximately desired holograms, which are fairly good agreement with what we suggested in the theory. The second step, effect of several parameters on the operation of the hybrid algorithm is investigated. In principle, the operation of the hybrid algorithm and GA are the same except the modification of the initial step. Hence, the verified results in Ref [2] of the parameters such as the probability of crossover and mutation, the tournament size, and the crossover block size are remained unchanged, beside of the reduced population size. The reconstructed image of 76.4% diffraction efficiency and 5.4% uniformity is achieved when the population size is 30, the iteration number is 2000, the probability of crossover is 0.75, and the probability of mutation is 0.001. A comparison between the hybrid algorithm and GA in term of diffraction efficiency and computation time is also evaluated as shown in Fig. 2. With a 66.7% reduction in computation time and a 2% increase in diffraction efficiency compared to the GA method, the hybrid algorithm demonstrates its efficient performance. In the optical experiment, the phase holograms were displayed on a programmable phase modulator (model XGA). Figures 3 are pictures of diffracted patterns of the letter "0" from the holograms generated using the hybrid algorithm. Diffraction efficiency of 75.8% and uniformity of 5.8% are measured. We see that the simulation and experiment results are fairly good agreement with each other. In this paper, Genetic Algorithm and Neural Network have been successfully combined in designing CGHs. This method gives a significant reduction in computation time compared to the GA method while still allowing holograms of high diffraction efficiency and uniformity to be achieved. This work was supported by No.mOl-2001-000-00324-0 (2002)) from the Korea Science & Engineering Foundation.

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고분해능 X-선 분말 회절을 이용한 Cs-, Cd-, Pb-, Sr-으로 치환된 합성 모데나이트의 격자상수 비교 연구 (Comparative Crystal Chemistry of Exchanged by Cs-, Cd-, Pb-, and Sr-synthetic Mordenite Using High Resolution X-ray Powder Diffraction)

  • 이수진;이현승;성동훈;김표상;김현수;이용문
    • 광물과 암석
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    • 제35권3호
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    • pp.345-353
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    • 2022
  • 본 연구는 합성 모데나이트(Na6.6Al6.6Si41.4O96·20.4H2O, Na-MOR)를 이용한 다양한 중금속의 포획 연구를 하기 위한 기초 단계로, 고분해능 X-선 분말 회절을 이용하여 치환체의 격자상수 및 부피 변화를 이해하기 위한 목적으로 실험을 진행하였다. 열중량 분석법(Thermogravimetric analysis, TGA)으로 측정한 결과, 1가 양이온 치환체(Cs-MOR, Na-MOR)는 단위포 당 19.4, 20.4개의 물분자가 존재하였으며, 2가 양이온 치환체(Pb-MOR, Sr-MOR, Cd-MOR)는 단위포 당 21, 23.1, 23.2개가 존재하는 것을 확인하였다. 측정한 모든 물질은 사방정계에 속하는 Cmcm의 공간군을 가지는 것으로 확인할 수 있었다. 치환 전 물질인 Na-MOR과 비교했을 때, 치환체의 (110)면과 (200)면의 회절강도가 명확하게 변화하였으나, 전체적인 피크의 위치는 거의 유사하게 나타나는 것을 확인할 수 있었다. 또한 Na-MOR에서는 확인이 되지 않았던 (220)면의 피크가 Pb-, Cd-, Sr-MOR에서 뚜렷하게 관찰되었다. 이를 통해서 양이온 치환에 따른 원자들의 분포 변화가 주로 ab-평면상에서 나타나지만, 격자상수의 변화는 미세할 것으로 짐작할 수 있었다. Whole profile fitting 방법을 사용하여 치환된 모데나이트의 미세한 격자상수의 변화를 관찰하였다. 치환체의 격자상수 및 격자부피의 변화는 치환된 양이온의 반경 및 전하수에 따라 서로 다른 경향성을 보였다. 1가 양이온의 경우, 이온반경이 증가할수록 a-축의 길이는 증가하지만, 반면에 b- 및 c-축의 길이는 감소하였다. 2가 양이온의 경우, 이온반경이 증가할수록 대체적으로 a-축의 길이가 감소하고, b- 및 c-축의 길이는 증가하였다. 격자부피는 1가 또는 2가 양이온 치환체들이 각각 독립된 경향성을 가지며, 이온반경에 따라 증가하는 것을 확인할 수 있었다.

시상하부-뇌하수체-부신계 조절에 대한 Monoamine 신경전달물질의 역할에 관한 연구(III)-뇌 5-hydroxytyptamine(Serotonin)이 Stress 시 Corticosteroid 변동에 미치는 영향 (Roles of Monoamine Neurotransmitters in Regulation of Hypothalamic PITUITITARY-ADRENAL AXIS(HPA) (III) - Role of 5-hydroxytryptamine in Controlling the Stress-Induced Elevation of Corticosterone in Rat -)

  • 서유헌;임정규;박찬웅
    • 대한약리학회지
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    • 제19권2호
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    • pp.45-55
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    • 1983
  • 뇌내 여러 신경전달물질계가 시상하부-뇌하수체-부신계(HPA)를 복잡하게 조절하고 있다는 증거가 많이 나오고 있다. 그 중에서도 5-HT(Serotonin)계의 stress시의 역할에 대해서는 많은 연구가 있어왔으나 아직 논란이 많이 제기되고 있다. 따라서 저자는 5-HT가 stress시 HPA axis를 조절하는데 필수적인 역할을 하는가를 말아보기 위해서 1) Stress전후에 5-HT의 steady state농도와 5-HT의 교체율(turnover rate) 및 합성율(synthesis rate)을 측정해 보았으며 2) 비교적 5-HT계에 특이하게 작용하는 여러 약물들을 주사한 후에 stress 반응을 측정해 보았다. 1) 1분간 ether stress 가한 직후에 시상하부와 다른 뇌부위에서의 5-HT와 5-HIAA농도는 즉각적으로 의미있게 상승하였으나 혈장 corticosterone농도는 즉각상승을 보이지 않다가 2분후에 상승을 보였다. 2) Stress(30분 immobilization & 1분 ether stress)가한 백서에서는 시상하부와 다른 뇌부위에서 5-HT합성을 혹은 교체율이 2배-4배까지 상승하였다. 3) 5-HT합성 전구물질(L-tryptophan)과 수용체 자극제 (5-MeODMT)를 투여하였을 때는 투여용량에 비례해서 혈장 corticosterone함량이 상승하였다. 4) L-tryptophan과 MAO억제제 (pargyline) 혹은 L-tryptophan과 5-MeODMT의 병합 투여로 stress시 혈장 corticosterone의 상승이 더 높게 나타났다. 5) 5-HT 합성억제제(PCPA), 5-HT 신경독약(5,7-DHT)을 투여하고 stress를 가하였을 때는 시상하부와 다른 뇌 부위에서 5-HT의 하강이 별로 나타나지 않았으며, 동시에 혈장 corticosterone의 하강도 의미있게 나타나지 않았다. 그러나 midline raphe핵을 파괴하였을 때는 5-HT와 corticosterone의 하강이 나타났다. 6) 비교적 특이하게 serotonin제에 작용하는 여러 약물들을 투여한 후에 나타나는 5-T와 혈장 corticosterone함량 사이에는 상당히 높은 양의 상관관계계가 있었다(r>0.81). 이상의 결과를 종합해 볼때 serotonin(5-HT)은 시상하부-뇌하수체-부신계의 스트레스반응조절에 중요한 자극적 역할을 하리라고 생각된다.

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화력발전소 석탄비산재를 이용한 Na-X와 Na-A 제올라이트 제조 및 상업용 제올라이트와의 Cu(II) 흡착 특성 비교 (Preparation of Na-X and Na-A Zeolites from Coal Fly Ash in a Thermoelectric Power Plant and Comparison of the Adsorption Characteristics for Cu(II) with a Commercial Zeolite)

  • 최유림;;김동수;안혜영;김대호;최치동;;양재규;장윤영
    • 공업화학
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    • 제30권6호
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    • pp.749-756
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    • 2019
  • 본 연구에서는 화력발전소에서 채취한 석탄 비산재(coal fly ash)로부터 fusion method를 이용하여 중금속 흡착 성능이 뛰어난 Na-X과 Na-A 제올라이트를 합성하였다. 또한 이를 이용하여 Cu(II) 흡착 성능을 상업용 Na-X 및 Na-A 제올라이트와 비교하였다. 제올라이트의 최적 합성 조건을 선정하기 위해 fusion method의 주요 영향인자인 NaOH 주입비율, 숙성시간(aging time), 수열반응 시간(hydrothermal reaction time), NaAlO2 (Na-A) 주입비율의 변화에 의한 제올라이트의 특성을 고찰하였다. 그리고 XRD, CEC, BET, SEM 분석을 실시하였으며, 최적의 제올라이트 합성 조건은 NaOH 주입 비율 = 1.5, 숙성시간 = 6 h, 수열반응 시간 = 6 h, NaAlO2 (Na-A) 주입 비율 = 0.5인 것으로 확인되었다. Langmuir 등온 흡착곡선의 분석결과, Cu(II)에 대한 최대 흡착 농도는 합성된 Na-X와 Na-A 제올라이트의 경우 각각 90.1와 105.26 mg/g, 상업용 Na-X와 Na-A 제올라이트의 경우 각각, 102.05와 109.89 mg/g으로 나타나 Cu(II) 흡착 성능에 있어서 합성 제올라이트와 상업용 제올라이트가 유사한 결과를 보여주었다. 따라서 본 실험의 결과들은 화력발전소 석탄 비산재의 제올라이트 합성 재료로서의 활용 가능성을 나타내었다.

Mn-전기석(Tsilaisite)의 합성 및 리트벨트 구조분석 (Synthesis and Rietveld Structure Refinement of Mn-Tourmalines (Tsilaisite))

  • ;최진범
    • 한국광물학회지
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    • 제19권1호통권47호
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    • pp.15-29
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    • 2006
  • 2 Kbar, $375{\sim}700^{\circ}C$ 조건하에서, 드라바이트의 Mg를 전 구간 치환하는 Mn 조성(Mn%=0, 25, 50, 75, 및 100%)을 가지고 열수법으로 약 50일간 성장시켜 Mn-전기석(tsilaisite)을 합성하였다. 그 결과, 조성별로 생성온도가 다른 6개의 합성 전기석이 얻어졌으며, 앨바이트, 스페샤틴, 능망간석, 금운모 등 다양한 불순물이 함께 생성되었다. 합성 Mn-전기석의 X-자리의 자리결손($0.53{\sim}0.68$)이 천연산(약 $0.2{\sim}0.3$)보다 높게 나타났으며, Y-자리의 Mn mole wt.%는 예상보다 낮은 값을 보이며, 단종 성분의 tsilaisite를 합성하지 못했다. 다양한 복합상으로 이루어진 분말 합성 전기석에 대해 리트벨트 구조분석을 실시하였다. $R_{wp}$값은($R_{p}/R_{exp}$)은 $13.35{\sim}18.62%$의 범위를 보여주며, $R_{B}$ 값은 $4.85{\sim}6.25%$ (S-18: 8.57%), S (GofF) 값은 $1.31{\sim}l.59$ (S-18: 1.81)으로 각각 나타났다. 단위포의 평균값은 공간군 R3m (z=3)으로 ${\alpha}=15.8994\;{\AA},\;c=7.1846\;{\AA}$이며, S-18은 ${\alpha}=15.9491\;{\AA},\;c=7.1773\;{\AA}$이다. 평균 값은 $2.67{\sim}2.69\;{\AA}$ (S-18: $2.65\;{\AA}$), 평균 값은 $2.00{\sim}2.02{\AA}$ (S-18: $1.96\;{\AA}$)으로 각각 계산되었으며, 대칭도(ditrigonality)를 나타내는 ${\delta}$값을 보면 $0.022{\sim}0.031$ (S-18: 0.061)의 범위를 가지는데 Mn 함량이 높아지면서 대칭도가 낮아진다.