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Corrosion Behavior of Hastelloy C-276 for Carbon-anode-based Oxide Reduction Applications

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.383-393
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    • 2020
  • The corrosion behavior of Hastelloy C-276 was investigated to identify its applicability for carbon-anode-based oxide reduction (OR), in which Cl2 and O2 are simultaneously evolved at the anode. Under a 30 mL·min-1 Cl2 + 170 mL·min-1 Ar flow, the corrosion rate was less than 1 g·m-2·h-1 up to 500℃, whereas the rate increased exponentially from 500 to 700℃. The effects of the Cl2-O2 composition on the corrosion rate at flow rates of 30 mL·min-1 Cl2, 20 mL·min-1 Cl2 + 10 mL·min-1 O2, and 10 mL·min-1 Cl2 + 20 mL·min-1 O2 with a constant 170 mL·min-1 Ar flow rate at 600℃ was analyzed. Based on the data from an 8 h reaction, the fastest corrosion rate was observed for the 20 mL·min-1 Cl2 + 10 mL·min-1 O2 case, followed by 30 mL·min-1 Cl2 and 10 mL·min-1 Cl2 + 20 mL·min-1 O2. The effects of the chlorine flow rate on the corrosion rate were negligible within the 5-30 mL·min-1 range. A surface morphology analysis revealed the formation of vertical scratches in specimens that reacted under the Cl2-O2 mixed gas condition.

THE IMAGES OF LOCALLY FINITE 𝓔-DERIVATIONS OF POLYNOMIAL ALGEBRAS

  • Lv, Lintong;Yan, Dan
    • Bulletin of the Korean Mathematical Society
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    • v.59 no.1
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    • pp.73-82
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    • 2022
  • Let K be a field of characteristic zero. We first show that images of the linear derivations and the linear 𝓔-derivations of the polynomial algebra K[x] = K[x1, x2, …, xn] are ideals if the products of any power of eigenvalues of the matrices according to the linear derivations and the linear 𝓔-derivations are not unity. In addition, we prove that the images of D and 𝛿 are Mathieu-Zhao spaces of the polynomial algebra K[x] if D = ∑ni=1 (aixi + bi)∂i and 𝛿 = I - 𝜙, 𝜙(xi) = λixi + 𝜇i for ai, bi, λi, 𝜇i ∈ K for 1 ≤ i ≤ n. Finally, we prove that the image of an affine 𝓔-derivation of the polynomial algebra K[x1, x2] is a Mathieu-Zhao space of the polynomial algebra K[x1, x2]. Hence we give an affirmative answer to the LFED Conjecture for the affine 𝓔-derivations of the polynomial algebra K[x1, x2].

QUADRATIC (ρ1, ρ2)-FUNCTIONAL EQUATION IN FUZZY BANACH SPACES

  • Paokant, Siriluk;Shin, Dong Yun
    • The Pure and Applied Mathematics
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    • v.27 no.1
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    • pp.25-33
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    • 2020
  • In this paper, we consider the following quadratic (ρ1, ρ2)-functional equation (0, 1) $$N(2f({\frac{x+y}{2}})+2f({\frac{x-y}{2}})-f(x)-f(y)-{\rho}_1(f(x+y)+f(x-y)-2f(x)-2f(y))-{\rho}_2(4f({\frac{x+y}{2}})+f(x-y)-f(x)-f(y)),t){\geq}{\frac{t}{t+{\varphi}(x,y)}}$$, where ρ2 are fixed nonzero real numbers with ρ2 ≠ 1 and 2ρ1 + 2ρ2≠ 1, in fuzzy normed spaces. Using the fixed point method, we prove the Hyers-Ulam stability of the quadratic (ρ1, ρ2)-functional equation (0.1) in fuzzy Banach spaces.

Effect of Fe and BO3 Substitution in Li1+xFexTi2-x(PO4)3-y(BO3)y Glass Electrolytes (Li1+xFexTi2-x(PO4)3-y(BO3)y 계 유리 전해질에서 Fe 및 BO3 치환 효과)

  • Choi, Byung-Hyun;Jun, Hyung Tak;Yi, Eun Jeong;Hwang, Haejin
    • Journal of the Korean Electrochemical Society
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    • v.24 no.3
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    • pp.52-64
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    • 2021
  • The effect of Fe and BO3 doping on structure, thermal, and electrical properties of Li1+xFexTi2-x(PO4)3-y(BO3)y (x = 0.2, 0.5)-based glass and glass ceramics was investigated. In addition, their crystallization behavior during sintering and ionic conductivity were also investigated in terms of sintering temperature. FT-IR and XPS results indicated that Fe2+ and Fe3+ ions in Li1+xFexTi2-x(PO4)3-y(BO3)y glass worked as a network modifier (FeO6 octahedra) and also as a network former (FeO4 tetrahedra). In the case of the glass with low substitution of BO3, boron formed (PB)O4 network structure, while boron preferred BO3 triangles or B3O3 boroxol rings with increasing the BO3 content owing to boic oxide anomaly, which can result in an increased non-bridging oxygen. The glass transition temperature (GTT) and crystallization temperature (CT) was lowered as the BO3 substitution was increased, while Fe2+ lowered the GTT and raised the CT. The ionic conductivity of Li1+xFexTi2-x(PO4)3-y(BO3)y glass ceramics were 8.85×10-4 and 1.38×10-4S/cm for x = 0.2 and 0.5, respectively. The oxidation state of doped Fe and boric oxide anomaly were due to the enhanced lithium ion conductivity of glass ceramics.

On the Tensor Product of m-Partition Algebras

  • Kennedy, A. Joseph;Jaish, P.
    • Kyungpook Mathematical Journal
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    • v.61 no.4
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    • pp.679-710
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    • 2021
  • We study the tensor product algebra Pk(x1) ⊗ Pk(x2) ⊗ ⋯ ⊗ Pk(xm), where Pk(x) is the partition algebra defined by Jones and Martin. We discuss the centralizer of this algebra and corresponding Schur-Weyl dualities and also index the inequivalent irreducible representations of the algebra Pk(x1) ⊗ Pk(x2) ⊗ ⋯ ⊗ Pk(xm) and compute their dimensions in the semisimple case. In addition, we describe the Bratteli diagrams and branching rules. Along with that, we have also constructed the RS correspondence for the tensor product of m-partition algebras which gives the bijection between the set of tensor product of m-partition diagram of Pk(n1) ⊗ Pk(n2) ⊗ ⋯ ⊗ Pk(nm) and the pairs of m-vacillating tableaux of shape [λ] ∈ Γkm, Γkm = {[λ] = (λ1, λ2, …, λm)|λi ∈ Γk, i ∈ {1, 2, …, m}} where Γk = {λi ⊢ t|0 ≤ t ≤ k}. Also, we provide proof of the identity $(n_1n_2{\cdots}n_m)^k={\sum}_{[{\lambda}]{\in}{\Lambda}^k_{{n_1},{n_2},{\ldots},{n_m}}}$ f[λ]mk[λ] where mk[λ] is the multiplicity of the irreducible representation of $S{_{n_1}}{\times}S{_{n_2}}{\times}....{\times}S{_{n_m}}$ module indexed by ${[{\lambda}]{\in}{\Lambda}^k_{{n_1},{n_2},{\ldots},{n_m}}}$, where f[λ] is the degree of the corresponding representation indexed by ${[{\lambda}]{\in}{\Lambda}^k_{{n_1},{n_2},{\ldots},{n_m}}}$ and ${[{\lambda}]{\in}{\Lambda}^k_{{n_1},{n_2},{\ldots},{n_m}}}=\{[{\lambda}]=({\lambda}_1,{\lambda}_2,{\ldots},{\lambda}_m){\mid}{\lambda}_i{\in}{\Lambda}^k_{n_i},i{\in}\{1,2,{\ldots},m\}\}$ where ${\Lambda}^k_{n_i}=\{{\mu}=({\mu}_1,{\mu}_2,{\ldots},{\mu}_t){\vdash}n_i{\mid}n_i-{\mu}_1{\leq}k\}$.

A NOTE ON GENERALIZED DERIVATIONS AS A JORDAN HOMOMORPHISMS

  • Chandrasekhar, Arusha;Tiwari, Shailesh Kumar
    • Bulletin of the Korean Mathematical Society
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    • v.57 no.3
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    • pp.709-737
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    • 2020
  • Let R be a prime ring of characteristic different from 2. Suppose that F, G, H and T are generalized derivations of R. Let U be the Utumi quotient ring of R and C be the center of U, called the extended centroid of R and let f(x1, …, xn) be a non central multilinear polynomial over C. If F(f(r1, …, rn))G(f(r1, …, rn)) - f(r1, …, rn)T(f(r1, …, rn)) = H(f(r1, …, rn)2) for all r1, …, rn ∈ R, then we describe all possible forms of F, G, H and T.

Enhanced Electrochemical Performance of NaxFe2(CN)6 Positive Electrode Materials for Lithium-ion Batteries (리튬이온 이차전지용 양극물질로서 NaxFe2(CN)6의 전기화학적 성능개선 연구)

  • Yoo, Seong Tae;Yoon, Seung Ju;Kang, Jeong Min;Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.23 no.1
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    • pp.11-17
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    • 2020
  • The Prussian blue analogues of Fe2(CN)6 and NaxFe2(CN)6 are prepared by precipitation method and evaluated the electrochemical characteristics as positive electrode materials for lithium-ion batteries (LIBs) because of their low cost. Fe2(CN)6 shows a low reversible capacity of 34.6 mAh g-1, whereas sodium-containing NaxFe2(CN)6 exhibits a reversible capacity of 107.5 mAh g-1 when the discharge process proceeds first. When charging is first carried out to remove sodium in the structure, the reversible capacity of 114.1 mAh g-1 is achieved and the cycle performance is further improved. In addition, Nax-Fe2(CN)6 is synthesized at 0℃, room temperature (RT), and 60℃, respectively. Regardless of the synthesis temperature, NaxFe2(CN)6 shows similar initial reversible capacity, but the crystallite size is formed smaller and improved cycle performance when synthetic temperature is lower. The sample synthesized at 0℃ shows a reversible capacity of 86.4 mAh g-1 at the 120th cycle and maintains 76.8% of the initial capacity.

Distribution of the extended-spectrum beta-lactamase genes derived from microorganisms in the waterfront environments (주변 수계에서 미생물유래 extended-spectrum beta-lactamase 유전자의 분포)

  • Young-Min Bae
    • Journal of the Korean Applied Science and Technology
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    • v.39 no.6
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    • pp.916-923
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    • 2022
  • Water samples were collected from three spots(Namcheon, Changwoncheon and Cheongwoonji) in Changwon and genomic DNA was isolated from them. Quantitative PCR was performed with the isolated DNA as template and primers targeting five different class A extended-spectrum beta-lactamase(ESBL) genes(blaOXA-1, blaSHV, blaTEM, blaCTX-M-1, blaCTX-M-9). The number of total ESBL genes from each sample showed large variations between each sample. Thirty nanograms of DNA from Namcheon contained 1.93×106 copies of ESBL genes whereas the same amount of DNA from Changwoncheon contained 1.47×105 copies of ESBL genes. However, the same amount of DNA from Cheongwoonji pond contained only 9.5×103 copies of ESBL genes. The ratio of each ESBL genes showed little difference between Namcheon river and Changwoncheon river, but DNA from Cheongwoonji pond showed a large difference from the rest. blaOXA-1 gene was present at 65.3%, and blaCTX-M-1 gene 33.6% for Namcheon comprising together almost 99%. blaOXA-1 gene was present at 64.1%, and blaCTX-M-1 gene 19.1% for Changwoncheon comprising together over 83%. blaCTX-M-1 gene was present at 87.5% and blaCTX-M-9 genes 9.8% for Cheongwoonji, a pond which is a closed and isolated environment.

Microwave Dielectric Properties of (Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 Ceramics ((Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 세라믹스의 마이크로파 유전 특성)

  • Ju Hye Kim;Si Hyun Kim;Eung Soo Kim
    • Korean Journal of Materials Research
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    • v.33 no.8
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    • pp.330-336
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    • 2023
  • The effects of Ni2+ substitution for Mg2+-sites on the microwave dielectric properties of (Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 (0.01 ≤ x ≤ 0.05) (MNTMT) ceramics were investigated. MNTMT ceramics were prepared by conventional solid-state reaction. When the MgO / TiO2 ratio was changed from 1.00 to 1.02, MgTi2O5 was detected as a secondary phase along with the MgTiO3 main phase in the MNTMT specimens sintered at 1,400 ℃ for 4h. For the MNTMT specimens with MgO / TiO2 = 1.07 sintered at 1,400 ℃ for 4h, a single phase of MgTiO3 with an ilmenite structure was obtained from the entire range of compositions. The relative density of all the specimens sintered at 1,400 ℃ for 4h was higher than 95 %. The quality factor (Qf) of the sintered specimens depended strongly on the degree of covalency of the specimens, and the sintered specimens with x = 0.01 showed the maximum Qf value of 489,400 GHz. The dielectric constant (K) decreased with increasing Ni2+ content because Ni2+ had a lower dielectric polarizability (1.23Å3) than Mg2+ (1.32Å3). As Ni2+ content increased, the temperature coefficient of resonant frequency (TCF) improved, from -55.56 to -21.85 ppm/℃, due to the increase in tolerance factor (t) and the lower dielectric constant (K).

ADMISSIBLE BALANCED PAIRS OVER FORMAL TRIANGULAR MATRIX RINGS

  • Mao, Lixin
    • Bulletin of the Korean Mathematical Society
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    • v.58 no.6
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    • pp.1387-1400
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    • 2021
  • Suppose that $T=\(\array{A&0\\U&B}\)$ is a formal triangular matrix ring, where A and B are rings and U is a (B, A)-bimodule. Let ℭ1 and ℭ2 be two classes of left A-modules, 𝔇1 and 𝔇2 be two classes of left B-modules. We prove that (ℭ1, ℭ2) and (𝔇1, 𝔇2) are admissible balanced pairs if and only if (p(ℭ1, 𝔇1), h(ℭ2, 𝔇2) is an admissible balanced pair in T-Mod. Furthermore, we describe when ($P^{C_1}_{D_1}$, $I^{C_2}_{D_2}$) is an admissible balanced pair in T-Mod. As a consequence, we characterize when T is a left virtually Gorenstein ring.