• Advances in materials Research
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• v.1 no.3
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• pp.233-243
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• 2012

Thermal reactive diffusion coating of vanadium carbide on DIN 2714 steel substrate was performed in a molten borax bath at $950-1050^{\circ}C$. The coating formed on the surface of the substrate had uniform thickness ($1-12{\mu}m$) all over the surface and the coating layer was hard (2430-2700 HV), dense, smooth and compact. The influence of the kinetics parameters, temperature and time, has been investigated. Vanadium carbide coating was characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX) and X-ray diffraction analysis (XRD). The corrosion resistance of the coating was evaluated by potentiodynamic polarization in 3.5% NaCl solution. The results obtained showed that decrease of coating microhardness following increasing time and temperature is owing to the coarsening of carbides and coating grain size.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.721-726
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• 2003

The Durability of Concrete Structure is serverely degraded due to mainly carbonation, sulfate attack and chloride ion diffusion in concrete. The ultimate purpose of this study is to obtain how much the durability of Concrete Structure is improved according to the variation of physical properties in concrete or the frequency of surface coating on concrete. Where, variation of physical properties is a water-cement ratio or amount of air. The experiments are the chliride ion diffusion test, the lapid corrosion test, the lapid carbonation test, the test on resistance to freezing and thawing. Finally, this study shows that the effect by the surface coating method is better than the variation of physical properties in concrete.

• Journal of environmental and Sanitary engineering
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• v.11 no.3
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• pp.29-35
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• 1996

Numerical solutions were obtained to the model equations for various parameters characterizing the pore structure, effective internal diffusion and the chemical reaction constant. The conversion was decreased with the cause of pore closure at the surface of reacting particles, reduction of porosity, surface area of reaction and effective diffusion coefficient in the solid with the progress of reaction. Total conversion was strongly depend on the local conversion at surface. According to the decreasing of impregnated concentration of the copper oxide and the increase of the flue gases concentration, total conversion was increased. And the conversion were affected by gas flow rate and pore size distribution of the reacting solid.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.1
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• pp.61-69
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• 1998

Vapor Axial Deposition (VAD), one of optical fiber preform fabrication processes, is performed by deposition of submicron-size silica particles that are synthesized by combustion of raw chemical materials. In this study, flow field is assumed to be a forced uniform flow perpendicularly impinging on a rotating disk. Similarity solutions obtained in our previous study are utilized to solve the particle transport equation. The particles are approximated to be in a polydisperse state that satisfies a lognormal size distribution. A moment model is used in order to predict distributions of particle number density and size simultaneously. Deposition of the particles on the disk is examined considering convection, Brownian diffusion, thermophoresis, and coagulation with variations of the forced flow velocity and the disk rotating velocity. The deposition rate and the efficiency directly increase as the flow velocity increases, resulting from that the increase of the forced flow velocity causes thinner thermal and diffusion boundary layer thicknesses and thus causes the increase of thermophoretic drift and Brownian diffusion of the particles toward the disk. However, the increase of the disk rotating speed does not result in the direct increase of the deposition rate and the deposition efficiency. Slower flow velocity causes extension of the time scale for coagulation and thus yields larger mean particle size and its geometric standard deviation at the deposition surface. In the case of coagulation starting farther from the deposition surface, coagulation effects increases, resulting in the increase of the particle size and the decrease of the deposition rate at the surface.

• Journal of the Korea Concrete Institute
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• v.15 no.4
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• pp.522-528
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• 2003

Concrete has been considered as a semi-permanent structural material, because its excellent durability. However, such high durable structure is often attacked by some environmental condition such as chloride diffusion, carbonation and so on. In order to prevent the deterioration behaviors of concrete structures. We estimated durability of concrete when used surface treatment system and coatings by new type inorganic coating materials. Base on the results of chloride ion's diffusion test, the coated cement mortar had smaller transmitted quantity.

• Journal of Ocean Engineering and Technology
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• v.21 no.6
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• pp.87-94
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• 2007

This study used POM (Princeton ocean model) improved for applying to coastal area in order to predict the distribution of thermal waste water. This model was applied to the coastal circulation and the effect of thermal waste water of Cheonsu-Bay. So this study compared the discharge of thermal waste water with each layer and section. The tidal current was about 1.5 m/sec at surface level and 0.9 m/sec on bottom level at flood tide; tidal current was about 1.3 m/sec on surface level and 0.8 m/sec on bottom level at ebb tide. The method discharging the thermal waste water in the nearshore region (case 1) accelerates the diffusion of the thermal waste water in the north-south direction(longshore direction). However, the method discharge the thermal waster water in the offshore region (case 2) reduced the diffusion of the thermal waste water over the coastal region. According th the diffusion region of the thermal waste water with case 1 and case 2 at three different layers (surface, middle, bottom), the diffusion region by case 1 discharge method generally influenced wider region (twice) than the one by case 2 discharge method with lower temperature between $1^{\circ}C\;and\;2^{\circ}C$, whereas the case 2 discharge method influenced the deeper region (middle and botton layers) with higher change of the water temperature ($1{\sim}3^{\circ}C$).

• Journal of the Society of Naval Architects of Korea
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• v.34 no.2
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• pp.104-110
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• 1997

Increase of marine transpotation in coastal area frequently yields oil spill accidents due to collision or grounding of oil tankers, which affects great deal of damages on ocean environments. Exact prediction of oil pollution area in time domain, which is called oil map, is very important for effective and efficient oil recovery and minimization of environmental damage. The prediction is carried out by considering the two distinct processes which are initial diffusion on the still water surface and advection due to tide, wind wave induced surface currents. In the present paper, only the initial diffusion is dealt with. Somewhat new simulation model and its numerical scheme are proposed to predict it. Simple diffusion experiment is also carried out to check the validity of the present method. Furthermore, some example simulations are performed for virtual oil spill accident. Quite realistic oil map including oil thickness distributions can be obtained by the present model.

• Journal of the Korean institute of surface engineering
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• v.31 no.1
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• pp.54-62
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• 1998

In this study, the behaviorof ion nitriding of AISI 304 stainless steel was investigated using plasma ion nitriding system. The characteristics of ion nitriding, and their micsoctrucyures, and physical properties were investigated as a function of process parmeteds. important conclusions can be summarzied as follows. Firstly, it was found that growth of nitride layer in ion nitriding are mainly affected by N2 partial pressures and nitriding temperatures for AISI 304 stainless steel. The $N_2$<\TEX> partial pressure plays on important role in ion nitriding since it determiness the incoming flux of nitrogen species onto specimen surface. Nitriding thmprrature is also important besauseit determines the diffusion rates of nitrogen through nitride layers. While both parameters affects the characteristics rateding are controlled by nitridingen diffusion nitration profiles of N and alloying elements such as Cr and Ni are observed through niride layers. Secondly, nitride layer consists of the upper white laywe having various nitride phases and the underneath diffusion layers. The thickness of white layer increases with $N_2$<\TEX> partial pressures and nitriding temperatures. The thinkness of diffusion layer is increasting nitriding temperatures. Finally, nitriding of stainless steels steel show slighly low their corrsionce prorerties. However, passivation properties, which is normally observed in stainless steels, were still observed aftre ion nitriding.

• Membrane Journal
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• v.14 no.1
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• pp.75-84
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• 2004

In this study, we present a noble study far membrane transport models using chlorine resistance of polyamide RO membranes. Membrane transport mechanism is investigated by the comparison of membrane permeation performance under the continuous and Intermittent operation modes with mixed feed solution containing NaOCl and NaCl. Analysis of permeation performance indicates that solution-diffusion model and preferential adsorption-capillary flow model are relatively efficient according to operation mode. Under the continuous flow state, mass transfer depends on preferential adsorption-capillary flow model rather than solution-diffusion model. On the other hand, it prefers solution-diffusion model to preferential adsorption-capillary flow model under the stationary state. SEM images of NaOCl treated membrane surfaces strongly support these conclusions. These surface images reveal that NaOCl treated membrane in continuous operation mode exhibits ridge and valley structure in some fraction of the surface area, whereas that in intermittent operation mode shows surface degradation entirely.

• Journal of Korean Vacuum Science & Technology
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• v.4 no.3
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• pp.73-77
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• 2000

Single crystal and polycrystalline Si thin films were doped with phosphorus by a 2-zone diffusion method to develop the low-resistivity polycrystalline Si electrode for a hemispherical grain. Solid phosphorus source was used in order to achieve uniformly and highly doped surface region of polycrystalline Si films having rough surface morphology. In case of 2-zone diffusion method, it is proved that the heavy doping near the surface area can be achieved even at a relatively low temperature. SIMS analysis revealed that phosphorus doping concentration in case of using solid P as a doping source was about 50 times as that of phosphine source at 750$^{\circ}C$. Also, ASR analysis revealed that the carrier concentration was about 50 times as that of phosphine. In order to evaluate the electrical characteristics of doped polycrystalline Si films for semiconductor devices, MOS capacitors were fabricated to measure capacitance of polycrystalline Si films. In ${\pm}$2 V measuring condition, Si films, doped with solid source, have 8% higher $C_{min}$ than that of unadditional doped Si films and 3% higher $C_{min}$ than that of Si films doped with $PH_3$ source. The leakage current of these films was a few fA/${\mu}m^2$. As a result, a 2-zone diffusion method is suggested as an effective method to achieve highly doped polycrystalline Si films even at low temperature.