• Title/Summary/Keyword: Sulfur content

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CO2 Emission Characteristics of Bunker C Fuel Oil by Sulfur Contents (C 중유의 황 함유량에 따른 CO2 배출 특성)

  • Lim, Wan-Gyu;Doe, Jin-Woo;Hwang, In-Ha;Ha, Jong-Han;Lee, Sang-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.4
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    • pp.368-377
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    • 2015
  • Bunker C fuel oil is a high-viscosity oil obtained from petroleum distillation as a residue. The sulfur content of bunker C fuel oil is limited to 4.0% or even lower to protect the environment. Because bunker C fuel oil is burned in a furnace or boiler for the generation of heat or used in an engine for the generation of power, carbon dioxide is emitted as a result of combustion. The objective of this study is to investigate $CO_2$ emission characteristics of bunker C fuel oil by sulfur contents. Calorific values and carbon contents of the fuels were measured using the oxygen bomb calorimeter method and the CHN elemental analysis method, respectively. Sulfur and hydrogen contents, which were used to calculate the net calorific value, were also measured and then net calorific values and $CO_2$ emission factors were determined. The results showed that hydrogen content increases and carbon content decreases by reducing sulfur contents for bunker C fuel oil with sulfur contents less than 1.0%. For sulfur contents between 1.0% and 4.0%, carbon content increases as sulfur content decreases but there is no evident variation in hydrogen content. Net calorific value increases by reducing sulfur contents. $CO_2$ emission factor, which is calculated by dividing carbon content by net calorific value, decreases as sulfur content decreases for bunker C fuel oil with sulfur contents less than 1.0% but it showed relatively constant values for sulfur contents between 1.0% and 4.0%.

Effect of Sulfur Application on Mulberry Growth and Chemical Composition of Soil and Leaf. (황시용이 뽕나무의 생육 및 토양과 뽕잎의 화학성에 미치는 영향)

  • 이원주;임수호
    • Journal of Sericultural and Entomological Science
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    • v.37 no.2
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    • pp.109-113
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    • 1995
  • Effects of sulfur application on mulberry growth and soil chemical properties were examined in mulberry trees grown in a green house. Mulberry graftages were planted in Wagner pots and sulfur was applied at the levels of 0, 30, 60, or 120 kg/10a. Mulberry stem growth increased by 3.2 cm at 30 kg/ha than at 0 kg/ha sulfur application. Stem growth, however, decreased by 3.7 cm with the application of sulfur higher than at 60 kg/10a. Soil pH changed by the application of sulfur. With the application of sulfur at 120 kg/10a, soil pH decreased by 3.0. Temporal changes in the effective from sulfur content in soil indicated that sulfur dissolved between 4 to 10 days after application in the soil. Content of moisture and chemical components in mulberry leaves was also affected by the application levels of sulfur. Moisture, total-N, No3-N, K, and S content decreased, but F and Ca content increased with the application of sulfur lower than at 60 kg/10a. With the application of sulfur higher than at 60 kg/10a, P, S, and K content increased.

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A Study on the Effect of Air Pollutants in Daegu Area by Biological Indicator of Roadside (道路 指標生物을 이용한 대기오염이 植物에 미치는 영향에 관한 연구)

  • Kang, Hoe-Yang;Cha, Sang-Eun;Ha, Cheong-Gun
    • Journal of Environmental Health Sciences
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    • v.14 no.2
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    • pp.29-41
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    • 1988
  • This study was performed to investigate the air pollution levels in Daegu area titrough measuring of contents of water, chlorophyll, water soluble sulfur and lead metal in the leaves of roadside trees and chemical properties of soil under the urban trees. The results can be summarized as follows 1. The range of water content was from 60.4% to 74.6%. The comparisons of chlorophyll, water soluble sulfur and water content were regression equation, chlorophyll=0.1981+ 0.0040 water content (July), water soluble sulfur=3,139-0.0416 water content (July). and correlation coefficient, r=0.561 and r=0.549 respectively 2. Average contents of chlorophyll, water soluble sulfur and lead metal in the leaves of roadside tree at sampling sites were chlorophyll 0.050, 0.072mg/cm$^2$, water soluble sulfur 0.244, 0.333%, and lead metal 12.25, 12.68ppm in Oct. and Jul. respectively. 3. Correlation between chlorophyll and contents of water soluble sulfur and lead metal in the leaves of roadside tree at sampling sites were water soluble sulfur r=-0.564, -0.613 and lead metal r=-0.693, -0.699 in October and July, respectively. 4. Correlation between chlorophyll and water content, water soluble sulfur and lead metal in the leaves of tree showed positive significance.

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Influence of Sulfur Fertilization on the Antioxidant Activities of Onion Juices Prepared by Thermal Treatment

  • Koh, Eunmi;Surh, Jeonghee
    • Preventive Nutrition and Food Science
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    • v.21 no.2
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    • pp.160-164
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    • 2016
  • Two onions (Sulfur-1 and Sulfur-4) cultivated with different sulfur applications were thermally processed to elucidate the effects of heat treatment on browning index and antioxidant activity. Sulfur-4 onion had higher sulfur content compared with the Sulfur-1 onion. After thermal processing, browning intensity was different between the two onions juices, with lower values observed for Sulfur-4 onion juice. This suggests that sulfur inhibits the Maillard browning reaction. The total reducing capacity of the juices increased at higher thermal processing temperatures; however, it was also lower in the Sulfur-4 onion juice. This suggests that the heat treatment of onions enhanced their antioxidant activity, but the effect was offset in the Sulfur-4 onion juice presumably due to higher sulfur content. This study indicates that sulfur, a core element for the functionality of onions, can decrease the antioxidant activity of thermally processed onions because of its potential as a Maillard reaction inhibitor.

Study on the Sulfide Corrosion to the Internal Surface of Transportation Pipeline

  • Zhang, Yiling;Qi, Ping;Kong, Dehong
    • Corrosion Science and Technology
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    • v.7 no.4
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    • pp.193-196
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    • 2008
  • This article briefly tests and analyzes the sulfur content and the distribution of active sulfur in the crude oil of Kurkow Kazakhstan and Siberian Russian, and discusses the relationship between active sulfur content and total sulfur content, active sulfur and corrosion. At the same time, it measures the open circuit potential of X70 steel and X60 steel witch have been immerged in the above two kind of crude oil for a period of time, discusses the sulfur corrosion to metal.

Effect of Sulfur Fertilization Method on Quality of Safflower Seed (황 시용방법에 따른 잇꽃 종실의 품질)

  • Kim, Min-Ja;Kim, In-Jae;Nam, Sang-Young;Lee, Cheol-Hee;Song, Beom-Heon
    • Korean Journal of Medicinal Crop Science
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    • v.12 no.6
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    • pp.454-458
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    • 2004
  • This study was carried out to clarify the effect of sulfur fertilization method on the qualities of safflower (Carthamus tinctorious L.) seed. Sulfur application increased the nitrogen and sulfur content of seed. In nitrogen content, there was no significant difference among sulfur fertilizers, whereas sulfur content was increased by raising ammonium sulfate (AS) amounts by soil application. In application method of AS, there was no significantly difference between foliar application and soil application with 8 kg S/10a. N/S ratio in seed was decreased by sulfur application, and also decreased with the increase of AS amounts by soil application. The contents of lipid and protein were increased by sulfur application. Lipid content was highest in foliar application, and protein content was lowest in AS 4 kg S/10a. By sulfur application, the content of total phenolics and electron donating ability (EDA) were increased by $3.1{\sim}4.7%$ and $3.6{\sim}8.5%$, respectively compared with control. In content of total phenolics, there was no significant difference among sulfur fertilizers, but EDA was higher in sulfur powder 20 kg/10a and AS 8 kg S/10a than that in other fertilizers. Sulfur application showed positive effects on the qualities of safflower seed. In application effects, AS and foliar application were more efficient than sulfur powder and soil application, respectively.

The Effect of the Gypsum Application on the Composition of Nitrogen and Sulfur Compounds in Mixed Pasture and on the Sulfur Balance in Soil (혼파초지에서 Gypsum 처리가 목초의 질소 및 황화합물조성과 토양중 황균형에 미치는 영향)

  • 윤순강;황석중;김재규
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.8 no.3
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    • pp.152-157
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    • 1988
  • The effect of gypsum application was tested on dry matter yield, sulfur uptaken, composition of Ritrogen compound and sulhr compound and sulfur balance in mixed pasture. Total dry matter yields and sulfur uptake by grasses increased with the increasing of gypsum application rates. The ratios between total nitrogen and total sulfur in masses decreased with the increase of sulfur uptake at 2nd and 3rd cutting times. Cysteine content was little affected by gypsum while methionine content slightly increased an 4.0, 6.0 kg3 per 10a levels at 2nd and 3rd cutting times. The uptake of nitrate nitrogen decreased with gypsum application and dry matter digestibility increased about 1.1 to 3.3%. The soil pHs after experiment become high in surface and subsoil till 6.0 kg.S per 10a, but low at 10.0 kg.S per 10a. The content of sulfur in surface soil was 19.9 ppm after experiment, but very high in subsoi1,ranging from 94 to 143 ppm.S. Sulfur leached from the surface soil by 0.69, 2.39, and 6.24 kg.S per 10a in the plots of 4.0, 6.0, and 10.0 kg.S per 10a, respectively.

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Vucanization Study by DSC (DSC를 이용한 가황반응 연구)

  • Cho, Duk-Won;Yoon, Chan-Ho
    • Elastomers and Composites
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    • v.27 no.4
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    • pp.275-280
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    • 1992
  • Vulcanization reaction was studied by DSC through the comparison cure states to physical properties and the investegation of chemicals effect on vulcanization. Reaction enthalpy showed a good correlation with physical properties, increased with the increase of sulfur content, and increased with accelerator content, as well, where the ratio of MOR to sulfur was less than 1.0. Reaction temperature was decreased with increasing accelerator content and decreased also with sulfur content where the ratio of MOR to sulfur was more than 1:3. As a result, the cure state and reaction temperature could be controlled effectively with the ratio of accelerator to sulfur in the range of a third to unity.

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Effect of Carbon Content of Sulfur Electrode on the Electrochemical Properties of Lithium/Sulfur Battery Using PEO Electrolyte (유황전극의 탄소량 변화에 따른 리튬/유황 전지의 방전특성 변화)

  • Kang, K.Y.;Ryu, H.S.;Kim, J.S.;Kim, K.W.;Ahn, J.H.;Lee, G.H.;Ahn, H.J.
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.3
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    • pp.317-323
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    • 2006
  • Electric conductive material should be homogeneously mixed with sulfur in sulfur electrode fabrication of lithium/sulfur battery, because sulfur is electric insulator. In this paper electrochemical properties of Li/S battery was studied with various compositions of sulfur electrodes. When content of sulfur changed from 40 wt.% to 80 wt.%, the 60 wt.% sulfur electrode showed the maximum capacity of 1489 mAh/g-sulfur. Electrochemical properties of Li/S battery using 60 wt.% sulfur was also investigated with various carbon contents. The discharge capacity changed as a function of carbon contents. The optimum composition was 25 wt.% carbon for 60 wt.% sulfur electrode.

The Effect to Agricultural Crop Yield and Sulfur Content in Leaves by Sulfur Dioxide Gas Emission from Onsan Nonferric Metal Industrial Complex (온산(溫山) 공단지역(工團地域)의 배출(排出)가스 (아황산(亞黃酸))가 농작물(農作物) 수량(收量) 및 식물체내(植物體內) 유황함량(硫黃含量)에 미치는 영향(影響))

  • Shin, Nam-Chul
    • Korean Journal of Environmental Agriculture
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    • v.4 no.1
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    • pp.52-56
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    • 1985
  • This study was undertaken to investigate the crop yield of pear and rice cultivated around Onsan Industrial complex, the sulfur content in their leaves, and the crop loss. The correlation between them is as follows: 1) The sulfur content in pear and rice leaves in studied area is higher than that in unpolluted area, and there is crop loss in studied area. 2) There is a good correlation between sulfur content and crop loss of pear and rice. The air pollution in studied area is considered to be the reason of the crop loss. 3) The regression equation between the sulfur content in crop leaves and the crop loss seems to be useful for the crop loss rate by sulfur dioxide in the damaged area and that seems to be a good reference for the compensation of pear and rice loss by sulfur dioxide gas emission from Onsan Industral Complex.

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