• Title/Summary/Keyword: Surface hydration

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Surface Modification of MgO Microcrystals by Cycles of Hydration-Dehydration

  • 김해진;강진;송미영;박선회;박동곤;권호진;남상성
    • Bulletin of the Korean Chemical Society
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    • v.20 no.7
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    • pp.786-790
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    • 1999
  • Relatively inert surface of microcrystalline MgO was modified into chemically active one by carrying out controlled hydration followed by dehydration at elevated temperature under dynamic vacuum. Even though the treatment by the first cycle of hydration-dehydration did not alter the porosity of MgO, it largely enhanced surface reactivity of the MgO toward adsorbed water, turning its outer layer into brucite upon rehydration. Treatment by the second cycle of hydration-dehydration generated micropores, and slit-shaped mesopores, raising the porosity of the MgO. The overlayer of Fe2O3 of the core/shell type composite magnesium oxide enhanced this surface modification, turning its surface into more porous and more active one than that of uncoated MgO, after the treatment by the hydration-dehydration.

Skin Hydration Status and Skin Surface pH According to the Body Parts of the Aged with Immobilization (기동장애 노인의 신체 부위별 피부수분 상태와 피부표면 산성도)

  • Han, Ae-Kyung;Won, Jong-Soon;Kim, Ok-Soo
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.17 no.3
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    • pp.314-323
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    • 2010
  • Purpose: This study was performed to identify skin hydration status and skin surface pH according to the body parts of the aged with immobilization. Methods: The subjects were 101 aged patients in a hospital and a institution for the elderly in Seoul. Data for skin hydration and skin surface pH were collected using corneo-meter and skin pH-meter. The body parts of measurement were 10 parts; face, forearm, back of the hand, flank, upper abdomen, leg, back of the foot, heel, scapular, and sacrum. The data were analyzed by SPSS/WIN 12.0 program. Results: Skin hydration status were relatively low especially on lower extremity and back of body, and skin surface pH of scapular and sacrum were high. There was significant negative correlation between skin hydration status and skin surface pH on the 6 body parts. Conclusion: Skin hydration status and skin surface pH, especially on scapular, sacrum, and lower extremity need to be considered as important control factors for increasing skin health status of the aged with immobilization.

Field Application of a Technique for Reducing Hydration Heat-induced Cracks in Mass Concrete (수화발열량차 공법을 이용한 매트기초 매스콘크리트 균열저감 및 현장적용)

  • Jo, Man-Ki;Kim, Jun-Ho;Heo, Young-Sun;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.55-57
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    • 2012
  • In this study, the field applicability on reducing the heat of hydration of mass concrete by using the hydration heat difference method is analyzed with the following summary. As a result of applying the hydration heat difference method by using low heating combination, the temperature difference between the central part and the surface part of mass material was reduced, and as a result of visual observation, there was no showing of cracks by the hydration heat on the upper surface part. Therefore, the cracking index of the field to apply this method was shown to be approximately 1.57 with very little crack occurrence probability of less than 3%.

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Field Application of Mass Concrete Applying Hydration Heat Differential Method and Insulation Curing Method (수화발열량차 및 단열양생 공법을 활용한 매스콘크리트의 현장적용)

  • Han, Jun-Hui;Lim, Gun-Su;Shin, Se-Jun;Jeon, Choung-Keun;Kim, Jong;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.227-228
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    • 2023
  • This study is tocompare and analyze the results of hydration heat analysis and on-field measurements using the method with hydration heat difference and insulation curing method for controlling hydration heat in mass concrete. As a result of the analysis, the temperature difference between the center and the surface was predicted very similarly, and the mass concrete surface was controlled to a safe level when evaluating with a temperature crack index, and after being finished, it was confirmed that there was no hydration crack.

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The influences of film density on hydration of MgO protective layer in plasma display panel

  • Lee, Jung-Heon;Eun, Jae-Hwan;Park, Sun-Young;Kim, Soo-Gil;Kim, Hyeong-Joon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.228-231
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    • 2002
  • We report the effect of density of thin films on moisture adsorption and hydration of MgO thin film, usually used as a protective layer in AC-PDP After hydration, lots of hemispherical shaped clusters, $Mg(OH)_2$, formed on the surface of MgO thin films. However clusters formed on low-density thin films were bigger than those on high-density films. From ERD spectra, it seemed that the concentration of hydrogen was very high in the region 20 nm from the surface of MgO thin film. The low-density thin film had more hydrogen than high-density thin film. From simulation results of ERD and RBS it was found that hydration reaction also occurred in the inner part of the film. So diffusion of Mg atoms from the inner part of the film to the surface and $H_2O$ molecules from the surface to the inner part of the film is important. And because low density thin film has many short paths for diffusion of Mg atoms and $H_2O$ molecules, low-density thin film is more hydrated. So to suppress hydration of MgO thin films, high-density thin film is needed.

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Effect of Pretreatment on the Dissolution of Aluminum Alloy during Hydration Process (수화과정에서 전처리가 알루미늄 합금의 용출에 미치는 효과)

  • Lee, Byoung-Gu;Lee, Hoyeon;Tak, Yongsug
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.215-219
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    • 2013
  • Aluminum alloy(3003) can be dissolved during hydration process with hot tap water. In order to increase the stability of aluminum alloy, it was pretreated with anodization and phosphoric acid before hydration process. The effect of pretreatment on the surface property changes was analyzed with X-ray Photoelectron Spectroscopy (XPS) and Inductively Coupled Plasma-Optical Emission Spectrometer (ICP-OES) and their results supported that the increase of hydroxyl group (-OH) on the surface formed during anodization and phosphorous acid treatment prevented the dissolution of aluminum alloy during hydration process at high temperature.

Hydration Properties of Cement Matrix using Surface Treatment Blast Furnace Slag by Arc Discharge (아크방전에 의해 표면개질 된 고로슬래그를 사용한 시멘트 경화체의 수화 특성)

  • Kim, Sun-A;Kim, Hyeon-Sung;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.91-92
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    • 2018
  • A glassy thin film was formed on the surface of the blast furnace slag. When blast furnace slag is used as an admixture of concrete, addition of alkali activators were required. However, alkali activators are not only dangerous as chemical products, but they are also difficult to use as expensive materials. Therefore, it is necessary to study the way of removal of the glassy thin film of blast furnace slag without the risk and cost increase. In this study, to solve this problem, experiment was carried out to improve the hydration reactivity by treatment the surface of blast furnace slag using arc discharge. Experimental results show that when the surface of the blast furnace slag was tratmented by arc discharge, the glassy thin film was destroyed. And the hydration reactivity was improved, the compressive strength was increased.

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Mock-up Test on the Reduction of Hydration Heat of Mass Concrete for Transfer Girder (전이보 매스콘크리트의 수화열 저감에 관한 Mock-up 실험)

  • Yoon Seob;Hwang Yin Seong;Baik Byung Hoon;Han Cheon Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.707-710
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    • 2004
  • This paper reported the results of mock-up test on mass concrete for transfer girder using setting time difference of super retarding agent(SRA). According to test results, two mock-up structures were made. Plain concrete without placing layer reached maximum temperature after 24hours since placement and caused surface hydration cracks at top section. However, concrete with placing layer reached maximum temperature after 72hours and surface temperature was higher than center temperature, which did not cause surface crack. After form removing, no crack was observed at side surface of plain concrete, while concrete using SRA at mid section had surface scaling and settling crack. According to coring results, concrete with placing layer had a penetration crack from top section to bottom section. Therefore, the setting time difference method to reduce hydration heat will have difficulty in applying the mass concrete for transfer girder.

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The simulation of hydration of Portland cement blended with chemical inert filler

  • Xiaoyong, Wang;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1041-1044
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    • 2008
  • The addition of chemical inert filler in blended cement, such as limestone or chemical inert silica fume, will produce a physical effect on cement hydration. Due to the high surface area of inert filler in the mixtures, it provides sites for the nucleation and growth of hydration products, thus improving the hydration rate of cement compounds and consequently increasing the strength at early age. This paper proposes a model of hydration of Portland cement blended with chemical inert filler. This model considers the influence of water to cement ratio, cement particle size, cement composition and addition of chemical inert filler on hydration. The heat evolution, degree of hydration and porosity are obtained as accompanied results in hydration process. The prediction results agree well with experiment results.

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Fouling Mechanism of Microfiltration/Ultrafiltration by Macromolecules and a Suppression Strategy from the Viewpoint of the Hydration Structure at the Membrane Surface

  • Akamatsu, Kazuki;Nagumo, Ryo;Nakao, Shin-ichi
    • Membrane Journal
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    • v.30 no.4
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    • pp.205-212
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    • 2020
  • This short review focuses on fouling by proteins and macromolecules in microfiltration/ultrafiltration. First, an experimental system that enables investigation of how the extent of the adsorption of proteins and macromolecules on membrane surfaces contributes to a decrease in filtrate flux in microfiltration/ultrafiltration is described. Using this system, a causal relationship - not a correlation - indicating that adsorption results in a decrease in filtrate flux could be clearly demonstrated in some cases. Second, a hydration structure at the membrane surface that can suppress adsorption is discussed, inspired by biomaterial research. In their hydrated states, polymers with low-fouling properties have water molecules with a particular structure. Finally, some successful examples of the development of low-fouling membranes via surface modification using low-fouling polymers are discussed.