• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.527-534
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• 1992

Raney nickel was used as catalyst in the hydrogen electrode for an alkaline fuel cell. The hydrogen electrode manufactured with the Raney nickel catalyst which was sintered at $700^{\circ}C$ was found to have the highest electrode performance. Using the Raney nickel powder of average particle size $90{\AA}$ for the electrode, the current density which had been measured was $450mA/cm^2$ at $80^{\circ}C$ using 6N KOH solution as an electrolyte. The effects of PTFE addition were investigated with CO-chemisorption, polarization curves and Tafel slope. CO-chemisorption had shown the optimum value when the Raney nickel was mixed with 5wt% of PTFE, but from the current density and Tafel slope at porous Raney nickel electrode, the appropriate value of PTFE addition was 10wt%. Recommendable Ni and Al portion for Raney nickel was 60 : 40 and loading amount was $0.25g/cm^2$. Also the influence of pressing pressure for manufacturing catalytic layer and for junction with gas diffusion layer was examined. The morphology of catalyst surface was investigated with SEM. The influence of reactivation time and heat-treatment temperature were also studied.

• Journal of The Korean Society of Grassland and Forage Science
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• v.36 no.1
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• pp.34-40
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• 2016

The objective of this study was to determine the effect of moisture content on the physical and chemical characteristics of Italian ryegrass cube. Cube quality according to moisture contents (15, 20, 25, and 30%) was determined. Cubes made with 15 to 20% moisture showed a little cracks. But, the amount of powder generate from these cubes were lower by 10 to 16% compared to other cubes made with 25 to 30% moisture contents. The highest hardness at 159 kg/f was obtained when the cube was made with 15% moisture content and the lowest was 70 kg/f when the cube was made with 30% moisture content. The electrical loading and surface temperature were increased when moisture content was decreased. The chemical compositions of cube were differ from those of raw materials. Crude protein (CP) and ether extract (EE) contents were increased after cubing works. However, crude fiber (CF), acid detergent fiber (ADF), and neutral detergent fiber (NDF) contents were decreased after cubing. The crude ash content was not significantly (p > 0.05) different between raw material and cube. Higher moisture content resulted in higher crude protein content. However, crude fiber and crude ash content were not significantly (p > 0.05) different between each other. The contents of ADF and NDF were the lowest in cubes made with 30% moisture content. Our results suggest that the proper moisture content of Italian ryegrass cubing is recommended to be 15 to 20% and that cubing works should help increase forage quality.

• Korean Journal of Remote Sensing
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• v.25 no.1
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• pp.45-59
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• 2009

This research presents the effect of Asian dust on the derived sea surface temperature (SST) from measurements of the Advanced Very High Resolution Radiometer (AVHRR) instrument flown onboard NOAA polar orbiting satellites. To analyze the effect, A VHRR infrared brightness temperature (TB) is estimated from simulated radiance calculated from radiative transfer model on various atmospheric conditions. Vertical profiles of temperature, pressure, and humidity from radiosonde observation are used to build up the East Asian atmospheric conditions in spring. Aerosol optical thickness (AOT) and size distribution are derived from skyradiation measurements to be used as inputs to the radiative transfer model. The simulation results show that single channel TB at window region is depressed under the Asian dust condition. The magnitude of depression is about 2K at nadir under moderate aerosol loading, but the magnitude reaches up to 4K at slant path. The dual channel difference (DCD) in spilt window region is also reduced under the Asian dust condition, but the reduction of DCD is much smaller than that shown in single channel TB simulation. Owing to the depression of TB, SST has cold bias. In addition, the effect of AOT on SST is amplified at large satellite zenith angle (SZA), resulting in high variance in derived SSTs. The SST depression due to the presence of Asian dust can be expressed as a linear function of AOT and SZA. On the basis of this relationship, the effect of Asian dust on the SST retrieval from the conventional daytime multi-channel SST algorithm can be derived as a function of AOT and SZA.

• Journal of the Korean Geosynthetics Society
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• v.17 no.4
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• pp.119-128
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• 2018

Limit state design has been implemented in Korea since 2015; however, there exists no specification of lateral load determination on retaining wall due to the Korean standard traffic load on retaining wall's backfill surface. The lateral load from traffic depends on lane number, standard truck's axle loads and locations, loading distance from the inner wall. The concept of equivalent height of soil accounting for traffic loadings is typically used for design of retaining walls to quantify the traffic loads transmitted to the inner wall faces. Due to the different characteristics of the standard design trucks between Korea and US (AASHTO), the direct use of the guidelines from AASHTO LRFD leads to incorrect estimation of traffic load effects on retaining walls. This paper presents the results of evaluation of equivalent height of soil to reflect the Korean standard truck, based on the findings from analytical solutions using Bounessq's theory and numerical assessment using 2D finite element method. Consequently, it was found that the equivalent heights of soil from the Korean standard truck load were lower for lower retaining wall height.

• Clean Technology
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• v.25 no.1
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• pp.1-6
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• 2019

Effects of the Cu and K addition and the reduction condition of Fe-based catalysts for Fischer-Tropsch reaction are studied in a continuous flow reactor in this research. The catalysts for the reaction were prepared by homogeneous precipitation followed by incipient wetness impregnation. Physicochemical properties of the $Al_2O_3$ supported Fe-based catalysts are characterized by various methods including X-ray diffraction (XRD), temperature programmed reduction (TPR), and scanning electron microscopy (SEM). Catalytic activities and stabilities of the Fe/Cu/K catalyst are investigated in time-on-stream for an extended reaction time over 216 h. It is found that a reduction of the catalysts using a mixture of CO and $H_2$ can promote their catalytic activities, attributed to the iron carbides formed on the catalysts surface by X-ray diffraction analysis. The addition of Cu induces a fast stabilization of the reaction reducing the time to reach at the steady state by enhancement of catalytic reduction. The addition of K to the catalysts increases the CO conversion, while the physical stability of catalyst decreases with potassium loading up to 5%. The Fe/Cu (5%)/K (1%) catalyst shows an enhanced long term stability for the Fischer-Tropsch reaction under the practical reaction condition, displaying about 15% decrease in the CO conversion after 120 h of the operation.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.143-149
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• 2019

In this study, a U-shape composite beam was developed to be effectively used for a steel parking lot which is 8m or lower in height. When the U-shape composite beam was applied to a steel parking lot, essential considerations were story-height and long-span. In addition, due to the mixed structural system with reinforced concrete and steel material, the U-shape composite beam needed to have a structural integrity and reliable performance over demand capacity. The main objective of this study was to investigate the performance of the structure consisting of the reinforced concrete (RC) slab and U-shape beam. A U-shape composite beam generally used at a parking lot served as a control specimen. Four specimens were tested under four-point bending. To calculate theoretical values, strain gauges were attached to rebar, steel plate, and concrete surface in the middle of the specimens. As the results, initial yielding strength of the control specimen occurred at the bottom of the U-shaped steel. After yielding, the specimen reached the maximum strength and the RC slab concrete was finally failed by concrete crush due to compressive stress. The structural performance such as flexural strength and ductility of the specimen with the increased beam depth was significantly improved in comparison with the control specimen. Furthermore, the design of the U-shape composite beam with the consideration of flexural strength and ductility was effective since the structural performance by a negative loading was relatively decreased but the ductile behavior was evidently improved.

• Journal of the Korean Geotechnical Society
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• v.37 no.2
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• pp.19-31
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• 2021

Micropiles are cast-in-place piles with small diameters. The advantage of micropile is low construction expense and simple procedures, so it is widely applied to existing buildings and structures for the reinforcement of foundation and seismic performances. The base expansion structure has been developed following the original mechanism of horizontal expansion steps under compressive loading. This kind of structure can be installed at the pile end to improve the bearing capacity by tip area enlargement and horizontal force increment to the pile surface area. However, 'Micropile with base expansion structure' cannot be put into practical use, because detailed verification for the developed technique has not been conducted so far. In this research, 3-D numerical analysis was conducted to figure out the bearing mechanism of base expansion micropile and to verify the bearing capacity improvement compared to the general micropiles. 3-D modelling of micropile with base expansion structure was carried out and input parameter was determined. Bearing mechanism induced by base expansion structure was analyzed by lab-scale modelling, and bearing capacity improvement was verified by field-scale analysis.

• Journal of the Korean GEO-environmental Society
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• v.12 no.10
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• pp.83-90
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• 2011

A series of centrifugal model test was conducted to investigate the distribution of vertical earth pressure on circular ductile underground corrugated steel plate waterway culvert with considering the compaction degree of the backfill in the high landfilled embankment section. The compaction degree of backfill was varied to 80, 85, 90, and 95% at the 53g-level gravity considering the similarity of the site. As a result of this test, the load reduction factor by the arching effect of the top of corrugated steel plate showing ductile behavior nearly agreed with the load reduction factor according to the compaction degree of backfill specified in the AISI(2002) design method. The vertical earth pressure measured at the top of the corrugated steel plate was linearly decreased as the compaction degree increased. The greater the compaction degree of backfill was, the greater the reduction of surface loading on the top of the corrugated steel plate by arching effect. The load decreased by arching effect on top of the corrugated steel plate was transferred to the side backfill of the corrugated steel plate(EP 1) and the outside of backfill(EP 3).

• Korean Journal of Food Science and Technology
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• v.53 no.4
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• pp.479-485
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• 2021

To improve the oxidative stability of Glycyrrhiza uralensis extract (GU), GU extraction conditions were optimized for maximal antioxidant activity, and GU-loaded nanocapsules were prepared by chitosan ionic gelation. The optimized ethanol concentration and extraction time were 83.0% and 32.6 min, respectively, using response surface methodology. The particle size of the GU-loaded nanocapsules ranged from 280 to 370 nm. A GU extract of 0.8 mg/mL and chitosan concentration of 2.0 mg/mL were selected as the optimal conditions for entrapment and loading efficiency. Both free GU and GU-loaded chitosan nanocapsules exhibited concentration-dependent antioxidant activity. However, the antioxidant protection factor of GU was effectively maintained when it was entrapped within the chitosan nanocapsules. In conclusion, chitosan nanoencapsulation is a potentially valuable technique for improving the oxidative stability of GU.

• Journal of Dental Rehabilitation and Applied Science
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• v.38 no.3
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• pp.138-149
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• 2022

The clinical applicability of ceramics can be increased by analyzing the causes of fractures after fracture testing of dental ceramics. Fractography to analyze the cause of fracture of dental ceramics is being widely applied with the development of imaging technologies such as scanning electron microscopy. Setting the experimental conditions is important for accurate interpretation. The fractured specimens should be stored and cleaned to avoid contamination, and metal pretreatment is required for better observation. Depending on the type of fracture, there are dimple rupture, cleavage, and decohesive rupture mainly observed in metals, and fatigue fractures and conchoidal fractures observed in ceramics. In order to reproduce fatigue fracture in the laboratory, which is the main cause of fracture of ceramics, a dynamic loading for observing slow crack growth is essential, and the load conditions and number of loads must be appropriately set. A typical characteristic of a fracture surface of ceramic is a hackle, and the causes of fracture vary depending on the shape of hackle. Fractography is a useful method for in-depth understanding of fractures of dental ceramics, so it is necessary to follow the exact experimental procedure and interpret the results with caution.