• Nuclear Engineering and Technology
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• v.54 no.10
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• pp.3641-3649
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• 2022

A simple solvothermal reaction was used to prepare a 3-aminopropyl-functionalized silica-gel-based adsorbent for adsorbing Pd(II) from the nitric acid solution. Scanning electron microscopy, fourier transform infrared spectroscopy, and thermogravimetry analysis were performed on the as-synthesized adsorbent to demonstrate the successful introduction of Schiff base groups. Batch experiments were used to investigate the effects of contact time, nitric acid concentration, solution temperature, and adsorption capacity. It is worth noting that the prepared adsorbent exhibited a higher affinity toward Pd(II) with the uptake approximately 100% even in a 2 M HNO₃ solution. At an equilibrium time of 5 h, the maximum adsorption capacity of Pd(II) was estimated to be 0.452 mmol/g. The adsorbed Pd(II) could be completely eluted by dissolving 0.2 M thiourea solution in 0.1 M HNO₃. Using a combination of particle-induced X-ray emission analysis and an X-ray photoelectron spectrometer, the adsorbed Pd was found to be uniformly distributed on the surface of the prepared adsorbent and the existing species were Pd(II) and zero-valent Pd(0). Due to the desirable performances, facile preparation method, and abundant raw material source, the prepared adsorbent demonstrated a high application potential in the recovery of Pd(II) from simulated high-level liquid waste treatment.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.617-620
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• 2008

When fresh concrete is exposed to the cold weather, the concrete may happen frost damage because of freezing at early ages and the strength development may be go down. Therefore, this paper is intend to investigate the properties and availabilities of cold weather concrete using anti-freeze based formate-acetate for ensure of excellent concrete quality on cold temperature. According to test result for concrete in anti-freeze agent, strength properties in sub-zero temperature increases in comparison with concrete of non anti-freeze agent without decline of strength until later age. When anti-freezing agent is added by 3.0% to binder, it gives good effects on the performance of the fresh and harden concrete.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.4
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• pp.462-469
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• 2016

This paper presents the results of thermodynamic cycle analysis and performance tests of alternative mixtures in low temperature applications. Two near-azeotropic binary mixtures R-152a/R-1270 (35:65 by wt.%) and R-290/E170 (35:65 by wt.%) are considered in this study. They have zero ODP (Ozone Depletion Potential) and much lower GWP (Global Warming Potential) than R-404A which is an alternative of R-502. Refrigeration cycle characteristics such as cooling capacity, coefficient of performance, suction and discharge pressures and temperatures are compared to those for the baseline refrigerants (R-502 and R-404A) cycles. The performance tests are conducted at the evaporation and condensation temperatures of $5^{\circ}C$ and $45^{\circ}C$, subcooling and superheating temperatures of $5^{\circ}C$, respectively. Performance comparisons between baseline and alternative refrigerants are conducted on the same cooling capacity. The system performance of newly proposed refrigerant mixtures show promising results.

• Korean Journal of Metals and Materials
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• v.47 no.3
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• pp.169-174
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• 2009

The effect of sub zero treatment on the damping capacity in austempered ductile cast iron investigated. Austenite transformed in to martensite by subzero treatment, and with the decrease of subzero treatment temperature, volume fraction of martensite increased. Damping capacity of austempered ductile cast iron was highly increased by subzero treatment, with the decrease of subzero treatment temperature, damping capacity was slowly increased. With the decrease of subzero treatment time, damping capacity was rapidly increased to 30 min. and then slowly increased. With the increase of volume fraction of martensite, damping capacity rapidly increasing to 5% and then slowly increased.

• Atmosphere
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• v.26 no.1
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• pp.35-45
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• 2016

Initialization of the global seasonal forecast system is as much important as the quality of the embedded climate model for the climate prediction in sub-seasonal time scale. Recent studies have emphasized the important role of soil moisture initialization, suggesting a significant increase in the prediction skill particularly in the mid-latitude land area where the influence of sea surface temperature in the tropics is less crucial and the potential predictability is supplemented by land-atmosphere interaction. This study developed a new soil moisture initialization method applicable to the KMA operational seasonal forecasting system. The method includes first the long-term integration of the offline land surface model driven by observed atmospheric forcing and precipitation. This soil moisture reanalysis is given for the initial state in the ensemble seasonal forecasts through a simple anomaly initialization technique to avoid the simulation drift caused by the systematic model bias. To evaluate the impact of the soil moisture initialization, two sets of long-term, 10-member ensemble experiment runs have been conducted for 1996~2009. As a result, the soil moisture initialization improves the prediction skill of surface air temperature significantly at the zero to one month forecast lead (up to ~60 days forecast lead), although the skill increase in precipitation is less significant. This study suggests that improvements of the prediction in the sub-seasonal timescale require the improvement in the quality of initial data as well as the adequate treatment of the model systematic bias.

• Journal of the Korean Magnetics Society
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• v.13 no.5
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• pp.187-192
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• 2003

The magnetic and thermal properties of NiFe/[IrMn-Mn]/CoFe with Mn additions have been studied. As-deposited CoFe pinned layers with [IrMn-Mn]layer had dominantly larger exchange biasing field ( $H_{ex}$) and blocking temperature ( $T_{b}$) than those with pure I $r_{22}$M $n_{78}$ used. The $H_{ex}$ and $T_{b}$ improved with 76.8-78.1 vol% Mn, but those of the NiFe/IrMn/CoFe dropped considerably with more addition of 0.6 vol % Mn. The average x-ray diffraction peak ratios of fcc [(111)CoFe, NiFe]/(111)IrM $n_3$ textures for the Mn inserted total vol of 75.5, 77.5, and 79.3% were about 1.4, 0.8, and 0.6, respectively. For the sample without Mn inserted layer, the $H_{ex}$ between IrMn and CoFe layers was almost zero, but it increased to 100 Oe after annealing of 250 $^{\circ}C$. For as-grown two multilayers samples with ultra-thin Mn layers of 77.5 and 78.7 vol %, the $H_{ex}$s were 259 and 150 Oe, respectively. In case of IrMn with 77.5 vol% Mn, the $H_{ex}$ was increased up to 475 Oe at 350 $^{\circ}C$ but decreased to 200 Oe at 450 $^{\circ}C$, respectively. The magnetic properties and thermal stabilities of NiFe/[IrMn-Mn]/CoFe multilayer were enhanced with Mn additions. In applications where higher $H_{ex}$ and $T_{b}$ are required, proper contents of Mn can be used. be used. used.

• Journal of the Korean GEO-environmental Society
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• v.17 no.1
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• pp.49-54
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• 2016

An active layer distributed on surface of an extreme cold region causes a frost heave by repeating the freezing and thawing according to the seasonal temperature change. Since the height of frost heave is greatly affected by the thickness of active layer, an accurate evaluation of the thickness of active layer is necessary for the safe design and construction of the infrastructure in the extreme cold region. In this study, dynamic cone penetrometer, which is miniaturized in-situ penetration device, is applied for the evaluation of active layer depth distribution. As the application tests, two dynamic cone penetration tests were conducted on the study sites located in Solomon and Alaska. In addition, ground temperature variations were obtained. As the results of the application tests, the depth of interface between the active layer and the permafrost was evaluated from the difference in dynamic cone penetration indexes of the active layer and the permafrost, and a layer was detected around the interface considered as an ice lens layer. Also, the interface depths between the above zero and the below zero temperature determined from the ground temperature variations correspond with the interface depths evaluated from the dynamic cone penetration tests. This study demonstrates that the dynamic cone penetrometer may be a useful tool for the evaluation of the active layer in the extreme cold region.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1001-1004
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• 2008

This study reviewed the results of utilization of insulation heat curing method using double layer bubble sheet in slab concrete and mass concrete in cold weather environment. First of all, when double layer bubble sheets are applied, it was shown that slab concrete was protected from early freezing by remaining between 6 and $10^{\circ}C$ even in case outside temperature drops $10^{\circ}C$ below zero until the 2nd day from piling, and in the case of mass concrete, with the maximum temperature difference between the center and surface less than $6^{\circ}C$, crack occurrence index was close to 2 and no hydration heat crack occurred by internal constraint. The insulation heat preservation curing method using the double bubble sheet applied in this field prevented early freezing owing to stable curing temperature management, deterring concrete strength development delay at low temperature, and obtained the needed strength. Also, it was proven that the method is highly effective and economic for cold weather concrete quality maintenance through curing cost reduction like construction period shortening and labor cost reduction, etc by reducing the process of temporary equipment installation and disassembling.

• Korean Journal of Agricultural and Forest Meteorology
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• v.23 no.4
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• pp.198-221
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• 2021

After large-scale reforestation in the 1960s and 1970s, forests in Korea have gradually been aging. Net ecosystem CO₂ exchange of old-growth forests is theoretically near zero; however, it can be a CO₂ sink or source depending on the intervention of disturbance or management. In this study, we report the CO₂ budget dynamics of the Gwangneung deciduous old-growth forest (GDK) in Korea and examined the following two questions: (1) is the preserved GDK indeed CO₂ neutral as theoretically known? and (2) can we explain the dynamics of CO₂ budget by the common mechanisms reported in the literature? To answer, we analyzed the 15-year long CO₂ flux data measured by eddy covariance technique along with other biometeorological data at the KoFlux GDK site from 2006 to 2020. The results showed that (1) GDK switched back-and-forth between sink and source of CO₂ but averaged to be a week CO₂ source (and turning to a moderate CO₂ source for the recent five years) and (2) the interannual variability of solar radiation, growing season length, and leaf area index showed a positive correlation with that of gross primary production (GPP) (R²=0.32~0.45); whereas the interannual variability of both air and surface temperature was not significantly correlated with that of ecosystem respiration (RE). Furthermore, the machine learning-based model trained using the dataset of early monitoring period (first 10 years) failed to reproduce the observed interannual variations of GPP and RE for the recent five years. Biomass data analysis suggests that carbon emissions from coarse woody debris may have contributed partly to the conversion to a moderate CO₂ source. To properly understand and interpret the long-term CO₂ budget dynamics of GDK, new framework of analysis and modeling based on complex systems science is needed. Also, it is important to maintain the flux monitoring and data quality along with the monitoring of coarse woody debris and disturbances.

• Journal of the Korean Geotechnical Society
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• v.25 no.10
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• pp.31-40
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• 2009

As the measurement of strain-gage type cone penetrometer is influenced by the temperature change during penetration, the temperature is a factor producing an error of the cone tip resistance. In this study, the 0.5 mm diameter temperature transducer and 7 mm diameter micro cone penetrometer are manufactured by using FBG sensors to evaluate the effect of temperature on the cone tip resistance. Design concepts include the cone configuration, sensor installation and the temperature compensation process. The test shows that the tip resistance measured by strain gauge is affected by the temperature change. The error of the tip resistance increases with an increase in temperature change, while the temperature effect on the tip resistance of FBG cone is effectively compensated by using FBG temperature transducer. Temperature compensated tip resistance of the strain gauge cone shows the good matched profile with FBG cone which performs real-time temperature compensation during penetration. This study demonstrates that the temperature compensation by using FBG sensor is an effective method to produce the more reliable cone tip resistance.