• Journal of Magnetics
• /
• v.18 no.4
• /
• pp.405-411
• /
• 2013

The structural, magnetic and magnetocaloric properties of $CoMn_{1-x}Cr_xGe$ (x=0.05-0.125) have been investigated by using electron microscopy, x-ray diffraction, calorimetric and magnetic measurements. In this study, our aim is to justify the magnetocaloric effect by tuning the structural and magnetic transition temperature with Cr doping on CoMnGe pure system. The substitution of Cr for Mn leads to a decrease of both structural and magnetic transition temperatures. However, structural and magnetic transition temperatures do not close to each other. From magnetization measurement, we calculate that isothermal entropy change associated with magnetic transition can be as high as 3.82 J $kg^{-1}K^{-1}$ at 302 K in a field of 7 T. Meanwhile, structural phase transition contribution to isothermal entropy change is calculated as 5.85 J $kg^{-1}K^{-1}$ at 322 K for 7 T.

• Steel and Composite Structures
• /
• v.43 no.3
• /
• pp.363-373
• /
• 2022

As a key reinforcement connection between a tower and a substructure in offshore wind turbine system, the transition piece is inevitably subjected to cyclic dynamic environmental loads such as wind, current and wave. Therefore, well designed transition piece with high strength and good fatigue resistance is of great significance to the structural safety and reliability of offshore wind power systems. In this study, the structural behavior of the transition piece was studied by an extensive sets of finite element analyses. Three widely used types of transition piece were considered. The characteristics of stress development, fatigue life and weight depending on the type of the transition piece were investigated in the ultimate limit state (ULS) and the fatigue limit state (FLS) of a 5-MW offshore wind turbine to be placed in Korea. An optimal form of the transition piece was proposed based on this parametric study.

• Journal of the Korean Society for Railway
• /
• v.17 no.4
• /
• pp.260-269
• /
• 2014

Transition tracks are an alternative for enhancing the long-term serviceability and durability of concrete track components in railway bridges. The goal of this paper is to investigate the structural behavior for transition track systems of railway bridge deck ends. In this study, the structural behavior of transition tracks such as the variations in static, dynamic, and fatigue behaviors and dynamic properties (natural frequency and damping ratio) are assessed and compared through performing loading tests and finite element analyses using actual vehicle impact loadings. As a result, it is found that the structural behavior of the transition track system is expected to satisfy the actual vehicle impact loading, and the variation in the neutral axis and dynamic characteristics are not affected by the fatigue loading. Therefore, it is inferred that the structural capacity and long-term durability of the transition track system is proven.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.08a
• /
• pp.202.2-202.2
• /
• 2013

Ti2O3 is known as a typical Mott insulator with a transition temperature of near $200^{\circ}C$. Unlike VO2, Ti2O3 does not have a structural phase transition near the metal-insulator-transition (MIT) temperature. We investigated the temperature-dependent thermal vibration change using temperature-dependent x-ray absorption fine structure (XAFS) at Ti K-edge in the temperature range of 300~600 K. Ti2O3 powder and films were synthesized using thermal chemical vapor deposition (CVD) at $800{\sim}900^{\circ}C$. X-ray diffraction measurements show a single phased Ti2O3 at room temperature. XAFS confirmed no structural phase transition in the temperature of 300~600 K. A small but distinguishable structural disorder change was observed near the transition temperature. We will discuss the MIT behavior with the change of structural disorder.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.169.2-169.2
• /
• 2015

$VO_2$ is a well-known a metal-to-insulator-transition (MIT) material, accompanied with a first order structural phase transition near room temperature. Because of the structural phase transition and the MIT occur near a same temperature, there is an ongoing argument whether the MIT is induced by the structural phase transition. $VO_2$ exhibits a relatively weak anti-oxidization ability and can be oxidized to higher-valence oxides (e.g., $V_4$ $O_7$ or $V_2$ $O_5$) when annealed at a high temperature in an oxygen-rich atmosphere. We fabricated $VO_2$ films on $Al_2$ $O_3$ (0001) substrates using a DC magnetron sputtering deposition process with carefully control the $O_2$ percentage in an atmosphere. X-ray diffraction measurements from the films showed only (0l0) peaks with no extra peaks, indicating b-oriented films. The temperature-dependent local structural properties of $VO_2$ films were investigated by using in-situ X-ray absorption fine structure (XAFS) measurements at the V K edge. XAFS revealed that the structural phase transition was occurred nearly $70^{\circ}C$ for heating process and reproducible. Resistance measurements as a function of temperature (R-T) demonstrated that the resistance of $VO_2$ films was changed by a factor of 4 near $75^{\circ}C$ which was higher than $68^{\circ}C$ reported from a $VO_2$ bulk. We will discuss the MIT of $VO_2$ films, comparing with the local structural properties determined by XAFS measurements.

• Journal of Korean Vacuum Science & Technology
• /
• v.7 no.1
• /
• pp.13-17
• /
• 2003

The influence of structural transition on the resistance and impedance behavior of Ni$_2$MnGa alloy was investigated. The temperature-dependent resistance and impedance were measured in a temperature range of 4 - 350 K and 185 - 300 K, respectively. The dependence of temperature coefficient of resistivity on temperature shows a kink at 220 K, which is related to the structural transition. The change in dominant scattering mechanism results in the observed kink. Significant increases were also observed around the transition temperature for both real and imaginary parts of impedance. It is thought that this phenomenon originates from disappearance of the martensite twin boundaries during the structural transformation.

• Bulletin of the Korean Chemical Society
• /
• v.25 no.7
• /
• pp.959-964
• /
• 2004

A low-dimensional metal frequently exhibits a metal-insulator transition through a charge-density-wave (CDW) or a spin-density-wave (SDW) which accompany it's structural changes. The transition temperature is thought to be determined by the amount of energy produced during the transition process and the softness of the original structure. $AMo_4O_6$ (A=K, Sn) are known to be quasi-one dimensional metals which exhibit metalinsulator transitions. The difference of the transition temperatures between $KMo_4O_6$ and $SnMo_4O_6$ (A=K, Sn) is examined by investigating their electronic and structural properties. Fermi surface nesting area and the lattice softness are the governing factors to determine the metal-insulator transition temperature in $AMo_4O_6$ compounds.

• Proceedings of the Computational Structural Engineering Institute Conference
• /
• 1993.04a
• /
• pp.3-10
• /
• 1993

A new three-dimensional transition solid elements was presented for the automated three-dimensional adaptive h-refinement where the steep stress gradient exists. To be consistent with 8-node solid element with nonconforming modes in accuracy, these transition elements were improved through the addition of the associated nonconforming modes. Numerical examples show that the performance of the element and the applicability to 3D adaptations are satisfactory.

• Journal of Surface Science and Engineering
• /
• v.50 no.3
• /
• pp.141-146
• /
• 2017

We investigated configuration of metallic and insulating domains in $VO_2$ thin films, while spanning metal-insulator phase transition. Kelvin probe force microscopy, of which spatial resolution is less than 100 nm, enables us to measure local work function (WF) at the sample surface. The WF of $VO_2$ thin films decreased (increased) as increasing (decreasing) the sample temperature, during the phase transition. The higher and lower WF regions corresponded to the insulating and metallic domains, respectively. The metallic fraction, estimated from the WF maps, well explained the temperature-dependent resistivity based on the percolation model. The WF mapping also showed us how the structural defects affected the phase transition behaviors.

• Proceedings of the Computational Structural Engineering Institute Conference
• /
• 1993.10a
• /
• pp.8-15
• /
• 1993

The transition membrane elements with drilling freedom have been developed. The functionals for the linear problem, in which the drilling rotations are introduced as independent variables, have been presented by Hughes & Bressi. And 4-node membrane elements with drilling degrees of freedom were developed by Ibrahimbegovic. The transition elements can be efficiently used in modelling the in-plane structures, in particular, where the stress concentration exists. A modified Gaussian quadrature adopted to evaluate the stiffness matrices of these transition elements which have slope discontinuity of displacement within the elements. Detailed numerical studies show the excellent performance of the transition elements.