• Title/Summary/Keyword: Structural holes

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Fabrication and Characterization of InGaN/GaN LED structures grown on selectively wet-etched porous GaN template layer

  • Beck, Seol;Cho, Yong-Hoon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.124-124
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    • 2010
  • Much interest has been focused on InGaN-based materials and their quantum structures due to their optoelectronics applications such as light emitting diode (LED) and photovoltaic devices, because of its high thermal conductivity, high optical efficiency, and direct wide band gap, in spite of their high density of threading dislocations. Build-in internal field-induced quantum-confined Stark effect in InGaN/GaN quantum well LED structures results in a spatial separation of electrons and holes, which leads to a reduction of radiative recombination rate. Therefore, many growth techniques have been developed by utilizing lateral over-growth mode or by inserting additional layers such as patterned layer and superlattices for reducing threading dislocations and internal fields. In this work, we investigated various characteristics of InGaN multiple quantum wells (MQWs) LED structures grown on selectively wet-etched porous (SWEP) GaN template layer and compared with those grown on non-porous GaN template layer over c-plane sapphire substrates. From the surface morphology measured by atomic force microscope, high resolution X-ray diffraction analysis, low temperature photoluminescence (PL) and PL excitation measurements, good structural and optical properties were observed on both LED structures. However, InGaN MQWs LED structures grown on SWEP GaN template layer show relatively low In composition, thin well width, and blue shift of PL spectra on MQW emission. These results were explained by rough surface of template layer, reduction of residual compressive stress, and less piezoelectric field on MQWs by utilizing SWEP GaN template layer. Better electrical properties were also observed for InGaN MQWs on SWEP GaN template layer, specially at reverse operating condition for I-V measurements.

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Photocatalytic Properties of the Ag-Doped TiO2 Prepared by Sol-Gel Process/Photodeposition (졸-겔공정/광증착법을 이용한 Ag-Doped TiO2 합성 및 광촉매 특성)

  • Kim, Byeong-Min;Kim, Jung-Sik
    • Korean Journal of Materials Research
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    • v.26 no.2
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    • pp.73-78
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    • 2016
  • $TiO_2$ nanoparticles were synthesized by a sol-gel process using titanium tetra isopropoxide as a precursor at room temperature. Ag-doped $TiO_2$ nanoparticles were prepared by photoreduction of $AgNO_3$ on $TiO_2$ under UV light irradiation and calcinated at $400^{\circ}C$. Ag-doped $TiO_2$ nanoparticles were characterized for their structural and morphological properties by X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). The photocatalytic properties of the $TiO_2$ and Ag-doped $TiO_2$ nanoparticles were evaluated according to the degree of photocatalytic degradation of gaseous benzene under UV and visible light irradiation. To estimate the rate of photolysis under UV (${\lambda}=365nm$) and visible (${\lambda}{\geq}410nm$) light, the residual concentration of benzene was monitored by gas chromatography (GC). Both undoped/doped nanoparticles showed about 80 % of photolysis of benzene under UV light. However, under visible light irradiation Ag-doped $TiO_2$ nanoparticles exhibited a photocatalytic reaction toward the photodegradation of benzene more efficient than that of bare $TiO_2$. The enhanced photocatalytic reaction of Ag-doped $TiO_2$ nanoparticles is attributed to the decrease in the activation energy and to the existence of Ag in the $TiO_2$ host lattice, which increases the absorption capacity in the visible region by acting as an electron trapper and promotes charge separation of the photoinduced electrons ($e^-$) and holes ($h^+$). The use of Ag-doped $TiO_2$ nanoparticles preserved the option of an environmentally benign photocatalytic reaction using visible light; These particles can be applicable to environmental cleaning applications.

Synthesis of CdS with Graphene by CBD(Chemical Bath Deposition) Method and Its Photocatalytic Activity

  • Pawar, R.C.;Lee, Jin-Yong;Kim, Eun-Jeong;Kim, Hyungsub;Lee, Caroline Sunyong
    • Korean Journal of Materials Research
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    • v.22 no.10
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    • pp.504-507
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    • 2012
  • Synthesis of RGO (reduced graphene oxide)-CdS composite material was performed through CBD (chemical bath deposition) method in which graphene oxide served as the support and Cadmium Sulfate Hydrate as the starting material. Graphene-based semiconductor photocatalysts have attracted extensive attention due to their usefulness for environmental and energy applications. The band gap (2.4 eV) of CdS corresponds well with the spectrum of sunlight because the crystalline phase, size, morphology, specic surface area and defects, etc., of CdS can affect its photocatalytic activity. The specific surface structure (morphology) of the photocatalyst can be effective for the suppression of recombination between photogenerated electrons and holes. Graphene (GN) has unique properties such as a high value of Young's modulus, large theoretical specific surface area, excellent thermal conductivity, high mobility of charge carriers, and good optical transmittance. These excellent properties make GN an ideal building block in nanocomposites. It can act as an excellent electron-acceptor/transport material. Therefore, the morphology, structural characterization and crystal structure were observed using various analytical tools, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy. From this analysis, it is shown that CdS particles were well dispersed uniformly in the RGO sheet. Furthermore, the photocatalytic property of the resulting RGO-CdS composite is also discussed in relation to environmental applications such as the photocatalytic degradation of pollutants. It was found that the prepared RGO-CdS nanocomposites exhibited enhanced photocatalytic activity as compared with that of CdS nanoparticles. Therefore, better efficiency of photodegradation was found for water purification applications using RGO-CdS composite.

Investigation of Tensile Behaviors in Open Hole and Bolt Joint Configurations of Carbon Fiber/Epoxy Composites

  • Dong-Wook Hwang;Sanjay Kumar;Dong-Hun Ha;Su-Min Jo;Yun-Hae Kim
    • Composites Research
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    • v.36 no.4
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    • pp.259-263
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    • 2023
  • This study investigated the open hole tensile (OHT) properties of carbon fiber/epoxy composites and compared them to bolt joint tensile (BJT) properties. The net nominal modulus and strength (1376 MPa) were found to be higher than the gross nominal strength (1041 MPa), likely due to increasing hole size. The OHT and BJT specimens exhibited similar stiffness, as expected without bolt rotation causing secondary bending. OHT specimens experienced a sharp drop in stress indicating unstable crack propagation, delamination, and catastrophic failure. BJT specimens failed through shear out on the bolt side and bearing failure on the nut side, involving fiber kinking, matrix splitting, and delamination, resulting in lower strength compared to OHT specimens. The strength retention of carbon fiber/epoxy composites with open holes was 66%. Delamination initiation at the hole's edge caused a reduction in the stress concentration factor. Filling the hole with a bolt suppressed this relieving mechanism, leading to lower strength in BJT specimens compared to OHT specimens. Bolt joint efficiency was calculated as 15%. The reduction in strength in bolted joints was attributed to fiber-matrix splitting and delamination, aligning with Hart Smith's bolted joint efficiency diagram. These findings contribute to materials selection and structural reliability estimation for carbon fiber/epoxy composites. They highlight the behavior of open hole and bolt joint configurations under tensile loading, providing valuable insights for engineering applications.

Erection Capability of Heavy Precast Frames with Metal Plates using Wet Concrete for Tolerance (톨러런스기반 플레이트 접합 장치를 사용한 고중량 RC보의 설치 성능)

  • Hong, Won-Kee;Nguyen, Van Tien;Nguyen, Manh Cuong;Nkundimana, Eric
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.12-13
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    • 2021
  • Methods for the manufacture, erection, and assembly of heavy frame modules were proposed. Interferences among precast members were prevented by using bolted metal plates for dry precast beam-to-column joints during assembly with a clearance for tolerance implementing grouted concrete filler plates instead of metal filler plates. Clearances for tolerances were provided to avoid conflictions among components during erection phases. These gaps were, then, grouted by high-strength mortar. The constructability of new connections of a beam-to-column joint using bolted metal plates for precast structures was examined using a full-scale assembly test in which practical observations indicated that members could be aligned and placed accurately in both horizontal and vertical directions, leading to a fast and convenient assembling. Bolt holes of the endplate were properly aligned using couplers with 30 mm fastened length embedded in the columns. The assembly test demonstrated the erection safety and structural stability of the proposed joints that were without filler plates when they were subjected to heavy loads at the time of their erection. The facile and rapid assembly of precast beam-to-column connections with a 30 mm tolerance was observed. The proposed assembly method is rapid, sustainable, and resilient, replacing the conventional methods of concrete frame construction, offering a connection that can be used in constructing infrastructure, such as buildings and pipe-rack frames.

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Behavior of lightweight aggregate concrete voided slabs

  • Adel A. Al-Azzawi;Ali O, AL-Khaleel
    • Computers and Concrete
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    • v.32 no.4
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    • pp.351-363
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    • 2023
  • Reducing the self-weight of reinforced concrete structures problem is discussed in this paper by using two types of self-weight reduction, the first is by using lightweight coarse aggregate (crushed brick) and the second is by using styropor block. Experimental and Numerical studies are conducted on (LWAC) lightweight aggregate reinforced concrete slabs, having styropor blocks with various sizes of blocks and the ratio of shear span to the effective depth (a/d). The experimental part included testing eleven lightweight concrete one-way simply supported slabs, comprising three as reference slabs (solid slabs) and eight as styropor block slabs (SBS) with a total reduction in cross-sectional area of (43.3% and 49.7%) were considered. The holes were formed by placing styropor at the ineffective concrete zones in resisting the tensile stresses. The length, width, and thickness of specimen dimensions were 1.1 m, 0.6 m, and 0.12 m respectively, except one specimen had a depth of 85 mm (which has a cross-sectional area equal to styropor block slab with a weight reduction of 49.7%). Two shear spans to effective depth ratios (a/d) of (3.125) for load case (A) and (a/d) of (2) for load case (B), (two-line monotonic loads) are considered. The test results showed under loading cases A and B (using minimum shear reinforcement and the reduction in cross-sectional area of styropor block slab by 29.1%) caused an increase in strength capacity by 60.4% and 54.6 % compared to the lightweight reference slab. Also, the best percentage of reduction in cross-sectional area is found to be 49.7%. Numerically, the computer program named (ANSYS) was used to study the behavior of these reinforced concrete slabs by using the finite element method. The results show acceptable agreement with the experimental test results. The average difference between experimental and numerical results is found to be (11.06%) in ultimate strength and (5.33%) in ultimate deflection.

Experimental Study on Two-Seam Cold Formed Square CFT Column to Beam Connections with Asymmetric Diaphragms (상하 이형 다이아프램으로 보강된 2심 냉간성형 각형 CFT 기둥-보 접합부의 실험적 연구)

  • Oh, Heon Keun;Kim, Sun Hee;Choi, Sung Mo
    • Journal of Korean Society of Steel Construction
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    • v.25 no.1
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    • pp.35-45
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    • 2013
  • The concrete-filled tube column has the excellent structural performance. But it is difficult to connect with column and beam because of closed section. It suggests that pipe should be produced by welding two sides together where two shapes are joined after a channel is pre-welded onto the three sides in order to form an internal diaphragm. The upper diaphragm of the connection used the horizontal plate and the lower diaphragm used the Vertical plate. This research performed 6 monotonic tension experiments describing the connection upside and downside in order to evaluate the structural capability of the offered connection. And the cyclic loading experiment was performed about 2 T-Type column to beam connections. As to the experimental result edge cutting geometry, there was no big effect. An increase in the number of holes of the plate ultimate strength was increased by 5% and The thickness of the plate increases, the maximum strength was increased by 4%. T-Type connections until it reaches the plastic moment showed a stable behavior.

Level Set Based Topological Shape Optimization of Hyper-elastic Nonlinear Structures using Topological Derivatives (위상 민감도를 이용한 초탄성 비선형 구조의 레벨셋 기반 위상 및 형상 최적설계)

  • Kim, Min-Geun;Ha, Seung-Hyun;Cho, Seonho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.25 no.6
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    • pp.559-567
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    • 2012
  • A level set based topological shape optimization method for nonlinear structure considering hyper-elastic problems is developed. To relieve significant convergence difficulty in topology optimization of nonlinear structure due to inaccurate tangent stiffness which comes from material penalization of whole domain, explicit boundary for exact tangent stiffness is used by taking advantage of level set function for arbitrary boundary shape. For given arbitrary boundary which is represented by level set function, a Delaunay triangulation scheme is used for current structure discretization instead of using implicit fixed grid. The required velocity field in the actual domain to update the level set equation is determined from the descent direction of Lagrangian derived from optimality conditions. The velocity field outside the actual domain is determined through a velocity extension scheme based on the method suggested by Adalsteinsson and Sethian(1999). The topological derivatives are incorporated into the level set based framework to enable to create holes whenever and wherever necessary during the optimization.

Optimum Design and Structural Application of the Bracing Damper System by Utilizing Friction Energy Dissipation and Self-Centering Capability (마찰 에너지 소산과 자동 복원력을 활용한 가새 댐퍼 시스템의 최적 설계와 구조적 활용)

  • Hu, Jong Wan;Park, Ji-Woong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.2
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    • pp.377-387
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    • 2014
  • This study mainly treats a new type of the bracing friction damper system, which is able to minimize structural damage under earthquake loads. The slotted bolt holes are placed on the shear faying surfaces with an intention to dissipate considerable amount of friction energy. The superelastic shape memory alloy (SMA) wire strands are installed crossly between two plates for the purpose of enhancing recentering force that are able to reduce permanent deformation occurring at the friction damper system. The smart recentering friction damper system proposed in this study can be expected to reduce repair cost as compared to the conventional damper system because the proposed system mitigates the inter-story drift of the entire frame structure. The response mechanism of the proposed damper system is firstly investigated in this study, and then numerical analyses are performed on the component spring models calibrated to the experimental results. Based on the numerical analysis results, the seismic performance of the recentering friction damper system with respect to recentering capability and energy dissipation are investigated before suggesting optimal design methodology. Finally, nonlinear dynamic analyses are conducted by using the frame models designed with the proposed damper systems so as to verify superior performance to the existing damper systems.

A Study on the Relationship between Cooperation Network and Publication Performance of Korean Government-Funded Research Institutes through Collaborative Paper Status (공동논문 현황을 통한 정부출연(연)의 협력네트워크 구조와 논문성과와의 관계 분석)

  • Chung, Taewon;Chung, Dongsub;Kim, JeongHeum
    • Journal of Korea Technology Innovation Society
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    • v.17 no.1
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    • pp.242-263
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    • 2014
  • Establishment of efficient cooperative ecosystem of research institutes is important for the efficiency of national innovation system, especially in the era of technology convergence. Performance of institutes inside the ecosystem is dependent on the position of the institutes in the system. This study investigates the relationship between network structure and research performance, and determines significant factors on the research performance. The results of 5 year panel data analysis of SCI journal papers of Korean government research institutes indicate that four network centralities -degree, betweenness, closeness, and eigenvector- and structural holes have significant effect on the research performance of the institutes. Among the four centralities, closeness and eigenvectors are more significant than others. Implications of the results of this study for policy of establishing efficient cooperative system are that increasing the cooperative activities of less active institutes is more effective for research performance than increasing the magnitude of cooperative activities of all institutes. Also, when an institute starts a new cooperative relationship, it is better to have relationship with an active institute first.