• 제목/요약/키워드: Structural transition

검색결과 718건 처리시간 0.039초

The Effect of Cr doping on the Magnetic and Magnetocaloric Properties of MnCoGe Alloys

  • Emre, S. Yuce
    • Journal of Magnetics
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    • 제18권4호
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    • pp.405-411
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    • 2013
  • The structural, magnetic and magnetocaloric properties of $CoMn_{1-x}Cr_xGe$ (x=0.05-0.125) have been investigated by using electron microscopy, x-ray diffraction, calorimetric and magnetic measurements. In this study, our aim is to justify the magnetocaloric effect by tuning the structural and magnetic transition temperature with Cr doping on CoMnGe pure system. The substitution of Cr for Mn leads to a decrease of both structural and magnetic transition temperatures. However, structural and magnetic transition temperatures do not close to each other. From magnetization measurement, we calculate that isothermal entropy change associated with magnetic transition can be as high as 3.82 J $kg^{-1}K^{-1}$ at 302 K in a field of 7 T. Meanwhile, structural phase transition contribution to isothermal entropy change is calculated as 5.85 J $kg^{-1}K^{-1}$ at 322 K for 7 T.

Comparative study on the structural behavior of a transition piece for offshore wind turbine with jacket support

  • Ma, Chuan;Zi, Goangseup
    • Steel and Composite Structures
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    • 제43권3호
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    • pp.363-373
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    • 2022
  • As a key reinforcement connection between a tower and a substructure in offshore wind turbine system, the transition piece is inevitably subjected to cyclic dynamic environmental loads such as wind, current and wave. Therefore, well designed transition piece with high strength and good fatigue resistance is of great significance to the structural safety and reliability of offshore wind power systems. In this study, the structural behavior of the transition piece was studied by an extensive sets of finite element analyses. Three widely used types of transition piece were considered. The characteristics of stress development, fatigue life and weight depending on the type of the transition piece were investigated in the ultimate limit state (ULS) and the fatigue limit state (FLS) of a 5-MW offshore wind turbine to be placed in Korea. An optimal form of the transition piece was proposed based on this parametric study.

철도교량 단부 전환부 궤도시스템의 구조적 거동특성 및 장기 내구성능 분석 (Evaluation of the Structural Behavior Characteristics and Long Term Durability for Transition Track Systems in Railway Bridge Deck Ends)

  • 이광도;정인철;최정열;박용걸
    • 한국철도학회논문집
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    • 제17권4호
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    • pp.260-269
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    • 2014
  • 본 논문의 목적은 철도교량 단부 전환부 궤도의 구조적 거동특성을 평가하는 것이다. 국내 고속철도 교량상 궤도표준단면을 이용하여 전환부 궤도구조를 설계 및 제작하여 피로시험 전, 후에 대한 전환부 궤도시스템의 중립축 및 동특성(고유진동수 및 감쇠비)의 변화를 비롯하여 피로균열 발생경향을 수치해석 결과와 비교, 검토하였다. 연구결과, 국내 고속철도 궤도설계기준을 준용하여 설계한 전환부 궤도시스템에 대한 동특성을 실험적으로 산정하였으며 국내 철도하중 및 충격효과를 고려한 피로하중에 대한 구조적 건전성을 실험 및 해석적으로 입증하였다.

Synthesis and Temperature-Dependent Local Structural Properties of Ti2O3

  • Hwang, Inhui;Jin, Zhenlan;Park, Changin;Jiang, Bingzhi;Han, S.W.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.202.2-202.2
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    • 2013
  • Ti2O3 is known as a typical Mott insulator with a transition temperature of near $200^{\circ}C$. Unlike VO2, Ti2O3 does not have a structural phase transition near the metal-insulator-transition (MIT) temperature. We investigated the temperature-dependent thermal vibration change using temperature-dependent x-ray absorption fine structure (XAFS) at Ti K-edge in the temperature range of 300~600 K. Ti2O3 powder and films were synthesized using thermal chemical vapor deposition (CVD) at $800{\sim}900^{\circ}C$. X-ray diffraction measurements show a single phased Ti2O3 at room temperature. XAFS confirmed no structural phase transition in the temperature of 300~600 K. A small but distinguishable structural disorder change was observed near the transition temperature. We will discuss the MIT behavior with the change of structural disorder.

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Fabrication, temperature-dependent local structural and electrical properties of VO2 thin films

  • Jin, Zhenlan;Hwang, In-Hui;Park, Chang-In;Han, Sang-Wook
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.169.2-169.2
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    • 2015
  • $VO_2$ is a well-known a metal-to-insulator-transition (MIT) material, accompanied with a first order structural phase transition near room temperature. Because of the structural phase transition and the MIT occur near a same temperature, there is an ongoing argument whether the MIT is induced by the structural phase transition. $VO_2$ exhibits a relatively weak anti-oxidization ability and can be oxidized to higher-valence oxides (e.g., $V_4$ $O_7$ or $V_2$ $O_5$) when annealed at a high temperature in an oxygen-rich atmosphere. We fabricated $VO_2$ films on $Al_2$ $O_3$ (0001) substrates using a DC magnetron sputtering deposition process with carefully control the $O_2$ percentage in an atmosphere. X-ray diffraction measurements from the films showed only (0l0) peaks with no extra peaks, indicating b-oriented films. The temperature-dependent local structural properties of $VO_2$ films were investigated by using in-situ X-ray absorption fine structure (XAFS) measurements at the V K edge. XAFS revealed that the structural phase transition was occurred nearly $70^{\circ}C$ for heating process and reproducible. Resistance measurements as a function of temperature (R-T) demonstrated that the resistance of $VO_2$ films was changed by a factor of 4 near $75^{\circ}C$ which was higher than $68^{\circ}C$ reported from a $VO_2$ bulk. We will discuss the MIT of $VO_2$ films, comparing with the local structural properties determined by XAFS measurements.

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Investigation on the phase transition of $Ni_2$MnGa alloy by using impedance spectroscopy

  • Park, S.Y.;Cho, K.H.;Lee, Y.P.
    • Journal of Korean Vacuum Science & Technology
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    • 제7권1호
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    • pp.13-17
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    • 2003
  • The influence of structural transition on the resistance and impedance behavior of Ni$_2$MnGa alloy was investigated. The temperature-dependent resistance and impedance were measured in a temperature range of 4 - 350 K and 185 - 300 K, respectively. The dependence of temperature coefficient of resistivity on temperature shows a kink at 220 K, which is related to the structural transition. The change in dominant scattering mechanism results in the observed kink. Significant increases were also observed around the transition temperature for both real and imaginary parts of impedance. It is thought that this phenomenon originates from disappearance of the martensite twin boundaries during the structural transformation.

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Factors Affecting the Magnitude of the Metal-Insulator Transition Temperature in AMo4O6 (A=K, Sn)

  • Jung, Dong-Woon;Choi, Kwang-Sik;Kim, Sung-Jin
    • Bulletin of the Korean Chemical Society
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    • 제25권7호
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    • pp.959-964
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    • 2004
  • A low-dimensional metal frequently exhibits a metal-insulator transition through a charge-density-wave (CDW) or a spin-density-wave (SDW) which accompany it's structural changes. The transition temperature is thought to be determined by the amount of energy produced during the transition process and the softness of the original structure. $AMo_4O_6$ (A=K, Sn) are known to be quasi-one dimensional metals which exhibit metalinsulator transitions. The difference of the transition temperatures between $KMo_4O_6$ and $SnMo_4O_6$ (A=K, Sn) is examined by investigating their electronic and structural properties. Fermi surface nesting area and the lattice softness are the governing factors to determine the metal-insulator transition temperature in $AMo_4O_6$ compounds.

적응적 체눈 세분화를 위한 3차원 입체 변이요소 (3-D Transition Solid Elements For Adaptive Mesh Gradation)

  • 최창근;이남호
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1993년도 봄 학술발표회논문집
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    • pp.3-10
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    • 1993
  • A new three-dimensional transition solid elements was presented for the automated three-dimensional adaptive h-refinement where the steep stress gradient exists. To be consistent with 8-node solid element with nonconforming modes in accuracy, these transition elements were improved through the addition of the associated nonconforming modes. Numerical examples show that the performance of the element and the applicability to 3D adaptations are satisfactory.

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에피택셜 VO2 박막의 상전이에 대한 미시적 이해 (Nanoscopic Understanding of Phase Transition of Epitaxial VO2 Thin Films)

  • 김동욱;손아름
    • 한국표면공학회지
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    • 제50권3호
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    • pp.141-146
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    • 2017
  • We investigated configuration of metallic and insulating domains in $VO_2$ thin films, while spanning metal-insulator phase transition. Kelvin probe force microscopy, of which spatial resolution is less than 100 nm, enables us to measure local work function (WF) at the sample surface. The WF of $VO_2$ thin films decreased (increased) as increasing (decreasing) the sample temperature, during the phase transition. The higher and lower WF regions corresponded to the insulating and metallic domains, respectively. The metallic fraction, estimated from the WF maps, well explained the temperature-dependent resistivity based on the percolation model. The WF mapping also showed us how the structural defects affected the phase transition behaviors.

Mixed 형태의 정식화에 기초한 회전자유도를 가진 변이 평면요소 (Transition membrane elements with drilling freedom based on mixed-type formulation)

  • 최창근;이완훈
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1993년도 가을 학술발표회논문집
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    • pp.8-15
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    • 1993
  • The transition membrane elements with drilling freedom have been developed. The functionals for the linear problem, in which the drilling rotations are introduced as independent variables, have been presented by Hughes & Bressi. And 4-node membrane elements with drilling degrees of freedom were developed by Ibrahimbegovic. The transition elements can be efficiently used in modelling the in-plane structures, in particular, where the stress concentration exists. A modified Gaussian quadrature adopted to evaluate the stiffness matrices of these transition elements which have slope discontinuity of displacement within the elements. Detailed numerical studies show the excellent performance of the transition elements.

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