• Title/Summary/Keyword: Surface diffusion

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Oxidation Mechanism of $Si_3N_4$ ($Si_3N_4$의 산화반응 기구)

  • 이홍림;최태운;김종우
    • Journal of the Korean Ceramic Society
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    • v.17 no.4
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    • pp.197-202
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    • 1980
  • The oxidation mechanism of the not sintered pellets and sintered bodies of $Si_3N_4$ was investigated. in air over the temperature range of 800~130$0^{\circ}C$. The $\beta$-cristobalite was instantaneously formed and covered the particles of powder packed in the not sintered and weakly sintered porous $Si_3N_4$ bodies by molecular diffusion of oxygen through the porous Si3N4 bodies and an immediate oxidation. The diffusion of oxygen ion through the formed $\beta$-cristobalite surface layer is assumed to control the further oxidation of the $Si_3N_4$ particles of the porous $Si_3N_4$ bodies. The diffusion coefficients and activation energies of oxygen ion through the $\beta$-cristobalite layer were obtained by the use of a derived equation.

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Effects of Additives and Atmospheres on the Grain Growth of TiO2 Ceramics (분위기와 첨가제가 TiO2 세라믹스의 입자성장에 미치는 영향)

  • 박정현;최헌진;박한수
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.390-398
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    • 1988
  • Effects of atmospheres and adidtives on the grain growth of TiO2 ceramics were investigated. In the range of 1300~140$0^{\circ}C$, grain growth was increased in CO2 as compared with O2 atmosphere and the grain boundary migration activation energy was lower than the diffusion activation energy of oxygen ion in TiO2. Also, in the case of addition of oxides, the grain growth was increased by oxides acting as a acceptor andinhibited by oxides acting as a donor. From the above results, when the oxygen vacancy concentration was increased, the intrinsic grain boundary mobility was increased and the pore drag force was decreased due to the rapid densification. Also it seems that the pore was migrated by the surface diffusion rather than lattice diffusion.

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Numerical Simulation of Deposition Chamber for Aerosol Nanoparticles Upward 300 mm Wafer (300 mm 웨이퍼 위의 에어로졸 나노 입자의 증착 장비 개발을 위한 수치 해석적 연구)

  • Ahn, Kang-Ho;Ahn, Jin-Hong;Lee, Kwan-Soo;Lim, Kwang-Ok;Kang, Yoon-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.1 s.10
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    • pp.49-53
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    • 2005
  • The nanoparticle deposition chamber, which is used for quantum dot semiconductor memory applications, is designed by means of numerical simulation. In this research, the numerical simulations for deposition chamber were performed by commercial software, FLUENT. The deposition of nanoparticles is calculated by diffusion force, thermophoresis and electrophoresis of particles. As a results, when the diffusion force was considered, the most of particles deposited in the wall of deposition chamber. But as considering thermophoresis and electrophoresis of particles, the particles were deposited wafer surface, perfectly.

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Mechanical Property of Liquid Phase Diffusion Bonded Joint of Rene80/B/Rene80 (Rene 80/B/Rene 80 액상 확산접합부의 기계적 성질)

  • 정재필;강춘식
    • Journal of Welding and Joining
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    • v.13 no.3
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    • pp.125-133
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    • 1995
  • Rene80 superalloy was liquid phase diffusion bonded by using pure boron (B) as an insert material. As a basic study for the possibility of practical application of this bonding method, hardness and high temperature tensile strength of the bonded joint and metallurgical analysis were investigated. As experimental results, hardness of the bonded joint was homogenized after bonding and the tensile strength at 1144K was obtained to 90% of that of base metal. But there were some problems to be improved also, that means the joint was hardened after bonding due to increase of B content and elongation was much lower than that of base metal. Flat area and (Mo, Cr, W) boride, which should be harmful for bonding strength, were observed on the fractured surface of the tensile tested specimen.

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Study on Diffusion Bonding of Stainless Steel to Mild Steel (연강-스테인리스강의 확산접합에 관한 연구)

  • Kim, S.T.
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.1
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    • pp.17-26
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    • 1998
  • Cladding of stainless steel on mild steel was prepared by diffusion bonding process. The bond strength increased with an increase of bonding temperature and time. It was also found that the bond strength increased as the surface roughness decreased. After the diffusion bonding of stainless steel-mild steel, the mild steel part near the bonded interface showed higher strength than the base steel due to the migration of chromium and nickel from stainless steel to mild steel. Carbon migration from mild steel gave effect on the formation of chromium carbides at grain boundaries of stainless steel, the fractograpohic features of the imperfectly bonded interface showed rather coarse dimples in the mild steel part and very fine dimples in the stainless steel part.

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Analysis of Stratified Lake using an Eddy Diffusion and a Mixed-layer Models

  • Kim, Kyung-sub
    • Korean Journal of Hydrosciences
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    • v.8
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    • pp.111-123
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    • 1997
  • A one-dimensional eddy diffusion model and a mixed-layer model are developed and applied to simulate the vertical temperature profiles in lakes. Also the running result of each method are compared and analyzed. In an eddy diffusion model, molecular diffusivity is neglected and eddy diffusivity which does not need lake-specific fitting parameter and constant lake's level are applied. The heat exchanges at the water surface and the bottom are formulated by the energy balance and zero energy gradient, respectively. In a mixed-layer model, two layers approach which has a constant thickness is adopted. The application of these models which use explicit finite difference and Runge-Kutta methods respectively demonstrates that the models simulate water temperatures efficiently.

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A Study on Surface Case Hardening of Blend Heat Treated Mild Steel (복합열처리(複合熱處理)한 연강(軟鋼)의 표면경화(表面硬化)에 관한 연구)

  • Chung, In-Sang;Chon, Hae-Dong;Sin, Soug-Mok
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.1
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    • pp.23-31
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    • 1992
  • It is investigated that Fe-C-N compound layer, defusion layer, and induction hardened layer produced by nitrocarburizing blend heat treatment in austenitic temperature with high frequency induction heating of mild steel specimen sprayed sursulf salt-bath. As the temperature of blend-heat treatment got increased, the thickness and hardness of compound layer and diffusion layer were increased. Compound layer(max. $35{\mu}m$), diffusion layer (max. 2.5mm) and induction hardened layer were gained in the shortest time 10 sec and in the case of $1000^{\circ}C$ total hardness depth of those was about 3.5mm. When the blend-heat treated specimen was reheated, maximum hardness of compound layer was dropped more than that of the reheated compound layer after sursulf treated, whereas hardness of diffusion layer was increased.

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Synthesis and Characterization of Zeolite Composite Membranes (II): Synthesis and $CO_2$ Separation Efficiency of ZSM-5 Zeolite Composite Membranes (제올라이트 복합 분리막의 합성 및 특성화(II): ZSM-5 제올라이트 복합막의 합성 및 $CO_2$ 분리 효율)

  • 현상훈;송재권;김준학
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.747-757
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    • 1997
  • ZSM-5 zeolite composite membranes have been synthesized from a silica sol solution containing TPABr as an organic template by the dip-coating and the pressurized-coating hydrothermal treatment techniques. The CO2 separation efficiency of synthesized composite membranes was also investigated. The permeation mechanism of CO2 through ZSM-5 membranses was the surface diffusion, and that of N2, O2, and He gases was Knudsen diffusion or activated diffusion depending on the synthetic method of membranes and the measurement temperature. The CO2/N2 separation factor of the membrane prepared by the dip-coating hydrothermal treatment was 2.5 at about 12$0^{\circ}C$, while the ZSM-5 composite membrane synthesized by the pressurized-coating hydrothermal treatment technique showed the CO2/N2 separation factor of 9.0 at room temperature higher than that ever reported in the literature.

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Analysis of Pumping Performance of a Helical Drag Pump Using the Diffusion Equation (확산방정식을 이용한 헬리컬 드래그펌프의 성능해석)

  • Heo, Joong-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.5
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    • pp.382-391
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    • 2008
  • A simple analytical model of rarefied channel flow is developed to predict the compression ratio in a helical drag pump. If the surface velocity is zero, the model reduces to a capillary leaks. Predictions of our model agree well with the Knudsen's data for capillary leaks in transition flow, in addition to giving a good account of the Knudsen minimum. Also, the present results are compared with experimental data, and good agreement is obtained over the entire pressure range from molecular to slip flow.

The Effects of Tin in Bottom Surface to Ion Exchange of Float Glasses (Float 판유리에 있어서 바닥면의 Tin성분이 이온교환에 미치는 영향)

  • 이동인;이용근;이희수
    • Journal of the Korean Ceramic Society
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    • v.27 no.6
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    • pp.763-768
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    • 1990
  • The gradient and depth of tin at the side of glasses by float process were measured. The effects of tin to ion exchanged of glasses in the molten salt of KNO3 and AgNO3 were presented by means of Ag+ ion penetration depth, diffusion coefficient variation, spectral transmittance and color coordinates. The diffusion coefficient of Ag+ ion of tin side was higher than air side, and the activation energy of tin side was 0.2-0.6Kcal/mole lower than air side. Therefore Ag+ ion penetration depth of tin side is 2-10$\mu\textrm{m}$ deeper, hence it can be seen that tin promote Ag+ ion diffusion. The same treatment of ion exchange, reddish-brown oflong wavelength in case of tin present, yellowish-amber of short wavelength in case of tin absence were revealed.

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