• Journal of the Korean Electrochemical Society
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• v.8 no.2
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• pp.106-114
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• 2005

This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.18 no.6
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• pp.598-605
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• 2008

An improved beamforming method is proposed to measure the surface impedance of absorbing materials in a free field. It is possible to estimate the surface impedance by decomposing measured signals into incident and reflected signals by using the spatial filter matrix of the beamforming method. Wavelet do-noising techniques which reduce the white Gaussian noise are applied to improve the results. Phase calibration method is also used to improve the results of the measured surface impedance in a low frequency range. The results of the normal incidence experiments that are performed in a semi-anechoic chamber are verified by comparing with those of the standard test method that is presented in ASTM E1050. The proposed method is found to be reliable to measure the surface impedance for frequencies higher than 400 Hz.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2002.04a
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• pp.395-400
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• 2002

Epoxy coating and sealing used in nuclear plants for the protection of radiation degrades with aging and hazardous atmosphere. In order to evaluate the degradation of the epoxy, dependence of the acoustic impedance on the change of mechanical properties has been used. Unlike metals, the surface of the epoxy coating on a concrete liner is so wavy that the acoustic impedance is difficult to measure by using the reflectivity of the ultrasound on the interface surface because of the irregular reflection and propagation from the epoxy surface. SA(simulated annealing) algorithm is applied to calculate the acoustic impedance using a reflection wave from the rough epoxy surface. The surface waviness and acoustic impedance are taken into account and determined by SA method to evaluate the state of degradation quantitatively.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1744-1746
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• 1996

Surface impedance boundary condition(SIBC) concepts are introduced into the finite-difference time-domain(FDTD) method. Lossy conductors are replaced by surface impedance boundary computations reducing the soluton space and producing significant computational savings. Specifically, a surface impedance boundary condition is developed to reduce a lossy dielectric half-space. Since Maxwell's eqations are solved directly, the reflected and transmitted pulse amplitude demonstrate how the reflection and transmision coefficient determine reflected wave amplitude. In this paper, two implementations of reflection coefficient are presented. One implementation is a standard FDTD technique and the other is a FDTD using surface impedence boundary condition(FDTD-SIBC) that are applicabIe over a very large frequency bandwidth. Particulary, an efficient way to transform the time domain results to frequency domain is presented. Thus, frequency domain results are presented in one dimension and are compared with exact results.

• Journal of KSNVE
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• v.6 no.2
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• pp.225-231
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• 1996

A free field method using two microphones is used for measuring surface impedance and absorption coefficient of the absorbent materials. It is shown that this method can be performed in a large non-anechoic room. Precise values of the surface impedance can be obtained by changing the spaces between the two microphones. Comparison between experimental values of the surface impedance of the glass wool and the mineral wool and Miki's empirical model shows agreement.

• Journal of the Korean Electrochemical Society
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• v.11 no.3
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• pp.147-153
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• 2008

Improvement of the selectivity of nonenzymatic glucose based on mesoporous platinum ($H_1$-ePt) by using A.C. impedance is reported. The idea of the present work is based on the novel effect of the mesoporous electrode that the apparent exchange current due to glucose oxidation remarkably grows although the reaction kinetics on the surface is still sluggish. It is expected that the enlarged apparent exchange current on the mesoporous electrode can raise the sensitivity of admittance in A.C. impedance to glucose concentration. At a low frequency, A.C. impedance could become more powerful. The admittance at 0.01 Hz is even more sensitive to glucose than to ascorbic acid while amperometry exhibits the inverse order of sensitivity. This is the unique behavior that is neither observed by A.C. impedance on flat platinum electrode nor obtained by amperometry. The study shows how the combination of A.C. impedance and nano-structured surface can be applied to the detection of sluggish reaction such as electrochemical oxidation of glucose.

• The Journal of the Acoustical Society of Korea
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• v.18 no.1E
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• pp.20-26
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• 1999

Although the radiation impedance of a transducer with a regular square surface has been studied by many researchers, the formulas are still very complicated, which results in long computation time and low accuracy. In this paper, we propose a new algorithm for the calculation of acoustic radiation impedance in which the regular square vibrating surface of a transducer is divided into small elements and duplicate calculations are eliminated in the process of calculating mutual effects of the elements. Using this algorithm, shorter computation time and higher accuracy of results can be obtained. As a demonstration, the self and the mutual radiation impedance of transducers with a regular square surface are calculated and the accuracy of the results is evaluated.

• Applied Chemistry for Engineering
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• v.34 no.1
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• pp.9-14
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• 2023

In this work, we developed a Nafion polymer-coated impedance sensor with two gold electrode configurations to measure the ion concentration in solution samples. The gold electrodes were fabricated through the sputtering process, followed by surface modification using Nafion polymer. The resulting sensors enable the prevention of the polarization phenomenon on the electrode surface, resulting in stable measurement of electrochemical signals. Spectroscopy and scanning electron microscopy measurements revealed that the thin film of Nafion was coated uniformly onto the surface of the gold electrode. The Nafion-coated sensor exhibited more stable impedance signals than the conventional gold electrode. It showed a highly reliable calibration curve (R² = 0.983) of the impedance sensor using a standard sodium chloride solution. In addition, a comparison experiment between the impedance sensor and a commercial conductivity sensor was performed to measure the ion concentration of artificial tears, showing similar results for the two sensors.

• The Journal of the Acoustical Society of Korea
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• v.36 no.2
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• pp.108-114
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• 2017

We have experimentally analyzed the self-radiation impedance of an ultrasonic transducer with a square radiation surface that is used as a vibrator in underwater ultrasonic detection systems. The radiation reactance and the radiation resistance were measured in the range from 1 to 3 of ka that is the product of a wave number and a length of the edge of the square vibrator. By comparing the measured results with those of theoretical calculation of the radiation impedance using a series, we confirmed the validity of the experimental method and experimentally confirmed the variation trend in the radiation impedance of the square radiation surface.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2670-2675
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• 2008

We introduce a new type of surface microscope using hydrodynamic phenomena. The fluid flow through the opening of the pipette probe is blocked at short distances between the probe and the surface, thus increasing the pressure loss. Therefore, a scanning flow impedance microscope (SFIM) can image the surface topology by scanning the probe with measuring the pressure loss. The SFIM can display the topology regardless of surface hardness, surface electrical conductivity, and surrounding fluid. The present letter contains the first experimental results on surface topography obtained with this novel microscope. The preliminary results in air demonstrate the lateral resolution of the SFIM is very close to the inner diameter of the probe.