• Title/Summary/Keyword: Surface zeta potential

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Preparation and Surface Charge Characterization of Polystyrene Particles and Powders with Carboxyl and/or Poly(ethylene glycol) Groups

  • Kim, Bae-Joong;Kim, Seong-Hun;Park, Ki-Hong
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.94-94
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    • 2003
  • Cross-linked polystyrene (PS) particles with carboxyl and/or poly(ethylene glycol) units on surface were formed by an emulsifier-free emulsion polymerization using styrene, methacrylic acid (MA), and poly(ethylene glycol) dimethacrylate (PEG-diMMA) at pH 7, and followed by freeze-drying to give the corresponding powders. Monodisperse polymer particles could be obtained at a concentration of PEG-diMMA 1 mol% relative to styrene. Zeta potential of polymer surface was measured to be 91 mV at a polymer of PEG-diMMA 1 mol% and was dropped as the content of MA increased.

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Dyeability of photooxidized meta-aramid fabrics to cationic dyes

  • Dong, Yuanyuan;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.11a
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    • pp.79-80
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    • 2009
  • Aramid fabrics were photooxidized by UV/$O_3$ irradiation. The UV irradiation caused the oxygen content of the aramid fabric surface to increase and reduced the surface zeta potential, coupled with improved water wettability. The modified aramid fabrics showed higher affinity to cationic dyes which may be resultd from the newly introduced electrostatic interaction between cationic dyes and anionic dyeing sites on the photooxidized surface layers. Although color fastness to both staining and rubbing were good to excellent, color fastness to shade change was moderate.

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Surface Modification of Nanofiltration Membrane with Silane Coupling Agents for Separation of Dye (실란 표면 개질된 나노복합막의 염료 분리 특성)

  • Park, Hee Min;Lim, Jee Eun;Kim, Seong Ae;Lee, Yong Taek
    • Membrane Journal
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    • v.28 no.6
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    • pp.414-423
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    • 2018
  • In this study, the commercial nanofiltration membranes were modified with octyltrimethoxysilane(OcTMS) and (3-aminopropyl)trimethoxysilane (APTMS) to improve fouling resistance and to separate dye. The chemical structure and binding energy of elements of silane-deposited surface were analyzed using XPS analysis. And the morphology and hydrophilicity property of silane-modified NF membrane were analyzed using FE-SEM, EDX, AFM, and contact angle. The surface charge of silane-modified NF membrane was characterized by zeta potentiometer analyzer. As a result, silane-modified NF membrane improved fouling resistance about 2 times as compared with that of the commercial membrane. And the silane-modified NF membranes effectively were removed cation dye over 98%.

Antibacterial properties of traditional ceramic glazes containing copper oxide (산화구리를 함유하는 전통 세라믹 유약의 항균특성에 관한 연구)

  • Kim, Ung-Soo;Choi, Jung-Hoon;No, Hyung-Goo;Han, Kyu-Sung;Kim, Jin-Ho;Hwang, Kwang-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.372-378
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    • 2019
  • Traditional ceramic glazes formulated with copper oxide (CuO) exhibited antibacterial properties on Staphylococcus aureus (Gram Positive) and Escherichia coli (Gram Negative). All the ceramic glazes containing CuO showed antibacterial behavior when fired in reducing atmosphere. However, some of copper glazes presented antibacterial behavior and had no antibacterial properties at all when sintered in an oxidizing atmosphere. To elucidate the antibacterial mechanism, ceramic glazes were studied for phase and microstructure analysis, dissolution behavior and surface zeta potential. Metallic copper was precipitated in the glaze layer when sintered in reducing atmosphere. Less than 0.05 ppm of Cu ion was dissolved from glazes. Ca ion was most dissolved among all the samples. Glaze surface was highly negatively charged when CuO was added over 3 wt.% regardless of the sintering atmosphere. The antibacterial behavior of ceramic glazes seemed to be directly related to the dissolution behavior of cations, but the antibacterial behavior of oxidized specimens was not explained by the dissolution behavior. Surface potential of ceramic glazes appeared to play an auxiliary role in antibacterial properties.

Synergistic Effect of Reductase and Keratinase for Facile Synthesis of Protein-Coated Gold Nanoparticles

  • Gupta, Sonali;Singh, Surinder P.;Singh, Rajni
    • Journal of Microbiology and Biotechnology
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    • v.25 no.5
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    • pp.612-619
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    • 2015
  • We have synthesized gold nanoparticles (GNPs) using chicken feathers (poultry waste) and Bacillus subtilis RSE163. Disulfide reductase and keratinase produced by Bacillus subtilis during the degradation of chicken feather has been used to reduce Au3+ from HAuCl4 precursor to produce gold nanoparticles. The synthesized biogenic GNPs were characterized by UV-visible spectroscopy, transmission electron microscopy (TEM), and zeta potential measurements. Fourier transform infrared (FTIR) spectroscopy indicated the presence of protein capping on synthesized GNPs, imparting multifunctionality to the GNP surface. Furthermore, the nontoxic nature of biogenic GNPs was insured by interaction with Escherichia coli (ATCC11103), where TEM images and enhancement of growth rate of E. coli in log phase signified their nontoxic nature. The results indicate that the synthesis of biocompatible GNPs using poultry waste may find potential applications in drug delivery and sensing.

Surface Electrochemical Study on the Fixation Properties of New Water-borne Preservatives in Red Pine (새로운 수용성(水溶性) 방부방충제(防腐防蟲劑)의 재중(材中) 정착성(定着性)에 관한 계면전기화학적(界面電氣化學的) 특성(特性))

  • Kim, Yeong-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.4
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    • pp.93-99
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    • 1996
  • In order to investigate the extent of fixation of new water-borne preservatives in blocks of pinus densiflora sapwoods the streaming potential through the column with preservative treated wood was measured at various conditions. The rates of leachability of ingredients in the treated wood were estimated by the measurement of electric conductivity of the solution with the leached components. The solution was also analyzed by Atomic absorption spectrophotometer (AA). As a results, the experimental data indicated that the fixation of CCB, CCFZ and ACQ in wood were relatively unstable. The fixation rates of CCB, CCFZ were improved by increasing heat and drying time. The amounts of the leached ingredients were apparently higher in CCB and CCFZ than in CCA, while the rate of leaching of ACQ was not changed at various drying temperature.

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Rheological Study on bentonite Clay Sedimentation with various concentrations of Sea water (해수의 농도 변화에 따른 bentonite 침전에 대한 유변학적 고찰)

  • 최상원;서호준
    • Journal of Environmental Science International
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    • v.5 no.1
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    • pp.35-41
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    • 1996
  • For studying of coagulation and sedimentation in estuarine clay, we obtained several flow curves with various concentrations of sea water by using Coutte type rotational rheometer. The initial shear stress on high concentration of sea water was observed big, but after this, its value is decreasing with increasing shear rate. The maximum pick of shear stress is decreasing with the decreasing of concentration of sea water The trend is same totally above for viscosity. The sedimentation times with the concentration of sea water vary in $\infty$ ~ 5 minutes. The zeta potential is changed dramatically between 114 and 118 concentration of sea water. That is consistent with the sedimentation graph. From these results, the phenomena of coagulation and sedimentation can be explained with viscoelastic terms on structual formation among particles by the changes of surface potential affected from contacting sea water to dispersed particles.

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Preparation of Thiol-chitosan Coated EPA-containing Liposome and Immune Response in Mouse Model of Atopic Dermatitis (티올키토산으로 피복된 EPA(Eicosapentaenoic acid) 함유 리포좀의 제조 및 아토피 감염 쥐에 대한 면역 특성)

  • Jung, Hyo-Yun;Kim, Jin;Lee, Yong-Wook;Lee, Ki-Young
    • KSBB Journal
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    • v.25 no.1
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    • pp.97-102
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    • 2010
  • The enhancement of immunity for atopic dermatitis with application of eicosapentaenoic acid (EPA)-loaded liposome was evaluated on NC/Nga mice. The EPA-loaded liposome was coated with thiol-chitosan. The liposomes were characterized with transmission electron microscopy (TEM), surface zeta potential & particle size analyzer (Zeta-PSA) and differential scanning calorimetry (DSC). The loading efficiency of EPA in the liposome was about 4.7%. The particle size of the EPA-Ioaded liposome was about 230 nm. The values of Immunoglobulin E (IgE), interleukin-4 (IL-4), and tumor necrosis factor-$\alpha$ (TNF-$\alpha$) were reduced significantly with application of the EPA-loaded liposome. The interferon-$\gamma$ (IFN-$\gamma$) value was increased with the application effect. It is concluded that EPA loaded liposome have immunity advancing effects in mouse model of atopic dermatitis.

Stability and Improvement of Polishing Pad in W CMP (W CMP 공정에서의 연마패드표면 안정화 상태와 그 개선)

  • Park, Jae-Hong;Kinoshita, Masaharu;Yoshida, Koichi;Matsumura, Shinichi;Jeong, Hae-Do
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.12
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    • pp.1027-1033
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    • 2007
  • In this research, the polishing pad for W CMP has been analyzed to understand stabilization of polishing performance. For stabilization of process, the polishing pad condition is one of important factors. The polishing pad plays a key role in polishing process, because it contact with reacted surface of wafer[1]. The physical property of pad surface is ruled by conditioning tool which makes roughness and profile of pad surface. Pad surface affects on polishing performance such as RR(Removal Rate) and uniformity in CMP. The stabilized pad surface has stable roughness. And its surface has high level of wettability which can increase the probability of abrasive adhesion on pad. The result of this research is that the reduction of break-in and dummy polishing process were achieved by artificial machining to make stable pad surface. In this research, urethane polishing pad which is named IC pad(Nitta-Haas Inc.) and has micro pore structure, is studied. Because, this type of pad is the most conventional type.

Emulsifying Properties of Concentrated Red Ginseng Extract: Influence of Concentration, pH, NaCl (홍삼농축액 함유 유화액의 유화특성에 관한연구)

  • You, Kawn-Mo;Jang, Hyeon-Ho;Lee, Eui-Seok;Lee, Ki-Teak;Hong, Soon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.504-514
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    • 2017
  • This study was carried out to investigate the emulsifying properties of concentrated red ginseng extract (CRGE). First, we determined the interfacial tension of CRGE at the oil-water interface. Second, oil-in-water emulsions were prepared with CRGE and then their physicochemical properties such as fat globule size, zeta-potential, dispersion stability, and microscopic characteristics were determined. It was found that interfacial tension gradually decreased with increasing CRGE concentration, indicative of some surface activity. In emulsions, fat globule size was decreased as CRGE concentration increased, showing a critical value ($d_{43}$$0.39{\mu}m$) at ${\geq}3.5wt%$ of CRGE. In addition, pH and NaCl also influenced on fat globule sizes; they were increased in acidic conditions ($pH{\leq}3$) or in higher NaCl concentration (${\geq}0.4M$) and these results were interpreted in view of the change in zeta potentials. The dispersion stability by separation analyzer ($LUMiFuge^{(R)}$) showed that it was more stable in emulsions with higher CRGE concentration (i.e., ${\geq}3.5wt%$). In conclusion, CRGE was surface-active and it could be used as an emulsifier in preparation of food emulsions.