• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 봄 학술발표회 논문집
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• pp.238-242
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• 1994

Recently, construction of mass concrete structures except Dam are increased very often. Generation heat due to the hydrating reaction of mass concrete is generally larger than the heat released to the air, foundations and the exist structures. Therefore, internal temperature of mass concrete is remarkably risen and temperature gap between center and surface is extended by various effect. It this gap get large, the crack may be occurred. This crack must be controlled as little as possible to ensure the soundness and durability of structure. Firstly, Temperature rising history of Mass concrete is expected correctly to constrain the crack of mass concrete. So, objectives of this research is to quantify the effects of hydration temperature for the purpose of evaluating accurately the temperature history of mass concrete.

• 한국세라믹학회지
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• 제13권3호
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• pp.37-42
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• 1976

Although the water mixed into the concrete plays the role of hydration and acquiring the necessary workability, the more portion of water acts to obtain the substantial workability rather than to complete the hydration. However, the excess amount of water causes the poor quality of concrete, therefore it is useful to add the minimum amount of water as required as to acquire the proper workability. There have been the considerable numbers of investigations in which the dispersion phenomena of strong eletrolytic high polymer compounds such as lignosulfate and some of surface activation agents were studied to utilize as the dispersion agent of concrete. In the present study, Na-lignate, dispersion properties of which has not been studied yet, were investigated with the purpose of utilizing as a dispersion agent of concrete. The microscopic observations showed a great improvement in the dispersion of cement particles, also the fluidity and compressive strength of concrete were remarkably increased with the addition of Na-lignate: The addition of Na-lignate by 0.02% showed the increase of 1.76 times and 1.27 times of slump value and flow value respectively, and the compressive strength was increased by 1.07 times.

• Applied Microscopy
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• 제44권2호
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• pp.53-60
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• 2014

In the present study, we investigated the effects of Polygonum tinctoria Niram (PTN) on atopic dermatitis (AD) in BALB/c mice induced by 2,4-dinitrochlorobenzene (DNCB). They were divided into four groups; Control, DNCB, DNCB+1%PTN (1% PTN extract) and DNCB+5%PTN (5% PTN extract), for evaluating the change of appearance of skin surface, skin hydration, thickness of epidermis and mast cell numbers during 4 weeks. PTN suppressed symptoms of AD in appearance of skin and increased skin hydration for DNCB+1%PTN and DNCB+5%PTN. Treatment with PTN significantly decreased the levels of eosinophils. In histopathological examination, DNCB+1%PTN and DNCB+5%PTN significantly reduced the thickness of epidermis and number of mast cell in dermis. These results suggested that the PTN improved symptoms of AD in BALB/c mice.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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• pp.263-267
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• 1995

The usual methods for the temperature control of mass-concrete structures include the use of low-heat cement, pre-cooling, post-cooling, or sheet curing. In order to control the heat of hydration during the construction of mass-concrete structures, the combination of the above methods is commonly employed. For the construction of mass-concrete structures such as massive pier or anchor, it is necessary to control the curing temperature with pipe cooling. In this study, the method of analysis on the effect of pipe of was proposed to prevent the thermal cracking due to heat of hydration In addition the effect of covering the concrete surface with blanket insulation was investigated. The results of the present study may be useful for the prediction of curing temperature of mass-concrete structures and the reasonable construction management.

• 한국응용과학기술학회지
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• 제27권2호
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• pp.175-182
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• 2010

Various research on the surface of the skin and the relationship between epidermis and composition of ion have been performed. Traditionally, bamboo extract was used as an important material for enhancing healthy condition of a skin. Bamboo salt is well known as one of the most famous traditional medical treatments. In this study, we investigated the stability of P/S (Polyol-in-Silicone) emulsions containing a fair amount of bamboo salt in the range of 0.5~5.0 wt%. For improving the stability of emulsions, we varied the quantity of fatty alcohol and wax ester in emulsions and the stability was checked using DSC (Differential Scanning Calorimeter). We also studied the efficacy of treating the P/S emulsions containing bamboo salt. From the experiment, the emulsions show the mitigation of stimuli, enhancing the skin hydration and improving the appearance of the skin.

• Bulletin of the Korean Chemical Society
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• 제22권3호
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• pp.281-287
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• 2001

Self-assembled monolayers (SAMs) of the alkylthiols with [Os(bpy)3]2+ moiety at the terminal position were prepared on gold electrode surface. Examination of the cyclic voltammograms for the SAM shows that it does not organiz e well unlike alkylthiols, which is attributed to the much larger diameter of [Os(bpy)3]2+ moiety compared with the cross-section of alkyl chains and the distance between the adsorption sites. Electromicrogravimetry study shows that the hydration numbers of the electrolyte were 16 $\pm2$, 11 $\pm1$, 5 $\pm$ 1 and 24 $\pm6$ for ClO4- , PF6-, NO3- , and SO42- , respectively. The binary SAMs of alkylthiols with [Os(bpy)3]2+ terminal-group were prepared by co-adsorption of alkylthiols as spacer molecules, which results in better packing in SAM and accordingly the stability was enhanced.

• 한국세라믹학회지
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• 제34권2호
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• pp.163-170
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• 1997

대표적인 무기계 지연제인 규불하마그네슘(MgSiF6.6H2O)을 시멘트 수화반응시 첨가했을 때의 수화반응의 지연 효과 및 특성과 수용액 이온농도 변화 고찰하기 위하여 규불화마그네슘을 시멘트 질랴의 0.3wt%에서 5wt%까지 변화시키면서 그 영향을 연구 검토하였다. 시멘트 모르타르의 flow는 지연제의 첨가에 따라 감소하는 경향이 있으며 응결 시간은 지연제의 첨가량에 따라 지연되었다. 모르타르의 압축 강도는 지연제의 첨가량에 따라 3일, 7일까지는 지연제를 첨가하지 않은 plain mortar에 비하여 약간 낮은 강도를 나타내나, 시간이 지남에 따라 회복되어 28일이 지나면 plain 모르타르와 같은 강도를 나타낸다. 규불화마그네슘이 첨가되면 수화 초기 단계에서 시멘트로부터 용출된 알카리 이온과 반응하여 K2SiF6의 생성이 일어나며 그와 동시에 Ca++와 F++와의 반응에 따라 CaF2화합물이 생성됨을 확인하였다. 이때 생성된 K2SiF6 및 CaF2생성물의 비표면적은 대단히 컸으며 이들 물질이 수화반응 초기에 미수화 시멘트시 입자 표면에 생성되어 시멘트의 수화가 지연되는 것으로 검토된다. 또한 수화초기의 수화용액의 Ca++ 및 K+이온 농도의 저하 역시 포틀랜드 수화반응속도를 지연시켜 주는 이유가된다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문발표회
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• pp.7-11
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• 2003

This study investigate the hydration heat history with variation of surface insulating material in cold weather concreting. According to the results, the temperature of concrete lowers below zero in 24hours, so early frost damage occurs in the case of exposure and 1 fold bubble sheet, but the lowest temperature keeps above zero, so a adiabatic effect is very favorable in the case of double bubble sheet and 부직포. Compressive strength of core specimen at 7 and 28 days is highest In the case of double bubble sheet and 부직포. But, considering convenience of construction and economical efficiency, it is thought that the most effective surface insulating material is 1 fold bubble sheet +blanket.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.677-680
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• 2008

저발열형 고로슬래그 시멘트의 초기강도 발현 특성을 향상시키기 위하여 낮은 분말도의 고로슬래그 분말과 보통 포틀랜드시멘트를 혼합 분쇄하여 입자 표면을 개질하였다. 사전 분쇄한 고로슬래그 분말의 비표면적은 $2535cm^2/g$(BS2), $3245cm^2/g$(BS3)의 2가지를 사용하였으며, 고로슬래그 분말과 시멘트를 진동밀에 투입하여 10분부터 30분까지 혼합 분쇄하여 표면을 개질하였다. 시멘트에 대한 고로슬래그 분말의 혼합비는 60$^{\sim}$80%의 3수준으로 변화시켰으며 혼합분쇄 후 비표면적의 변화, 입도분표, 시멘트의 수화열, 몰탈의 압축강도를 측정하였다. 시판 삼성분계 저발열 시멘트(LHC)와 비교시험 결과, 7일 압축강도발현의 100%이상과 72시간 누적수화열 170J/g 이하의 값을 만족하는 배합 및 혼합분쇄 시간을 찾을 수 있었으며 저분말도 고로슬래그를 다량으로 활용한 저발열 슬래그시멘트의 가능성을 확인하였다.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2005년도 춘계 학술발표회 논문집
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• pp.448-455
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• 2005

In this paper, an analytical model for estimation of the time at which the concrete surface begins to dry is introduced to predict whether or not plastic shrinkage cracks occur. First of all, the validity of a consolidation model for bleeding of cement paste proposed by Tan et al. is verified by comparing the analytical results with the experimental results, and used to evaluate the rate and amount of bleed water of concrete. Also an analytical model for evaporation of bleed water which considers the effect of the temperature variation of concrete surface due to hydration heat on the evaporation rate is proposed, and the experimental and analytical results are then compared to verify the validity of the introduced model. In advance, the time at which the concrete surface begins to dry is estimated using above two analytical models, and compared with the experimental results about the time at which plastic shrinkage cracks occur. From the comparison, it is verified that the proposed model can predict the occurrence of plastic shrinkage cracking with comparative precision.