• Polymer(Korea)
• /
• v.30 no.1
• /
• pp.50-55
• /
• 2006

When the monodisperse polystyrene(PS)/HDDA polymer particles were synthesized via one-step polymerization using polystyrene seed particles by dispersion polymerization, the effects of 1) the molecular weight of seed polymer particles, 2) the ratio of the absorbed HDDA to the seed polymer particles (swelling ratio) and 3) seeded polymerization rate on the surface morphology of PS/HDDA polymer particles were investigated. It was observed that the creation of the crater shaped defect on the surface of PS/HDDA polymer particles was irrespective of the molecular weight of seed polymer ant swelling ratio. But its surface morphology could be controlled by the change of the seeded polymerization rate.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.47 no.3
• /
• pp.3-10
• /
• 2015

In this study, we evaluated properties of pulp treated with swelling agent and swelling concentration. We used swelling agent, such as NaOH, DMSO, urea. One of them, pulps treated with NaOH from 0 to 5% measured WRV, beating efficiency, crystallinity and aspect ratio. We identified that NaOH when freeness reaches 100mL CSF was the shortest, on the other hand, WRV didn't change. Because NaOH is good beating efficiency, when pulp treated with various concentration of NaOH from 0 to 5%, pulp treated 1% NaOH was best beating efficiency. However, WRV, crystalline structure and crystallinity didn't change. The more NaOH concentration increased, the more aspect ratio increased, but when NaOH concentration exceeds 3%, aspect ratio decreased. As a result, pulp treated with 1% NaOH was the greatest beating efficiency and WRV, chemical structure didn't change.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2014.05a
• /
• pp.288-289
• /
• 2014

The purpose of this research is to examine strength properties of epoxy-modified mortar with expansive and swelling agent contents. The polymer-modified mortars (PMMs) using epoxy resin are prepared with various polymer-binder ratios, expansive and swelling agent contents. The PMMs using epoxy resin are tested for compressive, flexural and tensile strengths. As a result, the strength properties of the PMMs using epoxy resin are depending on the polymer-binder ratio rather than expansive and swelling agent content, and are remarkably improved over unmodified mortar (UMM).

• Macromolecular Research
• /
• v.16 no.1
• /
• pp.45-50
• /
• 2008

This study examined the swelling behavior and in vitro release of a model drug, tetracycline-HCl, from alginate and alginate-polyaspartate (Alg-PASP) composite gel beads. The alginate and Alg-PASP composite beads were prepared using an ionic crosslinking method with aqueous $Ca^{2+}$. Their microporous morphology was observed by scanning electron microscopy. The swelling ratio of the beads in different media varied according to their composition, cross-linking density ($Ca^{2+}$ concentration), and pH of the aqueous medium. The in vitro release experiment of the tetracycline-HCl encapsulated beads in different media suggests that the release of the drug is governed mainly by the swelling properties of the polymer network. The presence of PASP was found to significantly influence the swelling properties and drug release profile.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2002.05a
• /
• pp.81-84
• /
• 2002

Recently Bentonite mat is applied various structure : External waterproofing for underground structure, A reclaimed land, Artificial lake, Large-scaled civil structure, etc. With these various structure environment, water quality for application of Bentonite Mat affects watertightness. Specially spot with a large quantity of Chloride ion like salt water, degree of watertightness revelation is evaluated and applied. In this study, it is a main goal to investigate watertightness of Bentonite Mat with distilled water and salt water dissolved chloride ion Contents 0.88%. The result of this paper is as follows. 1) Water permeability coefficient of Bentonite Mat : distilled water(1.21$\times$10$^{-9}$cm/sec), salt water(3.12$\times$10$^{-7}$cm/sec). 2) Variation of thickness : distilled water(187%), salt water(108%). 3) Swelling ratio : distilled water(1500%), salt water(350%).

• Korea-Australia Rheology Journal
• /
• v.11 no.3
• /
• pp.225-232
• /
• 1999

This study presents 1-dimensional simple model for sheet casting or rectangular fiber spinning process. In order to achieve this goal, we introduce the concept of force flux balance at the die exit, which assigns for the extensional flow outside the die the initial condition containing the information of shear flow history inside the die. With the Leonov constitutive equation that predicts non-vanishing second normal stress difference in shear flow, we are able to describe the anisotropic swelling behavior of the extrudate at least qualitatively. In other words, the negative value of the second normal stress difference causes thickness swelling much higher than width of extrudate. This result implies the importance of choosing the rheological model in the analysis of polymer processing operations, since the constitutive equation with the vanishing second normal stress difference is shown to exhibit the characteristic of isotropic swelling, that is, the thickness swell ratio always equal to the ratio in width direction.

• Polymer(Korea)
• /
• v.37 no.4
• /
• pp.478-485
• /
• 2013

In this study, hydrogels with fast swelling and high absorbent properties were prepared using biopolymers approved as a food additive and their swelling properties were characterized. To improve the swelling properties of conventional hydrogels, we formed gas bubbles using a foaming agent in the process of preparing hydrogels and characterized in terms of equilibrium swelling ratio, swelling kinetics and cytotoxicity. In particular, alginate hydrogels observed by a digital microscope have an open-pore channels structure with the sizes of hundreds micrometers. Also, the cell viability of all hydrogels were found to be much higher than that of poly(acrylic acid).

• Archives of Pharmacal Research
• /
• v.28 no.8
• /
• pp.983-987
• /
• 2005

Hydrogels composed of glycidyl methacrylate dextran (GMD) and poly(acrylic acid, PM) were prepared by UV irradiation method for colon-specific drug delivery. GMD was synthesized by coupling of glycidyl methacrylate to dextran in the presence of 4-(N,N-dimethylamino)pyridine. GMD was photo-polymerized by ammonium peroxydisulfate as initiating system in phosphate­buffered solution (0.1 M, pH 7.4). And then, acrylic acid monomer was added and subsequently heat-polymerized by 2,2'-azobisisobutyronitrile as an initiator. The hydrogels exhibited high swelling ratio (about 20) at $37^{\circ}C$, and showed a pH-dependent swelling behavior. In addition, the swelling ratio of the hydrogel was remarkably enhanced to about 45 times in the presence of dextranase at pH 7.4. The swelling-deswelling behavior proceeded reversibly for the GMD/PM hydrogels between pH 2 and pH 7.4. Release of 5-aminosalicylic acid from the GMD/PAA hydrogels was evaluated in simulated gastrointestinal pH fluids in the absence or presence of dextranase. We concluded that the hydrogels prepared could be used as a dual-sensitive drug carrier for sequential release in gastrointestinal tract.

• Journal of Adhesion and Interface
• /
• v.12 no.2
• /
• pp.56-61
• /
• 2011

In the present study, glucose-sensitive hydrogels using phenylboronic acid (PBA) without glucose oxidase and catalase were prepared. The swelling-shrinking behavior of the hydrogel according to the variation of pH and glucose and ionic concentrations was investigated. The swelling ratio of the hydrogel containing PBA increased with increasing the glucose concentration and the volume was very sensitively varied with the pH. However, the ionic concentration did not change significantly the relative swelling ratio on the hydrogel, indicating that the hydrogel was dimensionally stable.

• Geomechanics and Engineering
• /
• v.22 no.3
• /
• pp.227-236
• /
• 2020

Expansive soils are renowned for their swelling-shrinkage property and these volumetric changes resultantly cause huge damage to civil infrastructures. Likewise, subgrades consisting of expansive soils instigate serviceability failures in pavements across various regions of Pakistan and worldwide. This study presents the use of polypropylene fibers to improve the engineering properties of a local swelling soil. The moisture-density relationship, unconfined compressive strength (UCS) and elastic modulus (E₅₀), California bearing ratio (CBR) and one-dimensional consolidation behavior of the soil treated with 0, 0.2, 0.4, 0.6 and 0.8% fibers have been investigated in this study. It is found that the maximum dry density of reinforced soil slightly decreased by 2.8% due to replacement of heavier soil particles by light-weight fibers and the optimum moisture content remained almost unaffected due to non-absorbent nature of the fibers. A significant improvement has been observed in UCS (an increase of 279%), E₅₀ (an increase of 113.6%) and CBR value (an increase of 94.4% under unsoaked and an increase of 55.6% under soaked conditions) of the soil reinforced with 0.4% fibers, thereby providing a better quality subgrade for the construction of pavements on such soils. Free swell and swell pressure of the soil also significantly reduced (94.4% and 87.9%, respectively) with the addition of 0.8% fibers and eventually converting the medium swelling soil to a low swelling class. Similarly, the compression and rebound indices also reduced by 69.9% and 88%, respectively with fiber inclusion of 0.8%. From the experimental evaluations, it emerges that polypropylene fiber has great potential as a low cost and sustainable stabilizing material for widespread swelling soils.