• Clean Technology
• /
• v.14 no.4
• /
• pp.287-292
• /
• 2008

In this study, computer simulation works have been performed for the capture process of the $CO_2$ and $H_{2}S$ gases contained in the effluent stream using methanol aqueous solution. In order to increase the solubilities of the $CO_2$ and $H_{2}S$ in the methanol aqueous stream, the operating pressure of the absorber was raised to 30 bar and the feeding temperature of the solvent was lowered to $-20^{\circ}C$ by using refrigeration cycle. NRTL liquid activity coefficient model was used to estimate the liquid phase nonidealities for methanol and water. Soave-Redlich-Kwong equation of state was used for the vapor phase nonidealities. Henry's law option was also used to calculate the solubilities of the supercritical noncondensible gases into the methanol aqueous solvent stream.

• 한국생물공학회:학술대회논문집
• /
• 2000.04a
• /
• pp.516-519
• /
• 2000

Generally pancreas consist of lipid, water and protein, digestion enzyme complex (pro-tease, lipase, amylase). The sample used in this work was frozen dry and treated by a semi-batch flow type. In order to develop a supercritical fluid extraction process to rem-ove lipid from the pancreas, experiments were conducted at various operating conditions(pressure range $1500{\sim}2800psi$, temperature range $25{\sim}40^{cdot}C$, particle size$(0.25{\sim}1.0mm$, flow rate $20{\sim}80m{\ell}/min)$. Also cholesterol in the pancreas was removed. The highest extraction efficiency was 2500psi, $35^{\cdot}C$, 0.25mm of pancreas size. The enzyme activity of the pancreas produced from this work showed high value compared with imported pancreas.

• Journal of environmental and Sanitary engineering
• /
• v.20 no.4 s.58
• /
• pp.45-50
• /
• 2005

Titania gel formations were prepared by sol-gel method using titanium(IV) chloride $(TiCl_4)$, and its characteristics were analyzed by varying the $epoxide/TiCl_4$ ratio and the amount of water In the end, titania $(TiO_2)$ aerogel were prepared using supercritical drying process. VOCs such as benzene, toluene, and m-xylene (BTX) were oxidized using prepared titania aerogel and commercially available $TiO_2$, and its performance was compared. The surface area, pore volume, and average pore diameter of 1,2-epoxybutane are significantly smaller than the propylene oxide. And the titania aerogels with 6 moi of epoxides have high surface areas, pore volumes, and average pore diameters. As a result of photo-oxidation, conversion of benzene was reached about $70\%$, and other reactants were reached about $60\%$ similarly. The conversion of BTX was increased as inlet concentration decreased. The reactivity of titania calcined at $600^{\circ}C$ was greater than $400^{\circ}C$ and $800^{\circ}C$. Water is required as a reactants for the oxidation of VOCs, and the continuous consumption of hydroxyl radicals required replenishments to maintain catalyst activity. The activity ratio increased with increasing reaction time when enough amount of water was present in the reactor.

• Journal of Surface Science and Engineering
• /
• v.51 no.1
• /
• pp.40-46
• /
• 2018

The light-weight of the research and development materials is actively carried out by overseas automobile companies and technology development continues in Korea. For the sake of fuel efficiency, the development of lightweight technology by improving the manufacturing method has been very effective. Recently, to maximize the effects of light weight, automotive interior parts have been applied by the micro-cellular injection molding using supercritical fluids and we call the Mucell manufacturing. This technique causes a problem in the quality of the surface of the products, because the shooting cells are revealed as the surface layer of the products by forming micro cells at the center of the products during injection molding. To overcome these phenomenon, we increased the temperature of injection molding using joule heating until critical value. In this study, we have predicted the problem of Mucell injection molding through the finite element analysis as changed the temperature by joule heating. From the result of finite element analysis, we have determined the optimized process and made the injection mold included electric current heating system with Mucell manufacturing analyzed the surface characteristics of the injection product according to changing mold temperature.

• The Bulletin of The Korean Astronomical Society
• /
• v.43 no.2
• /
• pp.42.1-42.1
• /
• 2018

Collisionless shocks with low sonic Mach numbers, M<4, are expected to accelerate cosmic ray (CR) protons via diffusive shock acceleration (DSA) in the intracluster medium (ICM). However, observational evidence for CR protons in the ICM has yet to be established. Performing particle-in-cell simulations, we study the injection of protons into DSA and the early development of a nonthermal particle population in weak shocks in high ${\beta}$ plasmas. Reflection of incident protons, self-excitation of plasma waves via CR-driven instabilities, and multiple cycles of shock drift acceleration are essential to the early acceleration of CR protons in supercritical quasi-parallel shocks. We find that only in ICM shocks with $M{\geq}2.3$, a sufficient fraction of incoming protons are reflected by the overshoot in the shock electric potential and magnetic mirror at locally perpendicular magnetic fields, leading to efficient excitation of magnetic waves via CR streaming instabilities and the injection into the DSA process. Since a significant fraction of ICM shocks have M < 2.3 CR proton acceleration in the ICM might be less efficient than previously expected. This may explain why the diffuse gamma-ray emission from galaxy clusters due to proton-proton collisions has not been detected so far.

• The Bulletin of The Korean Astronomical Society
• /
• v.46 no.2
• /
• pp.51.1-51.1
• /
• 2021

Merger shocks with M_s < ~ 3 - 4 have been detected in galaxy clusters through radio observations of synchrotron radiations emitted from cosmic-ray (CR) electrons. The CR electrons are believed to be produced by the so-called diffusive shock acceleration (DSA) at the merger shocks. To describe the acceleration of electrons, the injection into DSA has to be understood. Recent studies have showed that electrons could be energized through stochastic shock drift acceleration (SSDA), a mechanism mediated by multi-scale plasma waves at shock transition zone. However, such preacceleration process seems to be effective only at the supercritical shocks with M_s > ~ 2.3, implying that further studies should be done to explain radio relics with weaker shocks. In this talk, we present the results obtained by fully kinetic 2D particle-in-cell (PIC) simulations, which include pre-existing suprathermal electrons possibly ejected from active galactic nuclei (AGNs) or produced by previous episodes of turbulence/shocks. The simulations indicate that the pre-existing electrons enhance the upstream plasma waves in shocks with M_s < ~ 2.3. However, the wavelength of such waves is not long enough to scatter off suprathermal electrons and energize them to the injection momentum for DSA. Hence, we conclude that preexciting suprathermal electrons alone would not solve the problem of electron acceleration at radio relic shocks.

• KSBB Journal
• /
• v.25 no.4
• /
• pp.337-343
• /
• 2010

It has been well known that organic solvents like t-butanol and n-hexane can protect lipases from the inhibition by short-chain alcohols in the enzymatic transesterification. However, use of the organic solvents should be minimized considering their negative effects on environment and human health. Therefore, use of the greener solvents has been pursued in various are as including the enzymatic biotranformation. In this study, the liquid carbon dioxide ($LCO_2$) was employed as an alternative media for the enzymatic transesterification of canola oil. The conversion in the $LCO_2$ was comparable with those in organic solvents and the supercritical carbon dioxide, and under optimum conditions, the value reached 99.7%. It is expected that this method can provide a new type of biodiesel production process with higher energy efficiency and lower environmental impact.

• Clean Technology
• /
• v.11 no.3
• /
• pp.117-122
• /
• 2005

N-vinyl caprolactam (NVCL), a kind of N-vinyl amide monomer, must be dissolved in continuous phase ($scCO_2$) for dispersion polymerization in supercritical carbon dioxide. Phase behavior of $CO_2$+NVCL is very important and necessary for determining initial polymerization condition and for monomer extraction from final polymer. There is the limitation of experimental method for obtaining pure properties of the monomer because of the possibility of polymerization. And N-methyl caprolactam (NMCL) is the useful solvent for the gas treating process. In the viewpoint of molecular thermodynamics, NVCL and NMCL have same functional group i.e. ${\varepsilon}$-caprolactam. In the case of NVCL, hydrogen of amide group is substituted with vinyl group and for NMCL, hydrogen of amide group is substituted with methyl group. We suggested modified group contribution method for this ${\varepsilon}$-caprolactam derivatives. This new group contribution parameter was applied to correlate $CO_2$ + N-vinyl caprolactam or N-methyl caprolactam system.

• Applied Chemistry for Engineering
• /
• v.23 no.1
• /
• pp.105-111
• /
• 2012

Manganese (Mn) catalysts were generated using $CeO_2$ and $ZrO_2$supports synthesized by the supercritical hydrothermal method and two different Mn precursors, aimed at an application for a low-temperature selective catalytic reduction process. Manganese acetate (MA) and manganese nitrate (MA) were used as Mn precursors. Effects of the kind and the concentration of the Mn precursor used for catalyst generation on the NOx removal efficiency were investigated. The characteristics of the generated catalysts were analyzed using $N_2$ adsorption-desorption, thermo-gravimetric analysis, X-ray diffraction, and X-ray photoelectron spectroscopy. De-NOx experiments were carried out to measure NOx removal efficiencies of the catalysts. NOx removal efficiencies of the catalysts generated using MA were superior to those of the catalysts generated using MN at every temperature tested. Analyses of the catalyst characteristics indicated that the higher NOx removal efficiencies of the MA-derived catalysts stemmed from the higher oxygen mobility and the stronger interaction with support material of $Mn_2O_3$ produced from MA than those of $MnO_2$ produced from MN.

• Journal of Life Science
• /
• v.20 no.11
• /
• pp.1691-1696
• /
• 2010

Neohesperidin is a natural new nutrition sweetener, widely existing in plants of dry citrus peel, which can be derived from extraction. Since the sweetness is 1,300-1,500 times greater than that of sugar, neohesperidin are widely used in fruit juices, wines, beverages, bakeries and pharmaceutical formulations, and are particularly suitable for consumption by diabetic patients. However, the yield of extraction from citrus peel waste is very low. In this study optimal yield conditions were determinedusing response surface methodology (RSM) in order to increase the neohesperidin extraction yield. The critical factors for maximum extraction yield were selected extraction pressure ($x_1$), extraction time ($x_2$), and concentration of ethanol ($x_3$). As a result, the extraction yield was improved when the extracting pressure increased. The extraction yield also increased in a time-dependent manner. When adding ethanol as an assistance solvent to the supercritical carbon dioxide, extraction yield was increased as more ethanol concentration was added. Finally, the extraction yield of neohesperidin was improved to about 162.22% compared to ethanol extraction as a conventional method.