• 한국해양공학회지
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• 제1권2호
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• pp.113-122
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• 1987

Ships and offshore strrctures are exposed to the corrosive surroundings, and the extablishment of the design criteria and the elucidation on the influence by this environment are requested to maintain the safety and to demonstrate the function of the structure. In this paper, the fatigue-crack-growth behavior on the compact tension specimens of quenched, tempered HT80 grade steels and RA36 high tensile steels having a single edge fatigue cracked notch respectively, were investigated under the repeated tensile stress with constant stroke in sea water for the welded parts by shielded metal arc welding. Main results obtained are summerized as follows; 1. The fatigue-crack-growth rates da/dN in sea water appeared to be greater behavior than those in air environment at the same stress intensisy factor range $\DeltaK$. 2. The correlation data of da/dN$\DeltaK$ of the two kinds of high tensile steels in sea water showed no great difference, however, the correlation data of da/dN$\DeltaK/\sigma_y$($\sigma_y$ stands for yield strength of the material) showed that the fatigue-crack-growth behavior of RA36 plate is affected by active path corrosion(APC) mechanism, while that of HT80 grade plate is mainly affected by hydrogen embrittlement mechanism.

• 대한기계학회논문집A
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• 제36권11호
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• pp.1381-1389
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• 2012

본 논문에서는 쇼트피닝 가공한 알루미늄 7075-T6 재료의 부식피로향상에 대한 연구를 하였다. 사용된 알루미늄 금속은 상대적으로 가볍고 강한 재료의 특성으로 항공기 주요부품의 재료로 사용되고 있으며, 많은 연구를 통해 알루미늄을 사용하면 약 50%의 무게 감소효과를 낼 수 있다고 한다. 재료의 부식은 인장환경에서 재료의 파단시점을 앞당기고 구조물의 수명을 심각하게 감소시킨다. 따라서 알루미늄 금속의 부식 환경에서의 재료의 부식저항을 향상 시킬 수 있는 연구가 요구된다. 쇼트피닝 가공은 재료 표면에 압축잔류응력을 인가하여 재료의 피로수명을 늘리고 나아가 재료의 신뢰성을 확보하는 기술로 반복하중을 받는 많은 부품들에 이미 적용되어 사용되고 있다. 부식 환경에서는 가공 후 거칠어진 표면으로 인해 공식부식을 야기하지만, 피닝가공에 의한 표면 직하에 압축잔류응력이 부식을 억제하여 부식저항을 증가시킨다. 본 연구에서의 쇼트피닝가공된 시험편에 대한 실험결과와 선행연구에서의 쇼트피닝 가공하지 않은 알루미늄 합금 재료의 부식피로특성을 비교하였다. 실험 결과 쇼트피닝 가공은 알루미늄합금의 피로수명향상에 영향을 미치고, 압축잔류응력은 부식피로수명을 증가시킴을 알 수 있었다.

• Corrosion Science and Technology
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• 제18권4호
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• pp.129-137
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• 2019

CFRP (Carbon Fiber Reinforced Plastics) is composed of carbon fiber and plastic resin, and is approximately 20 - 50% lighter than metallic materials. CFRP has a low density, higher specific stiffness, specific strength, and high corrosion resistance. Because of these excellent properties, which meet various regulation conditions needed in the industrial fields, CFRP has been widely used in many industries including aviation and ship building. However, CFRP reveals water absorption in water immersion or high humidity environments, and water absorption occurs in an epoxy not carbon fiber, and can be facilitated by higher temperature. Since these properties can induce volume expansion inside CFRP and change the internal stress state and degrade the chemical bond between the fiber and the matrix, the mechanical properties including bond strength may be lowered. This study focused on the effects of NaCl concentration (0.01 - 1% NaCl) and solution temperature ($30-75^{\circ}C$) on the galvanic corrosion between CFRP and A516Gr.55 carbon steel. When NaCl concentration increases 10 times, corrosion rate of a specimen was not affected, but that of galvanic coupled carbon steel increased by 46.9% average. However, when solution temperature increases $10^{\circ}C$, average corrosion rate increased approximately 22%, regardless of single or galvanic coupled specimen.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.76.1-76.1
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• 2010

Recently, many efforts to solve the durability problem of PEM fuel cell are carried on constantly. However, despite this attention, durability researches of gas diffusion layer (GDL) are not much reported yet. Generally, GDL of PEM fuel cell experiences three external attacks, which are dissolution of water, erosion of gas flow, corrosion of electric potential. In this study, among these degradation factors, carbon corrosion of electric potential was focused and investigated with accelerated carbon corrosion test. Through the test, it is confirmed that carbon corrosion occurred at GDL, and corroded GDL decreased a performance of operating fuel cell. The property changes of GDL were measured with various methods such as air permeability meter, pore distribution analyzer, thermo gravimetric analyzer, and tensile stress test to discover the effects of carbon corrosion. Carbon corrosion caused not only loss of weight and thickness, but also degradation of mechanical strength of GDL. In addition, to analysis the reason of GDL property changes, a surface and a cross section of GDL were observed with scanning electron microscope. After 100 hours test, the GDL showed serious damage in center of layer.

• 대한기계학회논문집A
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• 제25권6호
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• pp.965-971
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• 2001

To estimate the reliability of 12Cr alloy steel, the material of turbine blade in the steam power plant, Its corrosion susceptibility and fatigue characteristics in NaCl and Na$_2$SO$_4$solution with the difference of concentration and temperature was investigated. The polarization tests recommended in ASTM G5 standard for corrosion susceptibility in the various corrosive solutions was estimated. It showed that the higher temperature, the faster corrosion rates and corrosion rates were the fastest in 3.5 wt.% NaCl and 1M Na$_2$SO$_4$solution. From these results, the degradation conditions were determined in distilled water, 3.5 wt.% NaCl and 1M Na$_2$SO$_4$solution at room temperature, 60$\^{C}$ and 90$\^{C}$ during 3, 6 and 9 months. Its surface had a few pits for long duration. But, it was not susceptible in sulfide and chloride condition of several temperatures. If the degraded 12Cr alloy steel and non-degraded one were compared with fatigue characteristics, Any differences were not found regardless of temperature and degradation period.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.310-315
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• 2003

This paper presents the effect of boundary condition of failure pressure model for buried pipelines on failure prediction by using a failure probability model. The first order Taylor series expansion of the limit state function is used in order to estimate the probability of failure associated with various corrosion defects for long exposure periods in years. A failure pressure model based on a failure function composed of failure pressure and operation pressure is adopted for the assessment of pipeline failure. The effects of random variables such as defect depth, pipe diameter, defect length, fluid pressure, corrosion rate, material yield stress, material ultimate tensile strength and pipe thickness on the failure probability of the buried pipelines are systematically studied by using a failure probability model for the corrosion pipeline.

• International Journal of Precision Engineering and Manufacturing
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• 제4권6호
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• pp.12-19
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• 2003

This paper presents the effect of boundary conditions in various failure pressure models published for the estimation of failure pressure. Furthermore, this approach is extended to the failure prediction with the aid of a failure probability model. The first order Taylor series expansion of the limit state function is used in order to estimate the probability of failure associated with each corrosion defect in buried pipelines for long exposure period with unit of years. A failure probability model based on the von-Mises failure criterion is adapted. The log-normal and standard normal probability functions for varying random variables are adapted. The effects of random variables such as defect depth, pipe diameter, defect length, fluid pressure, corrosion rate, material yield stress, material ultimate tensile strength and pipe thickness on the failure probability of the buried pipelines are systematically investigated for the corrosion pipeline by using an adapted failure probability model and varying failure pressure model.

• 한국재료학회지
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• 제28권12호
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• pp.738-747
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• 2018

For the aerospace structural application of high-strength 2xxx series aluminum alloys, stress corrosion cracking(SCC) behavior in aggressive environments needs to be well understood. In this study, the SCC sensitivities of 2024-T62, 2124-T851 and 2050-T84 alloys in a 3.5 % NaCl solution are measured using a constant load testing method without polarization and a slow strain rate test(SSRT) method at a strain rate of 10-6 /sec under a cathodic applied potential. When the specimens are exposed to a 3.5 % NaCl solution under a constant load for 10 days, the decrease in tensile ductility is negligible for 2124-T851 and 2050-T84 specimens, proving that T8 heat treatment is beneficial in improving the SCC resistance of 2xxx series aluminum alloys. The specimens are also susceptible to SCC in a hydrogen-generating environment at a slow strain rate of $10^{-6}/sec$ in a 3.5 % NaCl solution under a cathodic applied potential. Regardless of the test method, low impurity 2124-T851 and high Cu/Mg ratio 2050-T84 alloys are found to have relatively lower SCC sensitivity than 2024-T62. The SCC behavior of 2xxx series aluminum alloys in the 3.5 % NaCl solution is discussed based on fractographic and micrographic observations.

• Journal of Welding and Joining
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• 제27권6호
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• pp.74-79
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• 2009

Titanium and titanium alloy can be reproduced immediately even if oxide films($TiO_2$) break apart in sea water. Therefore, since titanium demonstrates large specific strength and outstanding resistance to stress corrosion cracking, crevice corrosion, pitting and microbiologically influenced corrosion in sea water environment, it has been widely applied to heat exchanger for ships. In particular, with excellent elongation, pure titanium may be deemed as optimal material for production of heat exchanger plate which is used with wrinkles formed for efficient heat exchange. Conventional plate type heat exchanger prevented leakage of liquid through insertion of gasket between plates and mechanical tightening by bolts and nuts, but in high temperature and high pressure environment, gasket deterioration and leakage occur, so heat exchanger for LPG re-liquefaction device etc do not use gasket but weld heat exchanger plate for use. On the other hand, since welded plate cannot be separated, it is important to obtain high quality reliable welds. In addition, for better workability and production performance, lasers that can obtain weldment with large aspect ratio and demonstrate fast welding speed even in atmospheric condition not in vacuum condition are used in producing products. So far, 1st report and 2nd report compared and analyzed embrittlement degrees by bead colors of weldment through quantitative analysis of oxygen and nitrogen and measurement of hardness as fundamental experiment for the evaluation of titanium laser welding, and evaluated the welding performance and mechanical properties of butt welding. This study welded specimens in various conditions by using laser and GTA welding machine to apply edge welding to heat exchanger, and evaluated the mechanical strength through tensile stress test. As a result of tensile test, laser weldment demonstrated tensile strength 4 times higher than GTA welds, and porosity could be controlled by increasing and decreasing slope of laser power at overlap area.

• 대한기계학회논문집A
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• 제26권2호
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• pp.374-379
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• 2002

Corrosion fatigue tests were carried out to clarify the influence of acid fog as environmental factor on the fatigue strength of SM55C using rotary bending fatigue tester. The fatigue strength of acid fog specimen extremely decreased about 80% compared to that of distilled water specimen. In acid fog environment, a number of cracks commenced at corrosion pit and coalesced with the adjacent cracks during they propagate, and they formed a single non-propagating circumferential crack under the endurance stress of N=5$\times$10$\^$7/ cycles. Also, the depth of the crack is smaller than that of normal fatigue crack, so the crack has a veil small aspect ratio. The reason of this peculiar crack growth characteristics is that the crack opening-closure behaviors are hindered by corrosion products on the surface crack faces, and hence it is thinkable that the strong corrosion action like anodic dissolution for crack growth in depth direction is weaker compared with surface, resulting from faint pumping action of crack during loading-shedding processes.