• Bulletin of the Korean Chemical Society
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• v.32 no.6
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• pp.1993-1996
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• 2011

The vibronically well-resolved emission spectrum was recorded from the corona discharge of precursor 2,3,4-trifluorotoluene in a corona excited supersonic expansion with a pinhole-type glass nozzle using a long-path monochromator in the visible region. From the analysis of the observed spectrum, we found the evidence of the presence of the difluorobenzyl radicals in the corona discharge of the precursor. A possible mechanism is proposed for the formation of difluorobenzyl radicals in the gas phase on the basis of the observed emission intensity of the difluorobenzyl radicals produced.

• Journal of computational fluids engineering
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• v.10 no.1
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• pp.80-86
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• 2005

In order to control the transonic flow field with a shock wave, a condensing flow was produced by an expansion of moist air on a circular bump model and shock waves were occurred in the supersonic parts of the fields. Furthermore, the additional passive technique of shock-boundary layer interaction using the porous wall with a cavity underneath was adopted in this flow field. The effects of these methods on the shock wave characteristics were investigated numerically. The result showed that the flow fields might be effectively controlled by the suitable combination between non-equilibrium condensation and the position of porous wall.

• Journal of the Korean Society for Precision Engineering
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• v.23 no.10
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• pp.88-95
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• 2006

Cold gas dynamic spray is a relatively new coating process by which coatings can be produced without significant heating during the process. Cold-spray uses supersonic gas flow to carry metallic powders to the substrate. Its low process temperature can minimize thermal stress and also reduce the deformation of the substrate. Most researches on cold-spray have focused on micro scale coating, but in this study macro scale deposition was conducted. Properties of aluminum layer by cold-spray deposition such as coefficient of thermal expansion (CTE), modulus of elasticity. hardness, and electric conductivity were measured. The results showed that properties of aluminum layer by cold-spray deposition were different from properties of pure aluminum and aluminum alloy.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2751-2755
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• 2011

The visible vibronic emission spectrum was recorded from the corona discharge of precursor 1,2,3,4-tetramethylbenzene with a large amount of inert carrier gas helium using a pinhole-type glass nozzle coupled with corona excited supersonic expansion. The spectrum showed a series of vibronic bands in the $D_1{\rightarrow}D_0$ electronic transition of jet-cooled benzyl-type radicals formed from the precursor in a corona excitation. The analysis confirmed that two isomeric radicals, 2,3,4- and 2,3,6-trimethylbenzyl radicals, were produced as a result of removal of a hydrogen atom from the methyl group at different substitution positions. For each isomeric product, the electronic transition and a few vibrational mode frequencies were determined in the ground electronic state.

• Bulletin of the Korean Chemical Society
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• v.32 no.9
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• pp.3389-3394
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• 2011

Isomeric trimethylbenzyl radicals were generated and vibronically excited from precursor 1,2,3,5-tetramethylbenzene, isodurene, with a large amount inert carrier gas helium in a corona excited supersonic expansion (CESE) using a pinhole-type glass nozzle. A long-path monochromator was used to record the visible vibronic emission spectra of the jet-cooled benzyl-type radicals in the $D_1{\rightarrow}D_0$ electronic transition. From the analysis of the spectra, we identified the evidence of the presence of three isomeric trimethylbenzyl radicals in the corona discharge, and obtained the electronic energy and a few vibrational mode frequencies in the ground electronic state for each isomer.

• 한국전산유체공학회:학술대회논문집
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• 2003.10a
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• pp.187-188
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• 2003

In order to control the transonic flow field with shock wave, a condensing flow was produced by an expansion of moist air on a circular bump model and shock waves were occurred in the supersonic parts of the fields. Furthermore, the additional passive technique of shock - boundary layer interaction using the porous wall with a cavity underneath was adopted in this flow field. The effects of these methods on the shock wave characteristics were investigated numerically. The result showed that the flow fields might be effectively controlled by the suitable combination between non-equilibrium condensation and the position of porous wall.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2001.05a
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• pp.420-425
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• 2001

Theoretical analysis of noise reduction by a membrane-duct system is presented. When acorn waves propagate in the membrane-duct, the membrane is also excited and its motion is coup with interior medium. It has been shown that propagating waves with supersonic wave speed exist beyond a certain critical frequency that is determined from the mass ratio of the me and the fluid. Also found are subsonic waves which couple strongly wi th the membrane a provide a powerful mechanism of energy dissipation. Existence of an exterior medium alter dispersion characteristics. It provides additional mass loading and reduces the subsort speed further. The effect of mean flow speed on dispersion characteristics is also consider results show that the membrane-duct system can be applied to diminish and absorb 1 frequency noise in duct instead of passive muffler, such as a simple expansion chamber absorption material.

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2479-2482
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• 2010

Using a pinhole-type glass nozzle equipped for a corona-excited supersonic expansion (CESE), precursor 2,6-dichlorotoluene seeded in a large amount of inert carrier gas helium was discharged to produce jet-cooled but electronically excited benzyl-type radicals. The visible vibronic emission spectrum was recorded with a long-path monochromator to observe vibronic bands in the $D_1{\rightarrow}D_0$ electronic transition of benzyl-type radicals. The spectral analysis revealed the generation of not only the 2,6-dichlorobenzyl radical as a typical product, but also the o-chlorobenzyl radical as an unexpected species, which indicates the possible molecular rearrangement in eliminating a chlorine atom from the benzene ring. A possible mechanism is proposed for the formation of the o-chlorobenzyl radical from the precurs or in the gas phase.

• Journal of The Korean Astronomical Society
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• v.29 no.2
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• pp.93-105
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• 1996

We have solved the radiative transfer problem using a Sobolev approximation with an escape probability method in case of the supersonic expansion of a stellar envelope to an ambient medium. The radiation from the expanding envelope turns out to produce a P-Cygni type profile. In order to investigate the morphology of the theoretical P-Cygni type profile, we have treated $V_\infty,\;V_{sto},\;\beta$ (parameters for the velocity field), it and E(parameter for collisional effect) as model parameters. We have investigated that the velocity field and the mass loss rate affect the shapes of the P-Cygni type profiles most effectively. The secondarily important factors are $V_\infty,\;V_{sto}$. The collisional effect tends to make the total flux increased but not so much in magnitude. We have infered some physical parameters of 68 Cyg, HD24912, and $\xi$ persei such as $V_\infty,\;M$ from the model calculation, which shows a good agreenment with the observational results.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2783-2785
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• 2010

Searching for new molecular radicals which are believed to play an important role as reaction intermediates in aromatic chain reactions, we have applied the technique of corona excited supersonic expansion employing a pinhole-type glass nozzle to obtain the vibronic spectrum from the corona discharge of precursor 3,5-difluorotoluene with a large amount of inert carrier gas helium. An analysis of the observed spectrum revealed that many vibronic bands are from other isomeric difluorobenzyl radicals generated in the jet by migration of the fluorine atom or methylene group to the adjacent position in the 3,5-difluorobenzyl radical. A possible mechanism was proposed for the formation of other isomers by using a bridged cyclic intermediate structure.