• 제목/요약/키워드: Submicron Aerosol

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단일입자 질량분석기를 애용한 서브마이크론 입자의 특성화(I) - 입자의 크기와 질량분광신호의 비선형성 - (Characterization of submicron Particles Using a Single Particle Mass Spectrometer(I) - Non - Linear Correlation Between Particle Size and Mass Spectra Signals -)

  • ;이동근
    • 대한기계학회논문집B
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    • 제29권4호
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    • pp.453-459
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    • 2005
  • In this paper, we are proposing a robust tool which is capable of measuring the size and elemental composition of submicron particles from twenty to several hundreds nanometers at the same time, i.e., named Single Particle Mass Spectrometer (SPMS). The home-made SPMS employs a laser ablation/multi-photon ionization method to tear a nanoparticle into the constituent elemental ions. One thing different from the conventional Aerosol Time-of-Flight Mass Spectrometer (ATOFMS) is the power of the ionization laser. Much strong laser used in this work makes it possible to generate elemental ions rather than molecular ions from a nanoparticle. Also the use of high power laser may guarantee a complete ionization of a particle, which was confirmed by the existence of multiple charged ions. If a particle is evaporated/ionized completely and detected through electric field-free TOF tube without any loss, we can extract the original particle volume from the measured total ion numbers. Collecting a number of particles mass spectra, we get a database of size and elemental composition of nanoparticles, with which we may take a took into any kinds of chemical reaction occurring at nanoscale. Several issues related to size estimation by SPMS will be discussed.

초미세 크기의 마른 안개 생성과 이를 이용한 미세먼지 제거 연구 (Experimental study on the generation of ultrafine-sized dry fog and removal of particulate matter)

  • 김기웅
    • 한국가시화정보학회지
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    • 제22권1호
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    • pp.34-39
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    • 2024
  • With the fine particulate matter (PM) poses a serious threat to public health and the environment. The ultrafine PM in particular can cause serious problems. This study investigates the effectiveness of a submicron dry fog system in removing fine PM. Two methods are used to create fine dust particles: burning incense and utilizing an aerosol generator. Results indicate that the dry fog system effectively removes fine dust particles, with a removal efficiency of up to 81.9% for PM10 and 61.9% for PM2.5 after 30 minutes of operation. The dry fog, characterized by a mean size of approximately 1.5 ㎛, exhibits superior performance in comparison to traditional water spraying methods, attributed to reduced water consumption and increased contact probability between water droplets and dust particles. Furthermore, experiments with uniform-sized particles which sizes are 1 ㎛ and 2 ㎛ demonstrate the system's capability in removing ultrafine PM. The proposed submicron dry fog system shows promise for mitigating fine dust pollution in various industrial settings, offering advantages such as energy consumption and enhanced safety for workers and equipment.

간접 광대전에 의한 서브 마이크론 입자의 단극하전 특성 (The Unipolar Charging Characteristics of Submicron Particles by Using an Indirect Photoelectric Charging)

  • 최영주;김상수
    • 대한기계학회논문집B
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    • 제27권6호
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    • pp.677-684
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    • 2003
  • A new unipolar aerosol charger was developed by using an indirect photoelectric charging. The charger consists of two coaxial tubes, the inner UV lamp wrapped with stainless mesh and the outer Al cylinder. In this study, the effects of flow rate, particle size, and electric field were examined to search the optimal charging conditions with experimental and numerical methods. Monodisperse NaCl particles were fed into an annular space and the particles were charged by negative ions generated from Al plate exposed to the UV light. According to experimental results, the average number of elementary charge on particles increases from 2.5 to 5.5 as particle size increases from 50nm to 130nm at 2.5 L/min and 100V. The average number of elementary charge on particles was maximized at 25V as the electric potential between the stainless mesh and Al plate was varied from 0V to 400V.

Theoretical Study on Magnetic Field Application for Fine Particle Capture

  • Huang, Shan;Park, Haewoo;Jo, Youngmin
    • 한국입자에어로졸학회지
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    • 제10권2호
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    • pp.45-51
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    • 2014
  • Fine particle capture is facing a challenge since traditional filtration which relies on the combination of impaction, interception, diffusion has a limited efficiency for fine particle capture particularly in size from 0.1 to $0.5{\mu}m$. This paper reviewed the collection efficiency of above mechanisms, as well as magnetic mechanisms for ferromagnetic particles, and mainly studied the influencing factors of magnetic filtration. Filtration velocity, magnetic field intensity and fiber size were found to be the most important parameters for magnetic filtration.

Hy-CPC의 개발 및 성능평가 (Development and Evaluation of Hy-CPC)

  • 이홍규;황인규;안강호
    • 한국입자에어로졸학회지
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    • 제10권3호
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    • pp.93-97
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    • 2014
  • Condensation particle counter (CPC) has been one of the most important basic instrument for measuring number concentration of submicron aerosols. The principle of the CPC is to expose aerosols to a supersaturated vapor and cool down which causes adiabatic expansion. The particles grow by heterogenous nucleation to a sufficient size for easy detection by optical method. However, for growth by condensation, CPC essentially needs both saturater and condensor causing a heavy system. Therefore, it is hard to install commercial CPC to tethered balloon package system. In this study, we developed customized CPC for tethered balloon package system called Hy-CPC which is lighter and smaller in structure than commercial CPCs, and evaluated activation efficiency and detection efficiency by Hy-CPC using electrostatic method (electrometer and Faraday cup).

Hy-SMPS의 개발 및 성능평가 (Development and Evaluation of Hy-SMPS)

  • 이홍규;은희람;이건호;안강호
    • 한국입자에어로졸학회지
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    • 제11권2호
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    • pp.57-61
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    • 2015
  • Atmospheric nano-particles along the altitude is one of the main factors causing severe weather phenomena. It is a challenge to find the precise particle size distribution. One useful instrument includes a scanning mobility particle sizer (SMPS). This measures the size distribution of submicron aerosols. The SMPS consists of a condensation particle counter (CPC), differential mobility analyzer (DMA), high voltage power supplier (HVPS), and neutralizer. Due to the many components, it is difficult to install a commercial SMPS into a tethered balloon package system (Eun, 2011). In this study, we customized a SMPS for the tethered balloon package system called Hy-SMPS. It is portable, compact in structure, and evaluated by TSI SMPS using mono and poly-dispersed particles.

입자의 크기와 유속에 따른 섬유질 여과포에 의한 부유입자 제거 연구 (Removal of Aerosol Through Fibrous Filter as a Function of Particle Size and Velocity)

  • Sang Hoon Lee;Kwan Sik Chun;Hoo Keun Lee
    • Nuclear Engineering and Technology
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    • 제16권1호
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    • pp.29-35
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    • 1984
  • 유리섬유 여과포에 의한 0.1~0.45$\mu\textrm{m}$ 크기의 DOP 부유입자의 제거효율시험을 1~10cm/sec의 유속범위에서 수행하였다. 섬유여과포에 의한 미세입자의 여과는 여과속도에 의하여 결정되는데, 최소제거 효율을 나타내는 DOP 입자의 크기는 여과속도가 증가함에 따라 감소한다. Kuwabara Cell Model과 Von Mises Transformation을 사용하여 유리섬유 여과포내에서 화산에 의한 입자 제거효율을 수치해석적으로 전개하여 구하였으며, 이 계산치는 실험치와 잘 일치하였다. 본 실험의 결과는 여과포의 입자제거효율을 예측하고 최적 운전조건을 추구하는데 기여할 수 있을 것이다.

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Aerosol Deposition Method으로 성막한 $BaTiO_3$ 박막과 기판과의 계면 및 미세구조가 전기적 특성에 미치는 영향 (Effects of Microstructures and Interfaces between $BaTiO_3$ Thin Films and Substrates on Electrical Properties in Aerosol Deposition Method)

  • 오종민;남송민
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.350-350
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    • 2008
  • 최근 이동 통신 분야에서 전자기기들의 고주파화와 소형화에 대한 관심이 높아지면서 고주파 소자로서 필수적으로 사용 되어온 디커플링 캐패시터도 이 두 가지 요구를 만족시키기 위해 기존의 표면 실장형에서 평판 형태인 기판 내장형 캐패시터로 발전해 가고 있다. 이를 실현하기 위한 공정법으로 Low Temperature Co-fired Ceramics (LTCCs)와 polymer composite등의 연구가 진행되고 있으나 LTCCs는 높은 공정온도에 의한 내부 확산과 서로 다른 열팽창 계수에 의한 소결후의 수축과 같은 단점들을 가지고 있으며 polymer composite 은 비교적 낮은 공정온도에도 불구하고 유전특성과 방열특성이 우수하지 못한 문제점을 가지고 있었다. 이러한 단점들을 극복하기 위해 Aerosol Deposition Method (ADM)를 주목하게 되었다. 이 공정 법은 상온 저 진공 분위기에서 세라믹 분말을 기판에 고속 분사시켜 기공과 균열이 거의 없는 치밀한 나노구조의 세라믹을 제작하는 새로운 코팅기술이다. 본 연구에서는 고주파용 디커플링 캐패시터의 응용을 위하여 상온에서 높은 유전율을 가지며 강유전체 물질인 $BaTiO_3$를 사용하였다. 출발원료로서 0.45 ${\mu}m$크기의 $BaTiO_3$ 분말을 이용하여 상온에서 submicron에서 수 micron의 두께로 성막하였다. 그러나 ADM으로 $BaTiO_3$ 막을 성막할 경우 유전율이 100이하로 급격히 떨어지는 현상이 기존 연구에서 보고되어 왔으며 본 연구에서도 이를 확인하였다. 디커플링 캐패시터의 밀도를 높이기 위해서 유전체의 유전율을 높이거나 두께를 앓게 하는 방법이 있으나 이번 연구에서는 박막화에 초점을 맞추어 진행하였다. 하지만 $BaTiO_3$ 막의 두께를 $1{\mu}m$이하의 박막으로 제조했을 경우 XRD 분석을 통하여 결정상이 얻어졌음을 확인했음에도 불구하고 유전체로서의 특성을 보이지 않았다. 이 원인을 $BaTiO_3$ 박막의 누설전류에 의한 것이라고 판단하고 $BaTiO_3$ 박막과 기판과의 계면 및 미세구조를 확인하였으며 이것이 전기적 특성에 미치는 영향에 대해 분석하였다.

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Visualization of Artificially Deposited Submicron-sized Aerosol Particles on the Surfaces of Leaves and Needles in Trees

  • Yamane, Kenichi;Nakaba, Satoshi;Yamaguchi, Masahiro;Kuroda, Katsushi;Sano, Yuzou;Lenggoro, I. Wuled;Izuta, Takeshi;Funada, Ryo
    • Asian Journal of Atmospheric Environment
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    • 제6권4호
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    • pp.275-280
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    • 2012
  • To understand the effect of aerosols on the growth and physiological conditions of trees in forests, it is important to know the state of aerosols that are deposited on the surface of the leaves or needles. In this study, we developed methods of visualization of submicron-sized aerosols that were artificially deposited from the gas-phase or liquid phase onto tree leaves or needles in trees. Firstly, we used field-emission scanning electron microscopy (FE-SEM) to observe black carbon (BC) particles that were artificially sprayed onto the leaves or needles. The distribution of BC particles deposited on the leaves and needles were distinguished based on the size and morphological features of the particles. The distribution and agglomerates size of BC particles differed between two spraying methods of BC particles employed. Secondly, we tried to visualize gold (Au) particles that were artificially sprayed onto the leaves using energy dispersive X-ray spectrometry (EDX) coupled to FE-SEM. We detected the Au particles based on the characteristic X-ray spectrum, which was secondarily generated from the Au particles. In contrast to the case of BC particles, the Au particles did not form agglomerates and were uniformly distributed on the leaf surfaces. The present results show that our methods provide useful information of adsorption and/or behavior of fine particles at the submicron level on the surface of the leaves.

한반도 서부유입권역에서 대기 중 에어로졸 성분의 물리·화학적 특성 연구 III. 화학적 거동 및 장거리 이동 (Physico-chemical Characteristics of Submicron Aerosol at West Inflow Regions in the Korean Peninsula III. Physical-Chemical Behavior and Long-range Transport of PM1)

  • 박태현;안준영;최진수;임용재;박진수;김정호;오준;이용환;홍유덕;홍지형;최용주;이태형
    • 한국대기환경학회지
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    • 제33권2호
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    • pp.124-138
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    • 2017
  • Physico-chemical measurement of non-refractory submicron particles($NR-PM_1$) was conducted in Baengnyeong Island, Korea using Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) from 2012 to 2014. Organics and ammoniated sulfate were dominant species in $NR-PM_1$. The organics was found to have similar fractions(approximate 40%) of $NR-PM_1$ during the summer and winter, while the sulfate fractions of $NR-PM_1$ were calculated to be approximately 47% and 31% for the summer and winter, respectively, suggesting the possibility that particles provide non-acidic surfaces for condensation of nitric acid in the winter. The nitrate fractions of approximate 4% and 20% of $NR-PM_1$ were observed in August (summer) and November (winter), respectively, resulting that the relatively low concentration of sulfate in $NR-PM_1$ provided a non-acidic surface for nitric acid condensation and formation of particulate ammoniated nitrate is favored thermodynamically in winter. The new particle formation (NPF) event and particle growth rate were analyzed for each month in 2014 using Scanning Mobility Particle Sizer(SMPS). The Percent of NPF events was the highest in winter, but NPF event was not observed during summer due to relatively high temperature and frequent rainfall. The average particle growth rate was 3.5 nm/h and the highest particle growth rate was 5.5 nm/h in May. We observed the long-range transport of the anthropogenic sulfate from the East Asia during the intensive monitoring period of November between Qingdao and Baengnyeong Island in 2013. The relatively high concentrations of m/z 60 measured in HR-ToF-AMS was observed in May and June at Baengnyeong Island, suggesting the possibility of the influence of biomass burning from the East Asia to the Korean Peninsula.