• Title/Summary/Keyword: Swollen surface

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Stabilization of Tocopheryl Acetate of Swollen Micelle by Poloxamer (Poloxamer를 이용한 Swollen Micelle의 Tocopheryl Acetate 안정화)

  • Kim, Mi-Seon;Yoon, Kyung-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.609-622
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    • 2019
  • When the surfactant is dissolved in an aqueous solution, it forms aggregate called micelles (<20 nm) in the solution, and micelles can form the solubilized formulation by supporting the active ingredient therein. Swollen micelles are formulations capable of carrying larger amounts of active ingredient than conventional solubilized formulations at 50~100 nm. Unlike liposomes or nanoemulsions, which require a separate process such as high pressure emulsification, Swollen micelle is a more efficient method of solubilization and particle formation from a productive point of view. In this study, stabilization experiments on swollen micelle formulations were carried out using poloxamer 407, and then optimized formulation experiments for tocopheryl acetate components were performed using Response Surface Methodology (RSM). Tocopheryl acetate, a surfactant that affects solubilization and an active substance, were set as a factor and the correlation between them was confirmed. As the evaluation method, stability and particle size distribution and size were confirmed by temperature and time, and the structure and shape of the swollen micelle carrying the active ingredient were confirmed by FIB. These results show that poloxamer 407 0.500%, octyldodeceth-16 0.387% and tocopheryl acetate 0.945% are the most optimized prescriptions for swollen micelle stabilized with tocopheryl acetate.

Basidiospore Development and Fine Structure of Entoloma (외대버섯속의 담자포자의 발생과 미세구조)

  • Cho, Duck-Hyun
    • Korean Journal of Plant Resources
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    • v.6 no.2
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    • pp.141-145
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    • 1993
  • Apexes of basidia in Rhodophyllus(synonyum of Entoloma) muraii var. albus are divided into four sections or depressed in the center. A spore is formed by inflation of the apex of the sterigma. The apex of the sterigma is swollen and changed from a papilla through a penisform and a club into a globeform. Six spots of globose spore are regularly or irregularly depressed with hilum axes. Finally the spores are cuboid. Basidia of Entoloma squamiferrum are developed from hymenium layer of crator-shaped parabasidium. Apex of basidium is flat or depressed in the center. Although four sterigmata are developed, only two sterigmata are symmetrically swollen to two spores in certain basidia. It means that two sterigmata among four sterigmata are infertile. The apex of the sterigma is swollen into a paillaform, and then turned into a penisform. It is swollen from a clubform into a globeform. Six spots of the surfaces of globose spore are deperssed with hilum axes. Finally the spore is cuboid, and then it is released from hilum. Four sterigmata of papillaform of E. violaceobrunneum are developed from cartor-shaped basidium. The apex of sterigma is swollen to a small globeform. And then it is swollen to a clubform. The clubform is again swollen to a ellipticalform, and then more than six spots of spore surfaces are ramomly depressed with hium axes. When the depression of surface of a elliptical spore is over, it is the multi-angular spore of the heterometrical-form.

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Effects of Risering Design and Chemical Composition on Formation of Shrinkage Cavity in Gray Cast Iron (회주철의 수축결함생성에 미치는 주조방안 및 화학조성의 영향)

  • Yu, Sung-Kon
    • Korean Journal of Materials Research
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    • v.13 no.5
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    • pp.297-302
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    • 2003
  • The effects of risering design and alloying element on the formation of defects such as external depression, primary and secondary shrinkage cavity in gray cast iron were investigated. Two types of risering design for the cylindrically step-wise specimen, No. 1(progressive solidification) and No. 2(directional solidification) risering designs, were prepared and five different alloy compositions were casted. In the No. 1 risering design, external depression or primary shrinkage cavity due to liquid contraction was observed in all the specimens from ISO 150 to ISO 350. The primary shrinkage cavity was located right under the top surface or connected to the top surface, and was characterized by smooth surface. Its size increased with an increase in ISO number. However, neither secondary shrinkage cavity nor swollen surface was observed in all the castings. In the No.2 risering design, neither primary shrinkage cavity nor secondary shrinkage cavity was observed in all the specimens due to proper risering design. A swollen surface was also not observed in all the castings with the application of pep-set mold.

Basidiospore Development and Fine Structure of Entoloma violaceobrunneum (황보라 외대버섯의 담자포자의 발생과 미세구조)

  • Cho, Duck-Hyun;Kwon, Sun-Bang
    • Korean Journal of Plant Resources
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    • v.6 no.1
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    • pp.83-86
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    • 1993
  • Four sterigmata of papillaform E. violaceobrunneum are developed from crator-shaped basidium. The apex of sterigma is swollen to a small globeform. And then it is swollen to a clubform. The clubform is again swollen to a ellipticalform, and then more than six spots of spore surfaces are ramdomly depressed with hilum axes. When the depression of surface of a elliptical spore is over, the spore is a heterodiametrical spore of multi-angular.

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Effects of Risering Design and Alloying Element on Formation of Shrinkage Cavity in Ductile Cast Iron (구상흑연주철의 수축결함생성에 미치는 주조방안 및 합금원소의 영향)

  • Yu, Sung-Kon
    • Korean Journal of Materials Research
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    • v.13 no.2
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    • pp.74-80
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    • 2003
  • The effects of risering design and alloying element on the formation of defects such as external depression, primary and secondary shrinkage cavities in ductile cast iron were investigated. Two types of risering design for the cylindrically step-wise specimen, No. 1(progressive solidification) and No. 2(directional solidification) risering designs, were prepared and six different alloy compositions were casted. In the No. 1 risering design, external depression or primary shrinkage cavities due to liquid contraction were observed in all the specimens from SG 10 to SG 60. The defects caused by liquid contraction seemed to be more affected by risering design than alloying elements. The secondary shrinkage cavities were also observed in all the specimens but a swollen surface was not observed in all the castings. The primary shrinkage cavities were located right under the top surface or connected to the top surface, and were characterized by smooth surfaces. On the other hand, the secondary shrinkage cavities were positioned in the thermal center of the specimen steps 3 and 4, and characterized by rough surfaces. In the No. 2 risering design, no external depression or primary shrinkage cavities due to liquid contraction were observed in all the specimens from SG 10 to SG 60. However, the secondary shrinkage cavities were formed in the thermal center of specimens SG 40, 50 and 60. Like the No. 1 risering design, a swollen surface was not observed in all the castings.

Characteristics of Maltose Formation in Heterogeneous Enzyme Reaction System Utilizing Swollen Extrusion Starch as a Substrate (팽윤 Extrusion 전분을 기질로 한 불균일상 효소반응계에서의 Maltose 생성 반응 특성)

  • Kim, Dong-Sun;Park, Dong-Chan;Cho, Myung-Jin;Lee, Yong-Hyun
    • Microbiology and Biotechnology Letters
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    • v.22 no.3
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    • pp.283-289
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    • 1994
  • The production of maltose utilizing swollen extrusion starch seems to have many technical advantages, such as, high reaction rate and high yield, production of high purity concentrated maltose, and low energy consumption, over the conventional method utilizing liquefied starch. The characteristics of maltose formation in heterogeneous enzyme reaction system comtaining swollen extrusion starch was investigated using fungal $\alpha $-amylase. The influence of extrusion conditions on structure of extruded starch, such as, degree of gelatinization, water absorption index, and water solubility index was analyzed. The relationship between the structural features and maltose forming reaction was investigated, and the result was analyzed in terms of surface reaction of insoluble extruded swollen starch. The characteristics of maltose formation from swollen sxtrusion starch was compared using endo-type fungal $\alpha $-amylase and exo-type $\beta $anylase, and the structural trasformation of extruded starch was also observed to clarify the reaction mechanism.

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A Phenomenological Study on Micellization and Solubilization (Micelle 형성에 관한 현상학적 고찰)

  • Myung Soo Kim
    • Journal of the Korean Chemical Society
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    • v.33 no.5
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    • pp.459-467
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    • 1989
  • When the sufactants are dissolved in water, they associate to form micelles and solubilize oil inside the micelle to form swollen micelles. Although spherical aggregates like micelles and swollen micelles occupy the same regions in the phase diagram of water-oil-surfactant systems, they are treated in different viewpoint for the formation of such aggregates. Hence a unified thermodynamic formalism for the formation of such structure is presented in this study. In all cases, the to ideal solution theory is applied for dilute system and the energy of formation is expressed as the sum of hydrophobic interaction energy and surface energy due to surfactant film. From the model, critical micelle concentration (CMC), average aggregation number, and solubilization ratio are predicted and compared with the known experimental observation.

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Histology and Morphometries of the Epidermis of the Fins and Sucking Disc of the Mudskipper, Periophthalmus modestus (Pisces, Gobiidae)

  • Park, Jong-Young;Kim, Ik-Soo;Lee, Yong-Joo;Kim, So-Young
    • Animal cells and systems
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    • v.8 no.2
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    • pp.111-115
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    • 2004
  • The epidermis of the mudskipper, Periophthalmus modestus, consists of three layers- the outermost layer, middle layer and stratum germinativum. Extensive fine blood capillaries are present near the superficial layer of epidermis and outermost layer in five fins and a sucking disc. The diffusion distance between the vascular capillaries and the surface of epidermis ranged from 3.6 to 10.9${\mu}$m: 3.6 ${\mu}$m in the sucking disc, 10.9 ${\mu}$m in the anal fin and 4.6 to 5.0 ${\mu}$m in the two dorsal fins. Rate of the surface area of respiratory epithelium, the surface area of the fine blood capillaries occupied per surface area of epidermis in 0.1mm, is 3.7 to 4.4% in two dorsal fins and 1.1% in the anal fin. The middle layer is simpler in structure consisting of small or voluminous cells swollen by epidermal cells, and this layer appeared web-like. Well-developed lymphatic spaces containing lymphocytes existed in the stratum germinativum. The five fins and sucking disc had no epidermal glands.

Fabrication of three-dimensional electrical patterns by swollen-off process: An evolution of the lift-off process

  • Mansouri, Mariam S.;An, Boo Hyun;Shibli, Hamda Al;Yassi, Hamad Al;Alkindi, Tawaddod Saif;Lee, Ji Sung;Kim, Young Keun;Ryu, Jong Eun;Choi, Daniel S.
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1235-1239
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    • 2018
  • We present a novel process to fabricate three-dimensional (3D) metallic patterns from 3D printed polymeric structures utilizing different hygroscopic swelling behavior of two different polymeric materials. 3D patterns are printed with two different polymers as cube shape. The surface of the 3D printed polymeric structures is plated with nickel by an electroless plating method. The nickel patterns on the surface of the 3D printed cube shape structure are formed by removing sacrificial layers using the difference in the rate of hygroscopic swelling between two printing polymer materials. The hygroscopic behavior on the interfaced structure was modeled with COMSOL Multiphysics. The surface and electrical properties of the fabricated three-dimensional patterns were analyzed and characterized.

Morphological and Cytochemical Study on the Skin of Korea Eel Goby, Odontamblyopus lacepedii(Pisces, Geobiidae)

  • Park, Jong-Young;Lee, Yong-Joo-Ik-Soo;Kim, So-Young;Kim, So-Young
    • Animal cells and systems
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    • v.7 no.1
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    • pp.43-47
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    • 2003
  • The skin of the eel goby, Odontamblyopus lacepedii, consists of epidermis, dermis and subcutis. The epidermis has three layers: the outermost layer, middle layer and stratum germinativum. The outermost layer is composed of polygonal cells or rather flattened cells, and mucous gland cells of acid mucopolysaccharides. The middle layer consists mainly of swollen small or voluminous epidermal cells and shows a web-shaped structure. The thickness of the epidermis depends on the various sizes and the number of layers of the swollen cells. Well-developed lymphatic spaces containing lymphocytes exist in the stratum germinativum and small scales are embedded in the dermis. A large number of blood capillaries are present just below the basement membrane, and a definite area giving AB and PAS positive was present between the basement membrane and scales, Taste buds ave distributed on surface of the epidermis at intervals. Considering the structural features of the skin, it may be considered that O. lacepedii is more likely to be related to cutaneous respiration as a dual respiratory system.