• 제목/요약/키워드: Sulphate

검색결과 365건 처리시간 0.029초

Modeling of continuous diffusion dialysis of aqueous solutions of sulphuric acid and nickel sulphate

  • Bendova, Helena;Palaty, Zdenek
    • Membrane and Water Treatment
    • /
    • 제2권4호
    • /
    • pp.267-279
    • /
    • 2011
  • At steady state, the simultaneous transport of sulphuric acid and nickel sulphate through an anion-exchange membrane Neosepta-AFN (Astom Corporation, Tokyo, Japan) was investigated in a two-compartment counter-current dialyzer with single passes. The transport was quantified by the recovery yield of acid, rejection of salt and four phenomenological coefficients, which were correlated with the acid and salt concentrations in the feed. The phenomenological coefficients were determined by the numerical integration of the basic differential equations describing the concentration profiles of the components in the dialyzer. This integration was combined with an optimizing procedure. The experiments proved that the acid recovery yield is in the limits from 63 to 91 %, while salt rejection is in the limits from 79 to 97 % in the dependence on the volumetric liquid flow rate and composition of the feed.

포틀랜드계 시멘트 콘크리트의 촉진 염화물 확산 특성 (Accelerated Chloride Diffusion Properties of Portland Cement Concrete)

  • 김진철;이찬영;이용은
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
    • /
    • pp.775-778
    • /
    • 1999
  • Accelerated chloride diffusion tests were carried out to estimate the chloride diffusion coefficient of concrete using ordinary portland cement, low heat belite-rich portland cement, and sulphate resistant portland cement. Concrete using low heat belite-rich portland cement showed a high diffusion coefficient due to delayed hydration of low heat belite rich portland cement, while the diffusion coefficients of concrete using sulphate resistant portland cement and ordinary portland cement were low.

  • PDF

전착과산화납양극에 의한 황산염. 전해산화시의 전해온도의 영향 (Influence of Temperature on the Electrolytic Oxidation of Sulphate Solutions by Electro-deposited Lead Peroxide Anode)

  • 남종우;김학준
    • 대한화학회지
    • /
    • 제15권5호
    • /
    • pp.223-228
    • /
    • 1971
  • In the electrolytic preparation of persulphate from sulphate solution, the current efficiency decrease with temperature increase at the platinum anode. But in case of electrodeposited lead peroxide anode, the current efficiency increase with temperature of the solution. The reason seems to be that the ozone formation is faster in platinum anode than in lead peroxide as temperature increase.

  • PDF

한강 지류의 유기물 농도와 황산염 환원세균의 상관관계 (Relationship between the Organic Content and the Number of Sdphate-Reducing Bacteria in the Tributaries to the Han River)

  • 김해영;김태성;김병홍;김재문
    • 한국미생물·생명공학회지
    • /
    • 제20권2호
    • /
    • pp.233-235
    • /
    • 1992
  • The number of sulphate-reducing bacteria (SRB) in some of the tributaries to the Han River was determined by the most probable number method using Postgate's Medium E.Higher number of SRB were obtained in the streams to which industrial waste water is discharged than those receiving only domestic waste water.

  • PDF

Magnetic Properties of Thin Cu/Co Multilayers Made by Electrodeposition

  • Lee, Jung-Ju;Lee, Jin-Han;Hong, Kim-In
    • Journal of Magnetics
    • /
    • 제10권3호
    • /
    • pp.118-121
    • /
    • 2005
  • We have investigated the magnetic properties of electroplated thin Cu/Co multilayers by using electrolytes made of copper sulphate and cobalt sulphate and by applying alternating plating voltage. While the multilayers plated with pure electrolyte showed superparamagnetism, those plated with organic additives showed ferromagnetic behavior. These changes are attributed to the so-called 'self-annealing' effect and reduction of grain size caused by the organic additives.

Optimization of Laccase Production from Bacillus sp. PK4 through Statistical Design of Experiments

  • Rajeswari, Murugesan;Bhuvaneswari, Vembu
    • 한국미생물·생명공학회지
    • /
    • 제45권4호
    • /
    • pp.330-342
    • /
    • 2017
  • Statistical design of experiments was employed to optimize the media composition for the production of laccase from Bacillus sp. PK4. In order to find the key ingredients for the best yield of enzyme production from the selected eleven variables viz yeast extract, glucose, zinc sulphate, copper sulphate, potassium chloride, magnesium sulphate, calcium chloride, ferrous sulphate, sodium chloride, potassium dihydrogen phosphate ($KH_2PO_4$) and dipotassium hydrogen phosphate ($K_2HPO_4$), Plackett-Burman design was applied. The $MgSO_4$, $FeSO_4$, and $CuSO_4$ showed positive estimate, and their concentration optimized further. The steepest ascent method and Box-Behnken method revealed that 1.5 mM $MgSO_4$, 0.33 g/l $FeSO_4$ and 1.41 mM $CuSO_4$ were optimal for the laccase production by Bacillus sp. PK4. This optimization strategy leads to enhancement of laccase production from 2.13 U/ml to 40.79 U/ml. Agro-wastes residues replace the carbon source glucose in the optimized media namely sugarcane bagasse, wheat bran, rice husk, and groundnut shell, among these groundnut shells (117 U/ml) was found to enhance the laccase production significantly. The laccase produced by Bacillus sp. PK4 was found to have the potential to degrade persistent organic pollutant benzo[a]pyrene.

위성자료를 이용한 2001-2010년 동안의 동아시아 지역 에어로졸 직접복사강제력 분석 (An Analysis of Aerosol Direct Radiative Forcing Using Satellite Data in East Asia During 2001-2010)

  • 정지현;김학성;김준태;박용필;최현정
    • 한국환경과학회지
    • /
    • 제22권8호
    • /
    • pp.1053-1062
    • /
    • 2013
  • The shortwave aerosol direct radiative forcing (SWARF) was analyzed using the Clouds and Earth's Radiant Energy System (CERES) data in the East Asian region from 2001 to 2010. In the Yellow Sea and the Korean Peninsula, located in the leeward side of China, significantly negative high SWARF at the top of atmosphere (TOA) occurs due to the long-range transport of anthropogenic (e.g. sulphate) and natural aerosols (e.g. mineral dust) from the East Asian continent. Conversely, eastern China has much higher levels of SWARF at the surface (SFC) due to anthropogenically emitted aerosol than in the Yellow Sea and the Korean Peninsula. Since the radiative forcing of aerosols in the atmosphere are different in type, aerosol types were classified into sea salt+sulphate, smoke, sulphate and dust by using satellite data. The analysis on the SWARF by the classified aerosol types indicated that sulphate occupies a predominant portion of the atmosphere in the Yellow Sea and the Korean Peninsula in the summer. In particular, the annual averages of the summer TOA SWARF increased in the Yellow Sea and the Korean Peninsula from 2001 to 2010.

수용액상 계면활성제의 임계 미셀 농도에 대한 N-methyl acetamide의 영향 (Effect of N-Methyl Acetamide on the Critical Micelle Concentration of Aqueous Solutions of Some Surfactants)

  • Alawi, Sadeq M.;Akhter, M. Salim
    • 대한화학회지
    • /
    • 제55권2호
    • /
    • pp.163-168
    • /
    • 2011
  • 다양한 농도의 N-methyl acetamide 수용액에서 계면 활성제의 농도에 따른 계면활성제들 (sodium caprylate, sodium laurate, sodium palmitate, sodium stearate, sodium oleate, sodium dodecyl sulphate, lithium dodecyl sulphate)의 몰 전도도 변화를 $30{\pm}0.2^{\circ}C$의 일정온도에서 연구하였다. 각각의 계면활성제에 대한 임계 미셀 농도 (CMC)를 측정하였다. 수용액에 N-methyl acetamide이 공존할 때에는 여러 계면 활성제의 CMC 값이 수용액에서의 CMC 값보다 더 낮고, 미셀 형성에 대한 추진력은 소용매성과 관련되었다. N-methyl acetamide 수용액에서 양쪽성 자기-조직화를 추진하는 계면활성제-용매의 상호작용에 대해 논의하였다. 이 결과들을 설명하기 위하여 미셀 시스템에 대한 열역학적 매개변수들을 추정하였다.