• Title/Summary/Keyword: Structured surface

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Growth mechanism of three dimensionally structured TiO2 thin film for gas sensors (가스 감응용 3차원 구조체 TiO2 박막 성장기구)

  • Moon, Hi-Gyu;Yoon, Seok-Jin;Park, Hyung-Ho;Kim, Jin-Sang
    • Journal of Sensor Science and Technology
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    • v.18 no.2
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    • pp.110-115
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    • 2009
  • Polystyrene (PS) microspheres were used to good advantage as a template material to prepare macroporous $TiO_2$ thin films. This is enabled to run the thermal decomposition of the PS without the collapsing of the 3-D macroporous framework during the calcination step. $TiO_2$ thin films were deposited onto the colloidal templated substrates at room temperature by RF sputtering, and then samples were thermally treated at $450^{\circ}C$ for 40.min in air to remove the organic colloidal template and induce crystallization of the $TiO_2$ film. The macroporous $TiO_2$ thin film exhibited a quasi-ordered partially hexagonal close-packed structure. Burst holes, estimated to be formed during PS thermal decomposition, are seen as the hemisphere walls. the inner as well as the outer surfaces of the hollow hemispheres formed by the method of thermal decomposition can be easily accessed by the diffusing gas species. As a consequence, the active surface area interacting with the gas species is expected to be enlarged about by a factor of fourth as large as compared to that of a planar films. Also the thickness at neighboring hemisphere could be controlled a few nm thickness. If the acceptor density becomes as large that depletion width reaches those thickness, the device is in the pinch off-situation and a strong resistance change should be observed.

Forced Convective Boiling of Pure Refrigerants in a Bundle of Enhanced Tubes (전열촉진관군의 순수냉매 강제대류비등)

  • Kim, Nae-Hyeon;Jeong, Ho-Jong;Jo, Jin-Pyo;Choe, Guk-Gwang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.12
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    • pp.1831-1843
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    • 2001
  • In this study, convective boiling tests were conducted for enhanced tube bundles. The surface geometry consists of pores and connecting gaps. Tubes with three different pore sizes (d$_{p}$ = 0.20, 0.23 and 0.27 mm) were tested using R-123 and R-l34a for the following range: 8 kg/m$^2$s G 26 kg/m$^2$s, 10 kW/m$^2$ q0 40 kW/m$^2$and 0.1 $\chi$ 0.9. The convective boiling heat transfer coefficients were strongly dependent on heat flux with negligible dependency on mass flux or quality. For the present enhanced geometry (pores and gaps), the convective effect was apparent. The gaps of the present tubes may have served routes for the passage of two-phase mixtures, and enhanced the boiling heat transfer. The convective effect was more pronounced at a higher saturation temperature. More bubbles will be generated at a higher saturation temperature, which will lead to enhanced convective contribution. The pore size where the maximum heat transfer coefficient was obtained was larger for R-l34a (d$_{p}$ = 0.27 mm) compared with that for R-123 (d$_{p}$ = 0.23 mm). This trend was consistent with the previous pool boiling results. For the enhanced tube bundles, the convective effect was more pronounced for R-134a than for R-123. This trend was reversed for the smooth tube bundle. Possible reasoning is provided based on the bubble behavior on the tube wall. Both the modified Chen and the asymptotic model predicted the present data reasonably well. The RMSEs were 14.3% for the modified Chen model and 12.7% for the asymptotic model.model.

Development of Infiltration System for Stormwater Management from Paved Area (포장지역 강우유출수 관리를 위한 침투도랑 기술개발)

  • Lee, Jeong-Yong;Maniquiz, Marla C.;Lee, So-Young;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.12 no.3
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    • pp.165-175
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    • 2010
  • Recently, various development projects have occurred due to rapid industrialization and urbanization. Both industry and population grew rapidly which causes a corresponding rise in pollution. The accumulated pollutants are washed-off during rainy days, highly degrading the water quality of the receiving water body. This is because a lot of non point source (NPS) pollutants were accumulated on the surface during dry periods. This research focuses on the development of Eco-Bio Filter (EBF) system that treats NPS pollutants. It is constructed at Kongju National University campus. The EBF is a type of a structured infiltration system that falls under the category of Low Impact Development (LID) hydrologic design practices. The monitoring of rain events was performed. It includes the development of design, the lessons learned from the post-construction testing and the improvements in the renovation made. After a series of monitoring, the MOE will use the results to apply the design to other areas in the country.

Anti-cancer effects of enzyme-digested fucoidan extract from seaweed Mozuku

  • Teruya, Kiichiro;Matsuda, Sakiko;Nakano, Ayumi;Nishimoto, Takuya;Ueno, Masashi;Niho, Akitono;Yamashita, Makiko;Eto, Hiroshi;Katakura, Yoshinori;Shirahata, Sanetaka
    • Korean Journal of Agricultural Science
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    • v.36 no.1
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    • pp.41-50
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    • 2009
  • Fucoidan is a uniquely-structured sulfated fucose-rich polysaccharide derived from brown algae. Recently, the abalone glycosidase-digested fucoidan extract (fucoidan extract) derived from seaweed Cladosiphon novae-caledoniae Kylin (Mozuku) draws much attention because of its clinical anti-cancer effect in Japan. Here, we report the cancer cells-specific apoptosis inducing effects of the fucoidan extract. The fucoidan extract suppressed the growth of various anchorage-dependent and -independent cancer cells. The fucoidan extract contained low molecular weight components, which induced apoptosis of human leukemic HL 60 cells but not of human lymphocytes. It was shown that the fucoidan extract lead caspase 3/7 activation and loss of mitochondrial membrane potential in HL 60 cells. Another function of the fucoidan extract was also observed. It has been known that sugar chain expression on the surface of cancer cell membrane changes dependent on their malignancy. The analysis on sugar chain expression profiling using FITC-labeled lectins revealed that the expression of concanavalin A (Con A) binding sugar chain was enhanced by the treatment of human lung adenocarcinoma A549, human uterine carcinoma HeLa and human fibrosarcoma HT1080 cells with the fucoidan extract. Con A-induced apoptosis of cancer cells was stimulated in a dose-and time-dependent manner by the treatment with the fucoidan extract but not of human normal fibroblast TIG-1 cells.

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Temperament by MBTI Personality Types, Learning Styles and Learning Strategies in Nursing Students (간호대학생의 MBTI 성격유형별 기질과 학습유형 및 학습전략)

  • Jang, Hyun-Jung;Kim, Myung-Ae
    • The Journal of the Korea Contents Association
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    • v.14 no.9
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    • pp.400-410
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    • 2014
  • The purpose of this study is to investigate temperament by MBTI personality types, learning styles and learning strategies in nursing students. The subjects of this study were 245 nursing students. The data were collected structured questionnaire including MBTI test, 42-items of learning styles and 25-items of learning strategies. According to correspondence with their ideas, the subjects were completed self reported items of 1-6points scale. According to the results, the highest personality type in subjects was ESFJ and the highest personality temperament type was SJ. The study results showed that there were significant difference among surface type, depth-type and performance-type by analyzing learning styles to each personality temperament. Learning strategies by personality temperament also were significant difference in a demonstration, elaboration, organization, and higher cognition. Based on the results of this study, it is necessary to develop and apply appropriate learning method and learning strategies for the individual.

Growth of Amorphous SiOx Nanowires by Thermal Chemical Vapor Deposition Method (열화학 기상 증착법에 의한 비정질 SiOx 나노와이어의 성장)

  • Kim, Ki-Chul
    • Journal of Convergence for Information Technology
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    • v.7 no.5
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    • pp.123-128
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    • 2017
  • Nanostructured materials have received attention due to their unique electronic, optical, optoelectrical, and magnetic properties as a results of their large surface-to-volume ratio and quantum confinement effects. Thermal chemical vapor deposition process has attracted much attention due to the synthesis capability of various structured nanomaterials during the growth of nanostructures. In this study, silicon oxide nanowires were grown on Si\$SiO_2$(300 nm)\Pt(5~40 nm) substrates by two-zone thermal chemical vapor deposition with the source material $TiO_2$ powder via vapor-liquid-solid process. The morphology and crystallographic properties of the grown silicon oxide nanowires were characterized by field-emission scanning electron microscope and transmission electron microscope. As results of analysis, the morphology, diameter and length, of the grown silicon oxide nanowires are depend on the thickness of the catalyst films. The grown silicon oxide nanowires exhibit amorphous phase.

Synthesis of Nano Structured Silica and Carbon Materials and Their Application (계면활성제를 이용한 나노 실리카 및 카본 소재의 합성과 응용)

  • Park Seungkyu;Kim Jongyun;Cho Wangoo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.321-328
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    • 2004
  • Nano silica ball and nano carbon ball are developed commercially by template synthesis method. Adsorption of unpleasant smelling substances such as ammonia, trimethylamine, acetaldehyde and methyl mercaptane onto nano carbon ball with hollow macroporous core/mesoporous shell structures, nano carbon ball, was investigated and compared with that onto odor adsorbent materials, activated carbon, commercially available. The adsorption and decomposition of malodor at nano carbon ball exhibited superior than those onto activated carbon. The physicochemical properties such as mesopore size distributions, large nitrogen BET specific surface area and large pore volume and decomposition of malodor were studied to interpret the predominant adsorption performance. The nano carbon ball is expected to be useful in many applications such as deodorizers, adsorbent of pollutants.

Properties Optimization for Perovskite Oxide Thin Films by Formation of Desired Microstructure

  • Liu, Xingzhao;Tao, Bowan;Wu, Chuangui;Zhang, Wanli;Li, Yanrong
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.715-723
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    • 2006
  • Perovskite oxide materials are very important for the electronics industry, because they exhibit promising properties. With an interest in the obvious applications, significant effort has been invested in the growth of highly crystalline epitaxial perovskite oxide thin films in our laboratory. And the desired structure of films was formed to achieve excellent properties. $Y_1Ba_2Cu_3O_{7-x}$ (YBCO) superconducting thin films were simultaneously deposited on both sides of 3 inch wafer by inverted cylindrical sputtering. Values of microwave surface resistance R$_2$ (75 K, 145 GHz, 0 T) smaller than 100 m$\Omega$ were reached over the whole area of YBCO thin films by pre-seeded a self-template layer. For implementation of voltage tunable high-quality varactor, A tri-layer structured SrTiO$_3$ (STO) thin films with different tetragonal distortion degree was prepared in order to simultaneously achieve a large relative capacitance change and a small dielectric loss. Highly a-axis textured $Ba_{0.65}Sr_{0.35}TiO_3$ (BST65/35) thin films was grown on Pt/Ti/SiO$_2$/Si substrate for monolithic bolometers by introducing $Ba_{0.65}Sr_{0.35}RuO_3$ (BSR65/35) thin films as buffer layer. With the buffer layer, the leakage current density of BST65/35 thin films were greatly reduced, and the pyroelectric coefficient of $7.6\times10_{-7}$ C $cm^{-2}$ $K^{-1}$ was achieved at 6 V/$\mu$m bias and room temperature.

Pressure-infiltration of Fe3O4-nanoparticles Into Porous Silicon and a Packing Density Monitoring Technique (다공성실리콘내 Fe3O4 나노입자의 압력침착과 채움밀도 모니터링 방법)

  • Lee, Joo Hyeon;Lee, Jae Joon;Lee, Ki Won
    • Journal of Sensor Science and Technology
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    • v.24 no.6
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    • pp.385-391
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    • 2015
  • In this paper, we propose a new method to infiltrate $Fe_3O_4$-nanoparticles into a porous silicon film and a monitoring technique to detect packing density of nanoparticles within the film. Recently, research to use porous silicon as a drug carrier or a new functional sensor material by infiltrating $Fe_3O_4$-nanoparticles has been extensively performed. However, it is still necessary to enhance the packing density and to develop a monitoring technique to detect the packing density in real time. In this light, we forcibly injected a nanoparticle solution into a rugate-structured free-standing porous silicon (FPS) film by applying a pressure difference between the two sides of the film. We found that the packing density by the pressure-infiltration method proposed in this paper is enhanced, relative to that by the previous diffusion method. Moreover, a continuous shift in wavelength of the rugate reflectance peak measured from the film surface was observed while the nanoparticle solution was being injected. By exploiting this phenomenon, we could qualitatively monitor the packing density of $Fe_3O_4$-nanoparticles within the FPS film with the injection volume of the nanoparticle solution.

Characteristics of Chronic Sensory Abnormalities in Korean Burn Patients (한국인에서 화상 후 만성 감각이상의 특징에 대한 연구)

  • Kim, Hyeong Seok;Chang, Hyun Mook;Choi, Do Young;Woo, Chul Ho;Mun, Sung Ha;Kim, Hyun Soo;Kim, Kwang Min
    • The Korean Journal of Pain
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    • v.20 no.2
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    • pp.158-162
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    • 2007
  • Background: After burn patients are discharged from the hospital, they may continue to feel pain and paresthetic sensations at the site of a healed burn and these problems may persist for years. This study was designed to describe the characteristics of these symptoms in terms of intensity, frequency, and influencing factors. Methods: Patients that developed paresthetic sensations at sites of a healed burn were recruited from the pain management center from January 2003 to April 2006. Data was collected using a structured interview protocol. Results: Fifty one adults, with a total body surface area burned (TBSA) of $21.1{\pm}16.3%$ aged $42.0{\pm}12.9$ years were studied. A paresthetic sensation was reported to be present every day in 52.9% (27/51) of the subjects. A variation in the intensity was most commonly related to changes in the weather. A tight sensation and itching types of sensations were significantly more frequent in patients with more extensive injuries. Conclusions: Recognition and understanding of the chronic paresthetic sensation that many burn patients continue to experience at sites of a healed burn deserve further attention. Not only do clinicians need to be aware of these problems but also strategies for prevention and alleviation shou\d be explored.