• Title/Summary/Keyword: Surface migration

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Migration of Alkali and Alkaline Earth Metallic Species and Structure Analysis of Sawdust Pyrolysis Biochar

  • Zhao, Yijun;Feng, Dongdong;Zhang, Yu;Tang, Wenbo;Meng, Shun;Guo, Yangzhou;Sun, Shaozeng
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.659-664
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    • 2016
  • In order to resolve the AAEM species migration routes and the interaction relationship between biochar structure and AAEM species during biomass pyrolysis, experiments were performed in an entrained flow reactor with $N_2$ at $500{\sim}900^{\circ}C$. ICP-AES, XPS and SEM-EDX were used to examine content and distribution of AAEM species and the physicochemical structures of biochar. The results show that at $500{\sim}700^{\circ}C$, the precipitation rate of AAEM species is relatively high. At high temperature (>$700^{\circ}C$), the AAEM species continue to migrate from interior to exterior, but little precipitation from biochar surface. And the migration of AAEM species is mainly realized by the C-O bond as the carrier medium. The AAEM species on biochar surface are mainly Na, Mg and Ca (<$700^{\circ}C$), while changing to K, Mg and Ca (${\geq}700^{\circ}C$). From $500^{\circ}C$ to $900^{\circ}C$, the biochar particle morphology gradually changes from fibers to porous structures, finally to molten particles. At $700{\sim}900^{\circ}C$, Ca element is obviously enriched on the molten edge of the biochar porous structures.

THIN FILM GROWTH AND SURFACE REACTION ON H-TERMINATED SILICON SURFACE

  • Yasuda, Yukio;Zaima, Shigeaki
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.407-414
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    • 1996
  • We have investigated the effects of H atoms on thin film growth processes and surface reactions. In the oxidation of Si, Si surfaces are passivated against the $O_2$ adsorption by terminating dangling bonds with H atoms. Moreover, the existence of Si-H bonds on Si(100) surfaces enhances the structural relaxation of Si-O-Si bonds due to a charge transfer from Si-Si back bonds. In the heteroepitaxial growth of a Si/Ge/Si(100) system, H atoms suppress the segregation of Ge atoms into Si overlayers since the exchange of Ge atoms with Si atoms bound with H must be accompanied with breaking of Si-H bonds. However, 3-dimensional island growth is also promoted by atomic H irradiation, which is considered to result from the suppression of surface migration of adsorbed reaction species and from the lowering of step energies by the H termination of dangling bonds.

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Change in Molecular Weight Distribution of Diffusible Species on RTV Silicone Rubber Using Solvent Extraction and Recovery Rate of Hydrophobicity (용매추출에 의한 옥외용 RTV 실리콘고무의 분자량 변화와 발수성 회복속도)

  • Lee, Chang-R.;Kim, Dong-H.;Choi, Yong-C.;Kim, Jong-G.;Homma, H.;Izumi, K.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1337-1339
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    • 2001
  • We have investigated the relation between the molecular weight distribution (MWD) of diffusible species and the recovery rate of hydrophobicity of room-temperature vulcanizing (RTV) silicone rubber (SIR) using solvent extraction at various temperatures. It was observed that the extract had a MWD ranging from a few hundreds g/mol to hundreds of thousands g/mol. By measuring the migration of siloxane to the extracted SIR surface through a thin carbon coating, the aspect of migration of diffusible species was observed as a real time plot, and the time constant of the migration was also calculated. According to the time dependence of IR-absorbance, the time constant was increased with the increase of MW of the extracts.

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Distribution of Zooplankton in Asan Bay, Korea with Comments on Vertical Migration (아산만 동물플랑크톤 분포와 수직이동)

  • PARK Chul;CHOI Keun-Hyung;MOON Chang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.6
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    • pp.472-482
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    • 1991
  • Seasonal distributions of zooplankton were investigated in Asan Bay, Korea. Labidocera euchaeta, Sagitta crassa, Calanus sinicus, Acartia omorii were dominant taxa throughout the year with seasonally varying percent compositions. Bivalve veliger larva (fall), Decapoda larva (spring and summer), and Paracalanus Parvus, Evadne tergestina (summer) were also dominated during contain period. The patterns of time dependent vertical distributions of one major taxon, A. omorii, showed seasonal differences, i.e., it showed the trends of normal vertical migration in winter and reversed vertical migration in spring. At surface layer day time abundances were equal or less than night time abundances in general.

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Retardation of Mobility of Gaseous VOCs in the Unsaturated Zone (불포화대중 휘발성 유기화합물 가스의 이동지연현상)

  • 이창수;배우근
    • Journal of Korea Soil Environment Society
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    • v.4 no.2
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    • pp.103-111
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    • 1999
  • This study is on the mathematical modeling and its verification of the retardation phenomenon of gas migration in an unsaturated zone of very little moisture content The adsorption of VOCs onto the surface of the dry medium was taken into account, which has not been usually considered in the conventional models. The trichloroethylene(TCE) gas migration predicted from the mathematical model developed in this study fits the experimental results obtained from a dry glass-bead column and a dry silica sand column very well The model developed in this study gave much better prediction than did a coventional model.

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CCR Expression of Bronchoalveolar Lavage Fluid (BALF) Neutrophils and Chemotactic Activity of BALF

  • Choi, Eu-Gene;Yang, Eun-Ju;Kim, Dong-Hee;Lee, Ji-Sook;Kim, In-Sik
    • Biomedical Science Letters
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    • v.17 no.1
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    • pp.89-93
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    • 2011
  • Asthma is an inflammatory airway disease and is characterized by the releases of inflammatory mediators including chemokines. They are mainly associated with the recruitment, activation and dysregulation of specific inflammatory cells, especially neutrophils in neutrophilic asthma. CC chemokines bind to CC chemokine receptors (CCRs) in the surface of their target cells. The aims of this study are to examine the CCR expression in neutrophils of bronchoalveolar lavage fluid (BALF) of asthmatic patients and to determine the alternation of migration and apoptosis of neutrophils by the BALF. We demonstrate that CCR3 strongly expresses in BALF neutrophils of asthmatic patients as compared to other CCRs and increases during apoptosis of the BALF neutrophils. The migration of asthmatic blood neutrophils increases in response to asthmatic BALF as compared to BALF of normal volunteer. In addition, asthmatic BALF includes the higher levels of IL-8 protein than normal BALF and it has no effect on apoptosis of asthmatic blood neutrophils. Taken together, our results indicate that CCR3 expression may be associated with unknown function of asthmatic BALF neutrophils and BALF may be involved in the recruitment of neutrophils into the airway, but not in the neutrophils apoptosis.

Early Healing Responses of the Skin Wounds in the Korean Fire-Bellied Toad, Bombina orientalis (무당개구리 (Bombina orientalis) 피부의 초기 상처치유반응)

  • Jeong, Moon-Jin;Moon, Myung-Jin
    • Applied Microscopy
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    • v.28 no.3
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    • pp.329-343
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    • 1998
  • Early wound healing responses in the skin of the Korean fire bellied toad, Bombina orientalis, were examined using histochemical , scanning and transmission electron microscopical techniques. Cutaneous wounds were induced by sharp razor blade , and maintained in special cages for up to 3 days. By this treatment whole parts of epithelium and dermis were profoundly affected. After injury, retraction of damaged surface of the skin was observed. At 3 hours after injury, poly-band was form by mucous substance. The wound skin consisted of mucous gland secreted mucous substance which flows into wound cavity and the wound area was sealed by mucous substance which form thick layer at 6 hours. It appeared that natural disposition showed acid and neutral mucous substance by reaction of PAS and Alcian blue (pH 2.5) staining. After formation of the poly-band, epithelial cells were formed by migration of regenerating epithelial cells. These cells moved over the wound surface by migration at 12 hours after wounding. Poly-band was much increased in thickness and migrating cells were completely formed wound closure at 24 hours post-wounding. After 72 hours regenerated epithelial layer consists of four or five cell layers which are similar to clear, granular, and spinous layer.

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Potential Applications of Low Altitude Remote Sensing for Monitoring Jellyfish

  • Jo, Young-Heon;Bi, Hongsheng;Lee, Jongsuk
    • Korean Journal of Remote Sensing
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    • v.33 no.1
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    • pp.15-24
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    • 2017
  • Jellyfish (cnidarian) are conspicuous in many marine ecosystems when in bloom. Despite their importance for the ecosystem structure and function, very few sampling programs are dedicated to sample jellyfish because they are patchily distributed and easily clogged plankton net. Although satellite remote sensing is an excellent observing tool for many phenomena in the ocean, their uses for monitoring jellyfish are not possible due to the coarse spatial resolutions. Hence, we developed the low altitude remote sensing platform to detect jellyfish in high resolutions, which allow us to monitor not only horizontal, but also vertical migration of them. Using low altitude remote sensing platform,we measured the jellyfish from the pier at the Chesapeake Biological Laboratory in Chesapeake Bay. The patterns observed included discrete patches, in rows that were aligned with waves that propagated from deeper regions, and aggregation around physical objects. The corresponding areas of exposed jellyfish on the sea surface were $0.1{\times}10^4pixel^2$, $0.3{\times}10^4pixel^2$, and $2.75{\times}10^4pixel^2$, respectively. Thus, the research result suggested that the migration of the jellyfish was related to the physical forcing in the sea surface.

Adhesion and Recovery of Semiconductive Silicone Rubber by Oxygen Plasma Treatment (산소 플라즈마 처리된 반도전성 실리콘 고무의 회복현상 및 접착특성)

  • Lee, Ki-Taek;Hwang, Sun-Mook;Hong, Joo-Il;Seo, Yu-Jin;Hwang, Cheong-Ho;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.147-148
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    • 2005
  • In this work, recovery of semiconductive silicone rubber on oxygen plasma treatment was investigated in terms of X-ray photoelectron spectroscopy(XPS). The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths. As a result, surface methyl groups is removed and an oxidized layer containing Si atoms bound to 3 or 4 oxygens appears. The surface is later covered by a very thin layer due to migration of low-molecular-weight components from the bulk, resulting in decreasing the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber these results are probably due to reorientation of polar groups or migration of low-molecular-weight.

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A Review on the Formation of Desert Pavements in High School Textbooks of World Geography (고등학교 세계지리 교과서의 사막포도 형성에 대한 고찰)

  • Kim, Taeho
    • Journal of The Geomorphological Association of Korea
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    • v.23 no.3
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    • pp.93-104
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    • 2016
  • High school textbooks of world geography show geomorphic featuresin arid environments such as sand dune, yardang and ventifact which are largely created by aeolian processes. Desert pavements, ubiquitous armored surfaces composed of a mosaic of clasts in hot and arid regions, are introduced as a major landform which can be attributed to wind erosion. However, they are formed by a variety of processes including deflation, surface runoff, upward clast migration and dust accretion that cause coarse particles concentration at the surface. The deflation by wind leaving a lag of coarse clasts has been solely regarded at home, even though the classical mechanism of deflation has been evaluated as a relatively unimportant process of pavement formation abroad through empiricalstudies. The accretionary model is gaining wider acceptance, thus implying that desert pavements could be formed through deposition of aeolian material. In addition, sheetflood and upward migration of clasts, irrelevant to the aeolian processes, could also create stone pavements. As a consequence, the deflation process in high school textbooks has to be urgently modified into a range of processes including aeolian mantling. By stressing that desert pavements are an exceptional geomorphic feature in deserts where wind is a predominant geomorphic agent, they can be used as a good example to demonstrate that a landform is not monogenetic.