• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2003년도 추계학술대회 논문집
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• pp.340-345
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• 2003

This study, as a basic study for establishing a influence forecasting/estimating model when drain the deep sea water to the ocean after using it, carried out studies as follows; 1) estimating the amount of river discharge and pollutant loads inflowing into the developing region of deep sea water in East Sea, Korea 2) a field observation of tidal current, vertical distribution of water temperature and salinity, and 3-D numerical experiment of tidal current to analysis physical oceanographic status. The amount of river discharge flowing into the study area was estimated about $462.6{times}10^{3}m^{3}/day$ of daily mean in 2002 year. annual mean pollutant load of COD, TN and TP were estimated 7.02 ton-COD/day, 4.06 ton-TN/day and 0.39 ton/day, respectively. Field observation of tidal current results usually show about $20{\sim}40cm/sec$ of current velocity at the surface layer, it indicated a tendency that the current velocity decreases under 20cm/sec as the water depth increases. We could find a stratification within approximately the depth of 30m in field observation area, and the depth increases. We could find a stratification within approximately the depth of 30m in field observation area, and the differences of water temperature and salinity between the surface layer and bottom layer were about $18^{\circ}C$ and 0.8 psu, respectively. On the other hand, we found that there was a definite as the water mass of deep sea water about 34 psu of salinity.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2014년도 추계학술대회 논문집
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• pp.273-273
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• 2014

Quantum-dot sensitized solar cells (QDSCs) are an emerging class of solar cells owing to their easy fabrication, low cost and material diversity. Despite of the fact that the maximum conversion efficiency of QDSCs is still far less than that of Dye-Sensitized Solar Cells (>12 %), their unique characteristics like Multiple Exciton Generation (MEG), energy band tune-ability and tendency to incorporate multiple co-sensitizers concurrently has made QDs a suitable alternative to expensive dyes for solar cell application. Lead Sulfide (PbS) Quantum dot sensitized solar cells are theoretically proficient enough to have a photo-current density ($J_{sc}$) of $36mA/cm^2$, but practically there are very few reports on photocurrent enhancement in PbS QDSCs. Recently, $Hg^{2+}$ incorporated PbS quantumdots and Cadmium Sulfide (CdS) co-sensitized PbS solarcells are reported to show an improvement in photo-current density ($J_{sc}$). In this study, we explored the efficacy of $In_2S_3$ as an interfacial layer deposited through SILAR process for PbS QDSCs. $In_2S_3$ was chosen as the interfacial layer in order to avoid the usage of hazardous CdS or Mercury (Hg). Herein, the deposition of $In_2S_3$ interfacial layer on $TiO_2$ prior to PbS QDs exhibited a direct enhancement in the photo-current (Isc). Improved photo-absorption as well as interfacial recombination barrier caused by $In_2S_3$ deposition increased the photo-current density ($J_{sc}$) from $13mA/cm^2$ to $15.5mA/cm^2$ for single cycle of $In_2S_3$ deposition. Increase in the number of cycles of $In_2S_3$ deposition was found to deteriorate the photocurrent, however it increased $V_{oc}$ of the device which reached to an optimum value of 2.25% Photo-conversion Efficiency (PCE) for 2 cycles of $In_2S_3$ deposition. Effect of Heat Treatment, Normalized Current Stability, Open Circuit Voltage Decay and Dark IV Characteristics were further measured to reveal the characteristics of device.

• 한국재료학회지
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• 제29권10호
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• pp.623-630
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• 2019

Because of their excellent stability and highly specific surface area, carbon based materials have received attention as electrode materials of electrical double-layer capacitors(EDLCs). Biomass based carbon materials have been studied for electrode materials of EDLCs; these materials have low capacitance and high-rate performance. We fabricated tofu based porous activated carbon by polymer dissolution reaction and KOH activation. The activated porous carbon(APC-15), which has an optimum condition of 15 wt%, has a high specific surface area($1,296.1m^2\;g^{-1}$), an increased average pore diameter(2.3194 nm), and a high mesopore distribution(32.4 %), as well as increased surface functional groups. In addition, APC has a high specific capacitance($195F\;g^{-1}$) at low current density of $0.1A\;g^{-1}$ and excellent specific capacitance($164F\;g^{-1}$) at high current density of $2.0A\;g^{-1}$. Due to the increased specific surface area, volume ratio of mesopores, and surface functional groups, the specific capacitance and high-rate performance increased. Consequently, the tofu based activated porous carbon can be proposed as an electrode material for high-performance EDLCs.

• 한국표면공학회지
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• 제30권1호
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• pp.23-32
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• 1997

The electrolytic boronizing on carbon steels in the mixture of $Na_2B_4O_7$ and NaCl was conducted at 750~$950^{\circ}C$ for 1~6 hours under 0.5A/$\textrm{cm}^2$ current density. The micorostructrure and microheredness of boronized layer was also studien. The effect of the additive such as $CaCl_2$ or NaOH on the formation of boronized layer was also investigated. The boronized layer were composed of two sublayers, i.e., FeB and $Fe_2B$ , which have tooth structure. the average layer thinknesses of the low carbon steel and SM45C boronized at $900^{\circ}C$ for 4hours were 153 and 138 $\mu\textrm{m}$, respectively. The thickness of the twosublayers was significantly increased with increasing boronizing temperature. To obtain a single $Fe_2B$ layer without FeB sublayer, the boronized materials ware homegenized at $950^{\circ}C$ for 4 hours. It was fount that the single layer with a microhardness Hv$\thickapprox$ 1120 -1250 was formed. The calculated activation energies for formation of boronized layer on the low carbon steel and SM45C were 18.7 and 12.6 Kcal/mol, respectively.

• 한국해안·해양공학회논문집
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• 제22권4호
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• pp.215-223
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• 2010

진주만에서 계절별 해수순환구조의 특성을 해석하기 위해 진주만의 서쪽인 노량수로와 동쪽인 대방수로에서 해수유동을 2005년부터 2008년까지 장기간 관측하였다. 진주만의 해수유동은 주로 노량수로와 대방수로를 통한 해수교환에 의해 지배된다. 동계 노량수로의 표층에서 조류는 광양만에서 동쪽인 진주만으로 유입하는 흐름이 발생하고, 저층에서는 진주만에서 서쪽인 광양만으로 유출하는 흐름이 발생하고 있다. 하계 노량수로의 표층에서 조류는 진주만에서 서쪽인 광양만으로 유출하는 흐름이 발생하고 있다. 즉, 노량수로에서 해수순환은 전형적인 열염분순환 형태를 보여주고 있다. 춘계 동-대방수로의 표층에서 조류는 진주만에서 외해로 유출하는 중력순환류가 발생하고 있다. 그러나, 하계 서-대방수로에서는 전층에 걸쳐 진주만내로 유입하는 흐름 양상을 보여주고 있다. 유속의 크기는 서-대방수로에서 유속이 동-대방수로에서 유속보다 약 50~70 cm/sec 정도 크게 나타났다. 노량수로와 대방수로에서 계절별 해수순환 패턴을 보다 정확하게 해석하기 위해서는 현장관측과 3차원 수치모형실험에 관한 상세한 연구가 추가적으로 수행되어야 할 것으로 사료된다.

• 한국재료학회지
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• 제17권10호
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• pp.509-515
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• 2007

In order to fabricate adhesiveless 2-layer flexible copper clad laminate (FCCL) used for COF (chip on film) with high peel strength, polyimide (PI; Kapton-EN, $38\;{\mu}m$) surface was modified by reactive $O_2^+$ and $N_2O^+$ ion beam irradiation. 300 mm-long linear electron-Hall drift ion source was used for ion irradiation with ion current density (J) higher than $0.5\;mA/cm^2$ and energy lower than 200 eV. By vacuum web coating process, PI surface was modified by linear ion source and then 10-20 nm thick Ni-Cr and 200 nm thick Cu film were in-situ sputtered as a tie layer and seed layer, respectively. Above this sputtered layer, another $8-9{\mu}m$ thick Cu layer was grown by electroplating and subsequently acid and base resistance and thermal stability were tested for examining the change of peel strength. Peel strength for the FCCLs treated by both $O_2^+$ and $N_2O^+$ ion irradiation showed similar magnitudes and increased as the thickness of tie layer increased. FCCL with Cu (200 nm)/Ni-Cr (20 nm)/PI structure irradiated with $N_2O^+$ at $1{\times}10^{16}/cm^2$ ion fluence was proved to have a strong peel strength of 0.73 kgf/cm for as-received and 0.34 kgf/cm after thermal test.

• 한국해양공학회지
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• 제15권4호
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• pp.28-37
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• 2001

The water quality in Yongil Bay is getting worse due to the sewage and the waste water from the surrounding industrial complex. The study aims to simulate the current system that is necessary to build ecosystem model for the optium water quality control and clarify the correlation of current system characteristics with water quality in Yongil Bay. To clarify the characteristics of coastal water movement system and verify the applicability of the 3-D model, the current system was simulated using 3-D model baroclinic model which considers tidal current and density effects. As the results of numerical experiments, it is proved the 3-D model is the most applicable on appearing the current system of the stratificated Yongil Bay difference of density. Form the results of simulation considered tidal current only, it can be clarified that the water body flows in the inner bay through the bottom layer and flows out the outer bay through the surface layer in Yongil Bay. And the fresh water from the Hyongsan river and the thermal discharge form POSCO have a little effect on the current system in Yongil Bay, but the diffusion of heat and salt has an important effect upon the formation of the density stratification of the water quality distribution is closely related with the current structure characteristics as well as the tidal residual current system in Yongil Bay.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2000년도 추계학술대회 논문집
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• pp.246-252
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• 2000

The water quality in Yeongil Bay is getting worse due to the sewage and the waste water from the surrounding industrial complex The study aims to simulate the current system that is necessary to built ecosystem model for the optium water quality control and clarify the correlation of current system characteristics with water quality in Yongil Bay. To clarify the characteristics of coastal water movement system and verify the applicability of the 3-D model, the current system was simulated using 3-D baroclinic model considered tidal current and density effects. As the results of numerical experiments, it is proved the 3-D model is the most appliable on the Yongil Bay where current flows slowly and the flow direction is varied by depths. From the results of simulation considered tidal current only, It am be clearly said the water in Yongil Bay flows in through the surface layer and flows out through the bottom layer. And the fresh water from the Hyongsan river and the heated discharge from POSCO have little effect on the current structure in Yonggil Bay, but have and important effect upon the density structure by diffusion of heat and salt. And the water quality distribution is closely related with the current structure characteristics as well as the tidal residual current system.

• Current Optics and Photonics
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• 제2권2호
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• pp.185-194
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• 2018

Ultra-small optical anisotropy of a rubbed polyimide (PI) alignment layer is quantitatively characterized using the improved reflection ellipsometer. Twisted nematic (TN) cells are fabricated using the rubbed PIs of known surface anisotropy as alignment layers. Distribution of liquid crystal (LC) molecules in the TN cell is characterized using transmission ellipsometry. The retardation of the rubbed PI surface increases as rubbing strength increases. The tilt angle of the optic axis of the rubbed PI surface decreases as rubbing strength especially as the angular speed of the rubbing roller increases. Pretilt angle of LC molecules in the TN cell shows strong correlation with tilt angle of the optic axis of the rubbed PI surface. Both the apparent order parameter and the effective twist angle of the LC molecules in the TN cell decrease as the pretilt angle of LC molecules increases.

• 한국표면공학회지
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• 제51권3호
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• pp.164-171
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• 2018

In this study, we have fabricated pure titanium (Ti)/hydroxyapatite (HA) double layer coating on medical grade PEEK from magnetron sputtering system, an investigation was performed whether the surface can be had more improve bio-active for orthopedi/dental applications than that of non-coated one. Pure Ti and HA coating layer were obtained by a radio-frequency and direct current power magnetron sputtering system. The microstructures surface, mechanical properties and wettability of the pure Ti/HA double layer deposited on the PEEK were analyzed by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), nano-indentation, and contact angle test. According to the EDS and XRD results, the composition and crystal structure of pure Ti and HA coated surface were verified. The elastic modulus and hardness value were increased by pure Ti and HA coating, and the pure Ti/HA double layer coating surface has the highest value. The contact angle showed higher value for pure Ti/HA double layered coating specimens than that of non-coated (PEEK) surface.